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Swap algorithms can shift the glass transition to lower temperatures, a recent unexplained observation constraining the nature of this phenomenon. Here we show that swap dynamic is governed by an effective potential describing both particle…

Soft Condensed Matter · Physics 2018-09-12 Carolina Brito , Edan Lerner , Matthieu Wyart

In two recent interesting letters evidence was presented for the existence of a growing dynamic correlation length when we approach the glass transition from the liquid phase (a similar divergence is present also in the off-equilibrium…

Statistical Mechanics · Physics 2007-05-23 S. Franz , G. Parisi

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

Statistical Mechanics · Physics 2015-06-23 Mikhail Vasin

In this work, we study the nature of transitions between inherent structures of a two-dimensional model supercooled liquid. We demonstrate that these transitions occur predominately along a small number of directions on the energy…

Statistical Mechanics · Physics 2013-03-12 Glen M. Hocky , David R. Reichman

State-of-the-art techniques for simulating deeply supercooled liquids require a high degree of size polydispersity to be effective. While these techniques have enabled great insight into the microscopic dynamics near the glass transition,…

Soft Condensed Matter · Physics 2023-08-10 Ilian Pihlajamaa , Corentin C. L. Laudicina , Liesbeth M. C. Janssen

Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative predictions of -relaxation activation barriers provided by the theory of glasses based on random first order transitions are compared with…

Soft Condensed Matter · Physics 2007-05-23 Jacob D. Stevenson , Peter G. Wolynes

Among the outstanding problems in the theory of supercooled liquids are the reasons for the rapid increase in their viscosity and relaxation times as the temperature is lowered towards the glass transition temperature, the non-exponential…

Disordered Systems and Neural Networks · Physics 2015-06-25 V. Halpern

Metallic glasses are formed by splat-cooling; this ensures that atomic motions are arrested before the latent heat of solidification can be extracted. Glass is defined as a higher disorder metastable state with arrested kinetics. Arrested…

Statistical Mechanics · Physics 2012-07-31 Praveen Chaddah , Alok Banerjee

In recent years it has become widely accepted that a dynamical length scale {\xi}_{\alpha} plays an important role in supercooled liquids near the glass transition. We examine the implications of the interplay between the growing…

Disordered Systems and Neural Networks · Physics 2016-09-28 Jacob D. Stevenson , Peter G. Wolynes

It is experimentally shown that, depending on the carrier-concentration of the system $n$, the dynamics of electron-glasses either \textit{slows down }with increasing temperature or it is \textit{independent} of it. This also correlates…

Strongly Correlated Electrons · Physics 2007-11-28 Z. Ovadyahu

A Monte Carlo method is used in order to simulate the competition between the molecular relaxation and crystallization times in the formation of a glass. The results show that nucleation is avoided during supercooling and produce…

Disordered Systems and Neural Networks · Physics 2009-11-07 Adrian Huerta , Gerardo G. Naumis

Recent experiments and computer simulations show that supercooled liquids around the glass transition temperature are "dynamically heterogeneous" [1]. Such heterogeneity is expected from the random first order transition theory of the glass…

Disordered Systems and Neural Networks · Physics 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N=108 to $10^4$ to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair…

Soft Condensed Matter · Physics 2007-05-23 Kang Kim , Ryoichi Yamamoto

We report a metadynamics simulation study of crystallization in a deep undercooled metallic glass-forming liquid by developing appropriate collective variables. Through a combined analysis of free energy surface (FES) and atomic-level…

Disordered Systems and Neural Networks · Physics 2020-02-25 Wen-Xiong Song , Yong Yang , Weihua Wang , Pengfei Guan

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

The dramatic slowing down of relaxation dynamics of liquids approaching the glass transition remains a highly debated problem, where the crux of the puzzle resides in the elusive increase of the activation barrier $\Delta E(T)$ with…

Soft Condensed Matter · Physics 2024-06-19 Geert Kapteijns , David Richard , Eran Bouchbinder , Thomas B. Schrøder , Jeppe C. Dyre , Edan Lerner

Using computer simulations of an atomistic glass-forming liquid, we investigate the fluctuations of the overlap between a fluid configuration and a quenched reference system. We find that large fluctuations of the overlap develop as…

Statistical Mechanics · Physics 2015-05-29 Ludovic Berthier , Robert L. Jack

A detailed experimental and theoretical study has been performed about a phenomenon, not previously reported in the literature, occurring in highly viscous liquids: the formation of a definite pipe structure induced by the passage of a…

Chemical Physics · Physics 2009-01-09 V. Capano , S. Esposito , G. Salesi

Experiments show that isochoric (constant-volume) conditions enhance supercooling stability relative to isobaric (constant-pressure) conditions. Here, combining Helmholtz equilibrium thermodynamics with a first-order perturbation…

Soft Condensed Matter · Physics 2026-04-30 Boris Rubinsky

The nature of the glass transition is theoretically understood in the mean-field limit of infinite spatial dimensions, but the problem remains totally open in physical dimensions. Nontrivial finite-dimensional fluctuations are hard to…

Statistical Mechanics · Physics 2019-04-05 Ludovic Berthier , Patrick Charbonneau , Andrea Ninarello , Misaki Ozawa , Sho Yaida