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Related papers: Theoretical overview of black phosphorus

200 papers

Amorphous red phosphorus (a-P) is one of the remaining puzzling cases in the structural chemistry of the elements. Here, we elucidate the structure, stability, and chemical bond-ing in a-P from first principles, combining machine-learning…

Materials Science · Physics 2023-06-06 Yuxing Zhou , Stephen R. Elliott , Volker L. Deringer

Thin layers of black phosphorus have recently raised interest for their two-dimensional (2D) semiconducting properties, such as tunable direct bandgap and high carrier mobilities. This lamellar crystal of P atoms stacked together by weak…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 A. Favron , E. Gaufrès , F. Fossard , P. L. Lévesque , A-L. Phaneuf-L'Heureux , N. Y-W. Tang , A. Loiseau , R. Leonelli , S. Francoeur , R. Martel

Black phosphorous is a layered material having a high capacity of 2596 mAh/g as a battery electrode, however it suffers from cracking due to high volume expansion during lithiation. These cracks causes loss of electrical contact in the…

Materials Science · Physics 2020-07-21 Burak Ozdemir

The large variety of complex electronic structure materials and their alloys, offer highly promising directions for improvements in thermoelectric (TE) power factors (PF). Their electronic structure contains rich features, referred to as…

Materials Science · Physics 2023-11-08 Patrizio Graziosi , Neophytos Neophytou

Violet phosphorus (VP), the most stable phosphorus allotrope, is a van der Waals semiconductor that can be used to construct $\textit{p}$-type nanodevices. Recently, high-quality VP crystals have been synthesized while a deep insight into…

Materials Science · Physics 2023-06-12 Zhenyu Sun , Zhihao Cai , Peng Cheng , Lan Chen , Xuewen Zhao , Jinying Zhang , Kehui Wu , Baojie Feng

Black phosphorus (BP) has recently attracted significant interest due to its unique electronic and optical properties. Doping is an effective strategy to tune a material's electronic structures, however, the direct and controllable growth…

Materials Science · Physics 2020-07-21 Mingqiang Liu , Simin Feng , Yi Hou , Shilong Zhao , Lei Tang , Jiaman Liu , Feng Wang , Bilu Liu

Optical and electronic properties of black phosphorus strongly depend on the number of layers and type of stacking. Using first-principles calculations within the framework of density functional theory, we investigate the electronic…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 Cem Sevik , John R. Wallbank , Oguz Gulseren , Francois M. Peeters , Deniz Cakır

The surface structure of phosphorene crystals materials is determined using surface sensitive dynamical micro-spot low energy electron diffraction ({\mu}LEED) analysis using a high spatial resolution low energy electron microscopy (LEEM)…

The effect of the number of stacking layers and the type of stacking on the electronic and optical properties of bilayer and trilayer black phosphorus are investigated by using first principles calcula- tions within the framework of density…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Deniz Cakir , Cem Sevik , Francois M. Peeters

Studies of polynitrogen phases are of great interest for fundamental science and for the design of novel high energy density materials. Laser heating of pure nitrogen at 140 GPa in a diamond anvil cell led to the synthesis of a polymeric…

The electronic transport in few-layer black phosphorus (FLBP) nanoribbons is studied theoretically. The system is modeled on the basis of band-structures, which have been measured recently by $\mu$-ARPES experiments. We show that the…

Mesoscale and Nanoscale Physics · Physics 2025-07-09 Jorge Alfonso Lizarraga-Brito , Armando Arciniega-Gutiérrez , Yonatan Betancur-Ocampo , Thomas Stegmann

We study the electronic and optical properties of single- and bilayer black phosphorus with shortand long-range defects by using the tight-binding propagation method. Both types of defect states are localized and induce a strong scattering…

Mesoscale and Nanoscale Physics · Physics 2015-05-12 Shengjun Yuan , A. N. Rudenko , M. I. Katsnelson

Newly fabricated monolayer phosphorene and its few-layer structures are expected to be promising for electronic and optical applications because of their finite direct band gaps and sizable but anisotropic electronic mobility. By…

Mesoscale and Nanoscale Physics · Physics 2014-06-02 Ruixiang Fei , Li Yang

Negative compressibility generated by many-body effects in 2D electronic systems can enhance gate capacitance. We observe capacitance enhancement in a newly emerged 2D layered material, atomically thin black phosphorus (BP). The…

Mesoscale and Nanoscale Physics · Physics 2016-04-05 Yingying Wu , Xiaolong Chen , Zefei Wu , Shuigang Xu , Tianyi Han , Jiangxiazi Lin , Yuan Cai , Yuheng He , Chun Cheng , Ning Wang

In this letter, we show that a new class of two-dimensional phosphorus allotropes can be constructed via assembling the previously proposed ultrathin metastable phosphorus nanotube into planar structures in different stacking orientations.…

Materials Science · Physics 2018-05-02 Zhenqing Li , Chaoyu He , Tao Ouyang , Chunxiao Zhang , Cao Tang , Rudolf A. Romer , Jianxin Zhong

We investigate the electronic properties of $N$-layer black phosphorus by means of an analytical method based on a recently proposed tight-binding Hamiltonian involving $14$ hopping parameters. The method provides simple and accurate…

Mesoscale and Nanoscale Physics · Physics 2017-10-18 D. J. P. de Souza , L. V. de Castro , D. R. da Costa , J. Milton Pereira , Tony Low

Tetragonal Mo5PB2 compound, a recently discovered superconductor, belongs to technologically important class of materials. It is quite surprising to note that a large number of physical properties of Mo5PB2, including elastic properties and…

Materials Science · Physics 2021-05-12 M. I. Naher , M. A. Afzal , S. H. Naqib

Two-dimensional layered materials have attracted tremendous attentions due to their extraordinary physical and chemical properties. Using first-principles calculations and Boltzmann transport theory, we give an accurate prediction of the…

Mesoscale and Nanoscale Physics · Physics 2019-02-13 Z. Z. Zhou , H. J. Liu , D. D. Fan , G. H. Cao , C. Y. Sheng

We explore the possibility of using van dar Waals bonded heterostructures of stacked together 2D bilayer black phosphorus (BP) for nanoscale device applications. The electronic property of BP in AA stacking and 90{\deg} twisted is studied…

Applied Physics · Physics 2018-11-09 Vivekanand Shukla , Anton Grigoriev , Rajeev Ahuja

Ballistic device performance of monolayer black phosphorous (BP) field-effect transistors (FET) is investigated in this work. Due to the anisotropic effect mass of the carriers, the ON-state current is dependent on the transport direction.…

Materials Science · Physics 2014-07-14 Kai-Tak Lam , Zhipeng Dong , Jing Guo