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Collinear dipole orders such as ferroelectricity and antiferroelectricity have developed rapidly in last decades. While, the noncollinear dipole orders are rarely touched in solids. Noncollinear dipole orders can provide a route to realize…

Materials Science · Physics 2024-11-01 Xinyu Yang , Jun Chen , Shan-Shan Wang , Shuai Dong

We report nearly single phase Pb(Zr0.14Ti0.56Ni0.30)O3-delta(PZTNi30) ferroelectric having large remanent polarization (15-30 {\mu}C/cm2), 0.3-0.4 V open circuit voltage (VOC), reduced band gap (direct 3.4 eV, and indirect 2.9 eV), large ON…

Materials Science · Physics 2014-03-04 Shalini Kumari , Nora Ortega , Ashok Kumar , J. F. Scott , R. S. Katiyar

Improper ferroelectrics are described by two order parameters: a primary one, driving a transition to long-range distortive, magnetic or otherwise non-electric order, and the electric polarization, which is induced by the primary order…

The electric polarization induced by local polar domains of two types (phase separation domains of magnetic nature and structure-distorted domains) has been observed in YCrO3 single crystals. These domains form a superparaelectric state.…

Materials Science · Physics 2019-02-19 V. A. Sanina , B. Kh. Khannanov , E. I. Golovenchits , M. P. Scheglov

The wealth of complex polar topologies recently found in nanoscale ferroelectrics result from a delicate balance between the materials intrinsic tendency to develop a homogeneous polarization and the electric and mechanic boundary…

We show the first-principles evidence of a hitherto unreported type of ferroelectricity with ultra-long ion-displacement in sodium and potassium hydroxides. Even a small amount of proton vacancies can completely change the mode of…

Materials Science · Physics 2018-12-04 Yangyang Ren , Shuai Dong , Menghao Wu

We report a ferroelectric order at ~ 98 K for NiFe2O4, which carries an inverse spinel structure with a centrosymmetric Fd3m structure at room temperature. The value of spontaneous electric polarization is considerably high as ~ 0.29…

Materials Science · Physics 2019-05-10 J. K. Dey , A. Chatterjee , S. Majumdar , A. -C. Dippel , O. Gutowski , M. v. Zimmermann , S. Giri

The number of magnetoelectric multiferroic materials reported to date is scarce, as magnetic structures that break inversion symmetry and induce an improper ferroelectric polarization typically arise through subtle competition between…

We have studied the structural phase transition of multiferroic YMnO$_3$ from first principles. Using group-theoretical analysis and first-principles density functional calculations of the total energy and phonons, we perform a systematic…

Materials Science · Physics 2009-11-11 Craig J. Fennie , Karin M. Rabe

Understanding the polarization switching mechanisms at play in ferroelectric materials is crucial for their exploitation in electronic devices. The conventional centrosymmetric reference structure-based mechanism which accounts for…

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

We show that for Ni$_3$V$_2$O$_8$ long-range ferroelectric and incommensurate magnetic order appear simultaneously in a single phase transition. The temperature and magnetic field dependence of the spontaneous polarization show a strong…

The statistical theory of the dipole flexoelectric (FE) polarization in liquid crystals is used to calculate the temperature dependence of order parameters, the elastic constants and the FE coefficients. Two systems with polar wedge-shaped…

Soft Condensed Matter · Physics 2011-02-10 A. Kapanowski

We have investigated the magnetic structure and ferroelectricity in RbFe(MoO$_4$)$_2$ via first-principles calculations. Phenomenological analyses have shown that ferroelectricity may arise due to both the triangular chirality of the…

Materials Science · Physics 2015-06-19 Kun Cao , R. D. Johnson , Feliciano Giustino , Paolo G. Radaelli , G-C Guo , Lixin He

The complete magnetic and multiferroic phase diagram of Mn$_{1-x}$Co$_{x}$WO$_4$ single crystals is investigated by means of magnetic, heat capacity, and polarization experiments. We show that the ferroelectric polarization…

Strongly Correlated Electrons · Physics 2012-07-13 K. -C. Liang , Y. Q. Wang , Y. Y. Sun , B. Lorenz , F. Ye , J. A. Fernandez-Baca , H. A. Mook , C. W. Chu

Ferroelectricity occurs in crystals with broken spatial inversion symmetry. In conventional perovskite oxides, concerted ionic displacements within a three-dimensional network of transition metal-oxygen polyhedra (MOx) manifest spontaneous…

Ferroelectric ordering, the electroclinic effect and chiral smectic C (SmC*) - smectic A (SmA*) phase transitions in thin planar ferroelectric liquid crystal (FLC) cells are studied by means of linear electrooptic and second harmonic…

Optics · Physics 2009-11-10 Yu. G. Fokin , T. V. Murzina , O. A. Aktsipetrov , S. Soria , G. Marowsky

Nematics with a broken polar symmetry is one of the fascinating recent discoveries in the field of soft matter. High spontaneous polarisation and the fluidity of the ferroelectric nematic $N_{\mathrm{F}}$ phase make such materials…

Soft Condensed Matter · Physics 2023-01-05 Evangelia Zavvou , Melanie Klasen-Memmer , Atsutaka Manabe , Matthias Bremer , Alexey Eremin

Two-dimensional (2D) ferroelectric semiconductors present opportunities for integrating ferroelectrics into high-density ultrathin nanoelectronics. Among the few synthesized 2D ferroelectrics, $\alpha$-In$_2$Se$_3$, known for its…

Materials Science · Physics 2024-02-29 Liyi Bai , Changming Ke , Zhongshen Luo , Tianyuan Zhu , Lu You , Shi Liu

Materials with reduced dimensions have been shown to host a wide variety of exotic properties and novel quantum states that often defy textbook wisdom1-5. Ferroelectric polarization and metallicity are well-known examples of mutually…