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An atomic-scale study utilizing scanning tunneling microscopy (STM) in ultrahigh vacuum (UHV) is performed on large single crystalline graphene grains synthesized on Cu foil by a chemical vapor deposition (CVD) method. After thermal…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 Jifa Tian , Helin Cao , Wei Wu , Qingkai Yu , Nathan P. Guisinger , Yong P. Chen

We studied the surface structures of chemical vapor deposited (CVD) graphene on Cu(103). The graphene covered Cu surface had (103) facets parallel to the Cu[010] direction, on which triangular patterns were formed. In contrast, the bare Cu…

Graphene on copper is a system of high technological relevance, as Cu is one of the most widely used substrates for the CVD growth of graphene. However, very little is known about the details of their interaction. One approach to gain such…

Materials Science · Physics 2014-08-27 P. Süle , M. Szendrő , C. Hwang , L. Tapasztó

The structure of a graphene monolayer on Ir(111) has been investigated {\it in situ} in the growth chamber by surface x-ray diffraction including the specular rod, which allows disentangling the effect of the sample roughness from that of…

Materials Science · Physics 2015-06-25 Fabien Jean , Tao Zhou , Nils Blanc , Roberto Felici , Johann Coraux , Gilles Renaud

The growth of graphene by catalytic decomposition of ethylene on Cu(111) in an ultra-high vacuum system was investigated with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. Attempts to form a…

Materials Science · Physics 2013-07-19 Zachary R. Robinson , Parul Tyagi , Tyler R. Mowll , James B. Hannon , Carl A. Ventrice

Graphene is susceptible to morphological instabilities such as wrinkles and folds, which result from the imposition of thermo-mechanical stresses upon cooling from high temperatures and/ or under biaxial loading. A particular pattern…

We have used scanning tunneling microscopy to study the structure of graphene islands on Au(111) grown by deposition of elemental carbon at 950{\deg}C. Consistent with low-energy electron microscopic observations, we find that the graphene…

In previous studies, it proved difficult to realize periodic graphene ripples with wavelengths of few nanometers. Here we show that one-dimensional periodic graphene ripples with wavelengths from 2 nm to tens of nanometers can be…

Mesoscale and Nanoscale Physics · Physics 2014-08-25 Ke-Ke Bai , Yu Zhou , Hong Zheng , Lan Meng , Hailin Peng , Zhongfan Liu , Jia-Cai Nie , Lin He

Graphene is the nature's thinnest elastic membrane, with exceptional mechanical and electrical properties. We report the direct observation and creation of one-dimensional (1D) and 2D periodic ripples in suspended graphene sheets, using…

Mesoscale and Nanoscale Physics · Physics 2009-07-28 Wenzhong Bao , Feng Miao , Zhen Chen , Hang Zhang , Wanyoung Jang , Chris Dames , Chun Ning Lau

Films of (111)-textured Cu, Ni, and Cu$_x$Ni$_y$ were evaluated as substrates for chemical vapor deposition of graphene. A metal thickness of 400 nm to 700 nm was sputtered onto a substrate of $\alpha-$Al$_2$O$_3$(0001) at temperatures of…

Materials Science · Physics 2013-05-23 David L. Miller , Mark W. Keller , Justin M. Shaw , Ann N. Chiaramonti , Robert R. Keller

Graphene is a very promising material for nanoelectronics applications due to its unique and remarkable electronic and thermal properties. However, when deposited on metallic electrodes the overall thermal conductivity is significantly…

Graphene quality indicators obtained by Raman spectroscopy have been correlated to the structural changes of the graphene/Germanium interface as a function of in-vacuum thermal annealing. Specifically, it is found that graphene becomes…

In this note, we report a Raman spectroscopy study of annealing-induced effects on graphene samples prepared by the microexfoliation method. It was shown that randomly located adhesive residues often contaminate nearby graphene sheets…

Materials Science · Physics 2011-04-19 Jieun Song , Taeg Yeoung Ko , Sunmin Ryu

We present a comprehensive study of graphene grown by chemical vapor deposition on copper single crystals with exposed (100), (110) and (111) faces. Direct examination of the as-grown graphene by Raman spectroscopy using a range of visible…

Mesoscale and Nanoscale Physics · Physics 2014-02-03 Otakar Frank , Jana Vejpravova , Vaclav Holy , Ladislav Kavan , Martin Kalbac

We report an atomically-resolved scanning tunneling microscopy (STM) investigation of the edges of graphene grains synthesized on Cu foils by chemical vapor deposition (CVD). Most of the edges are macroscopically parallel to the zigzag…

Mesoscale and Nanoscale Physics · Physics 2011-09-20 Jifa Tian , Helin Cao , Wei Wu , Qingkai Yu , Yong P. Chen

Epitaxial graphene grown on transition metal surfaces typically exhibits a moir\'e pattern due to the lattice mismatch between graphene and the underlying metal surface. We use both scanning tunneling microscopy (STM) and atomic force…

Graphene films grown by vapor deposition tend to be polycrystalline due to the nucleation and growth of islands with different in-plane orientations. Here, using low-energy electron microscopy, we find that micron-sized graphene islands on…

Chemical vapor deposition (CVD) is an important method to synthesis grapheme on a substract. Recently, Cu becomes the most popular CVD substrate for graphene growth. Here, we combine electronic structure calculation, molecular dynamics…

Materials Science · Physics 2011-09-14 Wenhua Zhang , Ping Wu , Zhenyu Li , Jinlong Yang

Graphene monolayer grown by Si evaporation from the 0001 surface of SiC displays a moir\'e pattern of corrugation whose structure is ambiguous: different measurements and theoretical studies show either protruding bumps surrounded by…

Mesoscale and Nanoscale Physics · Physics 2018-04-27 Tommaso Cavallucci , Valentina Tozzini

Graphene grown by chemical vapour deposition is transferred on top of flat gold nanoislands and characterized by scanning tunnelling microscopy (STM) and atomic force microscopy (AFM). Graphene bubbles are formed with lateral dimensions…

Mesoscale and Nanoscale Physics · Physics 2016-09-15 András Pálinkás , György Molnár , Chanyong Hwang , László Péter Biró , Zoltán Osváth
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