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A new method is presented that allows for efficient evaluation of spin-orbit coupling (SOC) in density-functional theory calculations. In the so-called second-variational scheme, where Kohn-Sham functions obtained in a scalar-relativistic…

Materials Science · Physics 2023-06-06 Cecilia Vona , Sven Lubeck , Hannah Kleine , Andris Gulans , Claudia Draxl

Spin-orbit coupling (SOC) drives interesting and non-trivial phenomena in solid state physics, ranging from topological to magnetic to transport properties. Thorough study of such phenomena often require effective models where SOC term is…

Materials Science · Physics 2024-07-09 Qiangqiang Gu , Shishir Kumar Pandey

Spin-orbit coupling (SOC) lifts molecular orbital degeneracy, enabling bi-level electronic platforms suitable for next-generation digital devices. However, common light-atom molecular feedstocks exhibit weak SOC due to the absence of heavy…

Materials Science · Physics 2025-05-07 Zihao Wang , Wan-Lu Li , Shaowei Li

We propose a computational method that simplifies drastically the inclusion of spin-orbit interaction in density functional theory implemented on localised atomic orbital basis sets. Our method is based on a well-known procedure for…

Materials Science · Physics 2009-11-11 Lucas Fernandez-Seivane , Miguel A. Oliveira , Stefano Sanvito , Jaime Ferrer

A first-principles computational method with self-consistent on-site and inter-site Hubbard functionals is able to treat local and non-local Coulomb interactions on an equal footing. To apply the method to understand solids with strong…

Materials Science · Physics 2024-10-17 Wooil Yang , Young-Woo Son

Noncollinear (NC) magnetism and spin-orbit coupling (SOC) are indispensable for predictive ab initio materials simulations with pronounced relativistic effects and magnetic frustration, yet they significantly increase the cost of…

The development of new exchange-correlation functionals within density functional theory means that increasingly accurate information is accessible at moderate computational cost. Recently, a newly developed self-consistent hybrid…

Materials Science · Physics 2017-11-10 Daniel Fritsch , Benjamin J. Morgan , Aron Walsh

Spin-orbit coupling (SOC) relates to the interaction between an electron's motion and its spin, and is ubiquitous in solid-state systems. Although the effect of SOC in normal-state phenomena has been extensively studied, its role in…

Superconductivity · Physics 2024-07-02 Morten Amundsen , Jacob Linder , Jason W. A. Robinson , Igor Žutić , Niladri Banerjee

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy

This paper investigates the dynamics of spin-2 Bose-Einstein condensates (BECs) with rotation and spin-orbit coupling (SOC). In order to better simulate the dynamics, we present an efficient high-order compact splitting Fourier spectral…

Numerical Analysis · Mathematics 2026-03-27 Xin Liu , Ziqing Xie , Yongjun Yuan , Yong Zhang , Xinyi Zhao

Spin-orbit coupling (SOC), the core of numerous condensed-matter phenomena such as nontrivial band gap, magnetocrystalline anisotropy, etc, is generally considered to be appreciable only in heavy elements, detrimental to the synthetization…

Materials Science · Physics 2022-02-21 Jiayu Li , Qiushi Yao , Lin Wu , Zongxiang Hu , Boya Gao , Xiangang Wan , Qihang Liu

Quantum mechanical calculations of core electron binding energies (CEBEs) leading to 2p hole states are relevant to interpreting L-edge x-ray photo-electron spectroscopy (XPS), as well as higher edges. Orbital-optimized density functional…

Chemical Physics · Physics 2025-07-31 Richard Kang , Leonardo A. Cunha , Diptarka Hait , Martin Head-Gordon

A simple approximation within the framework of the hybrid methods for the calculation of the electronic structure of solids is presented. By considering only the diagonal elements of the perturbation operator (Hartree-Fock exchange minus…

Materials Science · Physics 2012-01-31 Fabien Tran

A new, very fast, implementation of the exact (Fock) exchange operator for electronic structure calculations within the plane-wave pseudopotential method is described in detail for both molecular and periodic systems, and carefully…

Materials Science · Physics 2018-12-12 Ivan Carnimeo , Stefano Baroni , Paolo Giannozzi

We use an effective field theory (EFT) approach to calculate the next to leading order (NLO) gravitational spin-orbit interaction between two spinning compact objects. The NLO spin-orbit interaction provides the most computationally complex…

General Relativity and Quantum Cosmology · Physics 2010-12-03 Michele Levi

Spin-orbit coupling in organic crystals is responsible for many spin-relaxation phenomena, going from spin diffusion to intersystem crossing. With the goal of constructing effective spin-orbit Hamiltonians to be used in multiscale…

Materials Science · Physics 2017-03-01 Subhayan Roychoudhury , Stefano Sanvito

We demonstrate the emergence of the non-Abelian geometric potentials and thus the three-dimensional (3D) spin-orbit coupling (SOC) for ultracold atoms without using the laser beams. This is achieved by subjecting an atom to a periodic…

Quantum Gases · Physics 2019-12-12 Povilas Račkauskas , Viktor Novičenko , Han Pu , Gediminas Juzeliūnas

The spin-orbit coupling (SOC) affecting the center of mass of ultracold atoms can be simulated using a properly chosen periodic sequence of magnetic pulses. Yet such a method is generally accompanied by micro-motion which hinders a precise…

We investigate the correlation effects on spin-orbit coupling (SOC) in a two-orbital Hubbard model on a square lattice by applying the variational Monte Carlo method. We consider an effective SOC constant $\lambda_{\text{eff}}$ in the…

Strongly Correlated Electrons · Physics 2022-11-11 Katsunori Kubo

The accurate modeling of spin-orbit coupling (SOC) effects in diverse complex systems remains a significant challenge due to the high computational demands of density functional theory (DFT) and the limited transferability of existing…

Materials Science · Physics 2025-04-29 Yang Zhong , Rui Wang , Xingao Gong , Hongjun Xiang
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