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Epitaxial CaMnO3 films grown with 2.3% tensile strain on (001)-oriented LaAlO3 substrates are found to be incipiently ferroelectric below 25 K. Optical second harmonic generation (SHG) was used for the detection of the incipient…

Materials Science · Physics 2015-06-05 T. Günter , E. Bousquet , A. David , Ph. Boullay , Ph. Ghosez , W. Prellier , M. Fiebig

Femtosecond time-resolved second harmonic generation (SHG) measurements were performed at room temperature on a single crystal of LuFe2O4, which has recently attracted attention as an electronic ferroelectric material in which polarization…

Materials Science · Physics 2024-05-13 H. Yu , Y. Fukada , G. Nishida , K. Takubo , T. Ishikawa , S. Koshihara , N. Ikeda , Y. Okimoto

We present a detailed study of complex dielectric constant and ferroelectric polarization in multiferroic LiCuVO4 as function of temperature and external magnetic field. In zero external magnetic field, spiral spin order with an ab helix…

Strongly Correlated Electrons · Physics 2008-04-15 F. Schrettle , S. Krohns , P. Lunkenheimer , J. Hemberger , N. Büttgen , H. -A. Krug von Nidda , A. V. Prokofiev , A. Loidl

The influence of the pore network geometry and interparticle long-distance electric coupling on the ferroelectric phase transition in small particles embedded into mesoporous matrices is considered. It was shown that the temperature of the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 E. V. Charnaya , A. L. Pirozerski , Cheng Tien , M. K. Lee

Experimental observations of the change in the polarization charge of pyroelectric crystals of LiNbO3, LiTaO3 and CsNO3, as the temperature of the crystal is changed from about 300K to a lower limit of 4.2K, are described. It was found that…

Materials Science · Physics 2007-05-23 James D. Brownridge , Sol Raboy

Ferroelectricity (Valasek, J. Phys. Rev. 1921, 17, 475) - a spontaneous formation of electric polarisation - is a solid state phenomenon, usually, associated with ionic compounds or complex materials. Here we show that, atypically for…

Materials Science · Physics 2023-05-29 Aitor Garcia-Ruiz , Vladimir Enaldiev , Andrew McEllistrim , Vladimir I. Fal'ko

GaFeO3, AlFeO3 and related oxides are ferrimagnetic exhibiting magnetodielectric effect. There has been no evidence to date for ferroelectricity and hence multiferroicity in these oxides. We have investigated these oxides as well as oxides…

From an experimental point of view, room temperature ferroelectricity in BiFeO3 is raising many questions. Electric measurements made a long time ago on solid-solutions of BiFeO3 with Pb(Ti,Zr)O3 indicate that a spontaneous electric…

Monte Carlo simulations are used to examine cooperative creation of polar state in fluids of two-state particles with nonzero dipole in the excited state. With lowering temperature such systems undergo a second order transition from…

Soft Condensed Matter · Physics 2009-11-11 Dmitry V. Matyushov , Andriy Okhrimovskyy

Magnetic properties of high purity stoichiometric La$_2$CuO$_4$ nanoparticles are systematically investigated as a function of particle size. Ferromagnetic single-domain spin clusters are shown to spontaneously form at the surface of fine…

Strongly Correlated Electrons · Physics 2009-11-13 R. V. Yusupov , V. V. Kabanov , D. Mihailovic , K. Conder , K. A. Mueller , H. Keller

We review the phenomenology of coupled magnetic and electric order parameters for systems in which ferroelectric and incommensurate magnetic order occur simultaneously. We discuss the role that such materials might play in fabricating novel…

Materials Science · Physics 2007-05-23 A. B. Harris , G. Lawes

We present a first principles study of the series of multiferroic barium fluorides with the composition BaMF4, where M is Mn, Fe, Co, or Ni. We discuss trends in the structural, electronic, and magnetic properties, and we show that the…

Materials Science · Physics 2009-11-11 Claude Ederer , Nicola A. Spaldin

Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper…

Materials Science · Physics 2009-11-13 Silvia Picozzi , Kunihiko Yamauchi , Biplab Sanyal , Ivan A. Sergienko , Elbio Dagotto

In the last decades, multifunctional single-crystals that show, for example, multiferroic and magnetoelectric responses have attracted considerable attention due to the potential applications and physical phenomena involved in the…

Materials Science · Physics 2024-06-10 W. Ibarra-Hernández , A. Bautista-Hernández , A. C. Garcia-Castro

Two-dimensional ferroelectric monolayers are promising candidates for compact memory devices and flexible electronics. Here, through first-principles calculations, we predict room temperature ferroelectricity in AB-type monolayers…

The question of whether one can systematically identify (previously unknown) ferroelectric phases of a given material is addressed, taking hafnia (HfO$_2$) as an example. Low free energy phases at various pressures and temperatures are…

Materials Science · Physics 2014-08-28 Tran Doan Huan , Vinit Sharma , George A. Rossetti, , Rampi Ramprasad

For Sn$_2$P$_2$S$_6$ ferroelectrics the second order phase transitions line is observed until reaching the tricritical point at transition temperature lowering to 250 K by compression. Observed temperature-pressure phase diagram agrees with…

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

Materials Science · Physics 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

A crystalline solid is a periodic sequence of identical cells, each containing one or more atoms. If the constituting unit cell is not centrosymmetric, charge may distribute unevenly between the atoms, resulting in internal electric…

The realization of multiferroicity in 2D nanomaterials is crucially important for designing advanced nanoelectronic devices such as non-volatile multistate data storage. In this work, the coexistence of ferromagnetism and ferroelectricity…

Materials Science · Physics 2019-11-12 Yanyu Liu , Wei Zhou , Gang Tang , Chao Yang , Xueyun Wang , Jiawang Hong
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