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Orbital-free density functional theory as an extension of traditional Thomas-Fermi theory has attracted a lot of interest in the past decade because of developments in both more accurate kinetic energy functionals and highly efficient…

Materials Science · Physics 2009-11-10 Hong Jiang , Weitao Yang

A new method of computing multipolar exchange interaction in spin-orbit coupled systems is developed using multipolar tensor expansion of the density matrix in LDA+U electronic structure calculation. Within mean-field approximation,…

Strongly Correlated Electrons · Physics 2014-03-06 Shu-Ting Pi , Ravindra Nanguneri , Sergey Savrasov

The need for accurate calculations on atoms and diatomic molecules is motivated by the opportunities and challenges of such studies. The most commonly-used approach for all-electron electronic structure calculations in general - the linear…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

Motivated by recent experimental development, we investigate spin-orbit coupled repulsive Fermi atoms in a one-dimensional optical lattice. Using the density-matrix renormalization group method, we calculate momentum distribution function,…

Quantum Gases · Physics 2015-10-09 Xiaofan Zhou , Kuang Zhang , Junjun Liang , Gang Chen , Suotang Jia

We present a practical approach to treat static and dynamical correlation accurately in large multi-configurational systems. The static correlation is accounted for using the spin-flip approach which is well known for capturing static…

Strongly Correlated Electrons · Physics 2021-02-08 Oinam Romesh Meitei , Nicholas J. Mayhall

Electronic structure calculations, such as in the Hartree-Fock or Kohn-Sham density functional approach, require an initial guess for the molecular orbitals. The quality of the initial guess has a significant impact on the speed of…

Chemical Physics · Physics 2019-03-13 Susi Lehtola

Synthetic spin-orbit coupling (SOC) in controlled quantum systems such as cold atoms or trapped ions has been of great interest. Here we show, both theoretically and computationally, a simplest realization of SOC using two-level cold atoms…

Quantum Gases · Physics 2015-06-11 Qi Zhang , Jiangbin Gong , C. H. Oh

We propose to measure the importance of spin-orbit couplings (SOCs) in the nonadiabatic molecular quantum dynamics rigorously with quantum fidelity. To make the criterion practical, quantum fidelity is estimated efficiently with the…

Chemical Physics · Physics 2013-01-15 Tomas Zimmermann , Jiri Vanicek

The scale and complexity of quantum system to which real-space quantum Monte Carlo (QMC) can be applied in part depends on the representation and memory usage of the trial wavefunction. B-splines, the computationally most efficient basis…

Materials Science · Physics 2018-09-05 Ye Luo , Kenneth P. Esler , Paul R. C. Kent , Luke Shulenburger

Spin-orbit coupling (SOC) is an essential ingredient in topological materials, conventional and quantum-gas based alike.~Engineered spin-orbit coupling in ultracold atom systems --unique in their experimental control and measurement…

The spin mixing conductance (SMC) is a key quantity determining efficiency of spin transport across interfaces. Thus, knowledge of its precise value is required for accurate measurement of parameters quantifying numerous effects in…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 Kapildeb Dolui , Utkarsh Bajpai , Branislav K. Nikolic

Spin-current density functional theory (SCDFT) is a formally exact framework designed to handle the treatment of interacting many-electron systems including spin-orbit coupling at the level of the Pauli equation. In practice, robust and…

We quantify the accuracy of different non-self-consistent and self-consistent spin-orbit coupling (SOC) treatments in Kohn-Sham and hybrid density-functional theory by providing a band structure benchmark set for the valence and low-lying…

Materials Science · Physics 2017-09-06 William P. Huhn , Volker Blum

To improve the computational efficiencies of the real-space orbital-free density functional theory, this work develops a new single-grid solver by directly providing the closed-form solution to the inner iteration and using an improved…

Computational Physics · Physics 2023-05-16 Ling-Ze Bu , Wei Wang

Spin-orbit coupling (SOC) plays an important role in determining the structural and electronic properties of recently proposed two-dimensional planar pentagonal materials. In this work, density functional theory calculations are employed to…

We present an efficient and accurate implementation of hybrid exchange-correlation (XC) functionals in the SIESTA code, enabling large-scale simulations based on Hartree-Fock-type exact exchange combined with strictly localized numerical…

We have developed and implemented a self-consistent density functional method using standard norm-conserving pseudopotentials and a flexible, numerical LCAO basis set, which includes multiple-zeta and polarization orbitals. Exchange and…

Performing high accuracy hybrid functional calculations for condensed matter systems containing a large number of atoms is at present computationally very demanding - when not out of reach - if high quality basis sets are used. We present a…

Materials Science · Physics 2017-12-22 Laura E. Ratcliff , A. Degomme , José A. Flores-Livas , Stefan Goedecker , Luigi Genovese

We present a generalized extension of the recently developed electron/hole-transfer Dynamically-weighted State-Averaged Constrained CASSCF (eDSC/hDSC) method to model charge transfer in the presence of spin-orbit coupling (SOC) for systems…

Chemical Physics · Physics 2026-02-13 Alok Kumar , Zhen Tao , Joseph E. Subotnik , Tian Qiu

Spin-orbit coupling (SOC) can give rise to interesting physics, from spin Hall to topological insulators, normally in condensed matter systems. Recently, this topical area has extended into atomic quantum gases in searching for…

Quantum Gases · Physics 2012-04-11 Z. F. Xu , L. You