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Designing new 2D systems with tunable properties is an important subject for science and technology. Starting from graphene, we developed an algorithm to systematically generate 2D carbon crystals belonging to the family of graphdiynes…

Materials Science · Physics 2021-03-25 Patrick Serafini , Alberto Milani , Davide M. Proserpio , Carlo S. Casari

A structurally stable crystalline carbon allotrope is predicted by means of the first-principles calculations. This allotrope can be derived by substituting each atom in diamond with a carbon tetrahedron, and possesses the same space group…

Materials Science · Physics 2015-05-28 Xian-Lei Sheng , Qing-Bo Yan , Fei Ye , Qing-Rong Zheng , Gang Su

The structure of amorphous Cu$_2$GeTe$_3$ is investigated by a combination of anomalous x-ray scattering and extended x-ray absorption fine structure experiments. The experimental data are analyzed with a reverse Monte Carlo modeling…

A method is suggested for estimation of structural properties of amorphous fullerene and its derivatives produced by vacuum annealing. The method is based on the fitting of the neutron or x-ray powder diffraction patterns for scattering…

Materials Science · Physics 2014-12-24 V. S. Neverov , P. A. Borisova , A. B. Kukushkin , V. V. Voloshinov

A new kind of three-dimensional carbon allotropes, termed carbon honeycomb (CHC), has recently been synthesized [PRL 116, 055501 (2016)]. Based on the experimental results, a family of graphene networks are constructed, and their electronic…

Materials Science · Physics 2016-07-20 Yan Gao , Yuanping Chen , Chengyong Zhong , Zhongwei Zhang , Yuee Xie , Shengbai Zhang

We report a computational study of the anharmonicity of the vibrational modes of various individual fullerenes using the "moments method" [Y. Gao and M. Daw, Modelling Simul. Mater. Sci. Eng. 23 045002 (2015)] with a Tersoff-style potential…

Mesoscale and Nanoscale Physics · Physics 2017-05-02 Hengjia Wang , Murray S. Daw

Based on the third allotropic form of carbon (Fullerenes) through theoretical study have been predicted structures described as non-classical fullerenes. We have studied novel allotropic carbon structures with a closed cage configuration…

Materials Science · Physics 2017-05-24 Christian A. Celaya , Jesús Muñiz , Luis Enrique Sansores

In this paper, the validity and accuracy of three interatomic potentials and the continuum shell model of Ghaffari and Sauer [1] are investigated. The mechanical behavior of single-layered graphene sheets (SLGSs) under uniaxial stretching,…

Computational Physics · Physics 2023-05-26 Aningi Mokhalingam , Reza Ghaffari , Roger A. Sauer , Shakti S. Gupta

Through a systematic structural search we found an allotrope of carbon with Cmmm symmetry which we predict to be more stable than graphite for pressures above 10 GPa. This material, which we refer to as Z-carbon, is formed by pure sp3 bonds…

Although surface diffusion is critical for many physical and chemical processes, including the epitaxial growth of crystals and heterogeneous catalysis, it is particularly challenging to directly study. Here, we estimate the carbon adatom…

We study theoretically the equilibrium structure, as well as the response under external load, of characteristic carbon-based materials. The materials considered include diamond, amorphous carbon (a-C), ``amorphous diamond'' and…

The close packing density of log-normal and bimodal distributed, surface-adsorbed particles or discs in 2D is studied by numerical simulation. For small spread in particle size, the system orders in a polycrystalline structure of hexagonal…

Soft Condensed Matter · Physics 2012-01-27 Robert D. Groot , Simeon D. Stoyanov

Carbon-based materials have attracted great attention due to their exceptional structural diversity and wide-ranging applications. Recently, a new two-dimensional carbon allotrope, named pentagraphene (PG), was proposed. In this study, we…

High level ab initio calculations ranging from coupled cluster methods including explicitly correlated approaches to standard second order M{\o}ller-Plesset theory using spin scaling (SOS-MP2) have been performed on sandwich and slipped…

Chemical Physics · Physics 2016-11-15 Nadeesha J. Silva , Francisco B. C. Machado , Hans Lischka , Adelia J. A. Aquino

We have extended our experimentally constrained molecular relaxation technique (P. Biswas {\it et al}, Phys. Rev. B {\bf 71} 54204 (2005)) to hydrogenated amorphous silicon: a 540-atom model with 7.4 % hydrogen and a 611-atom model with 22…

Materials Science · Physics 2009-11-13 Parthapratim Biswas , Raymond Atta-Fynn , David A. Drabold

We report the results of X-ray spectroscopy and Raman measurements of as-prepared graphene on a high quality copper surface and the same materials after 1.5 years under different conditions (ambient and low humidity). The obtained results…

Many calculations require a simple classical model for the interactions between sp^2-bonded carbon atoms, as in graphene or carbon nanotubes. Here we present a new valence force model to describe these interactions. The calculated phonon…

Materials Science · Physics 2015-05-13 Vasili Perebeinos , J. Tersoff

A metallic covalently bonded carbon allotrope is predicted via first principles calculations. It is composed of an $sp^3$ carbon framework that acts as a diamond anvil cell by constraining the distance between parallel cis-polyacetylene…

Materials Science · Physics 2022-06-08 Xiaoyu Wang , Davide M Proserpio , Corey Oses , Cormac Toher , Stefano Curtarolo , Eva Zurek

Carbon nanoscroll is a unique topologically open configuration of graphene nanoribbon possessing outstanding properties and application perspectives due to its morphology. However molecular dynamics study of nanoscrolls with more than a few…

Mesoscale and Nanoscale Physics · Physics 2015-07-15 Alexander V. Savin , Elena A. Korznikova , Sergey V. Dmitriev

We use molecular dynamics computer simulations to study the equilibrium properties of the surface of amorphous silica. Two types of geometries are investigated: i) clusters with different diameters (13.5\AA, 19\AA, and 26.5\AA) and ii) a…

Statistical Mechanics · Physics 2009-10-31 Alexandra Roder , Walter Kob , Kurt Binder