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Recent progress on micro- and nanometer scale manipulation has opened the possibility to probe systems small enough that thermal fluctuations of energy and coordinate variables can be significant compared with their mean behavior. We…

Mesoscale and Nanoscale Physics · Physics 2012-11-02 O. -P. Saira , Y. Yoon , T. Tanttu , M. Möttönen , D. V. Averin , J. P. Pekola

The Fluctuation Theorem and the Jarzynski equality are examined in the light of recent experimental tests. For a particle dragged through a solvent, it is shown that $Q,$ the heat exchanged with the reservoir, obeys the asymptotic…

Statistical Mechanics · Physics 2009-11-10 Onuttom Narayan , Abhishek Dhar

Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While…

Quantum Physics · Physics 2025-06-05 Hui Li , Jie Xie , Hyukjoon Kwon , Yixin Zhao , M. S. Kim , Lijian Zhang

A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…

Statistical Mechanics · Physics 2009-10-31 Satoshi Yukawa

Five previously unknown inequalities relating equilibrium free energy differences and non-equilibrium work fluctuations are derived, and lucid path to derivation of many similar inequalities is presented. These results are based upon…

Statistical Mechanics · Physics 2011-05-24 Alexander Davydov

Work is one of the most basic notion in statistical mechanics, with work fluctuation theorems being one central topic in nanoscale thermodynamics. With Hamiltonian chaos commonly thought to provide a foundation for classical statistical…

Statistical Mechanics · Physics 2017-02-01 Jiawen Deng , Alvis Mazon Tan , Peter Hanggi , Jiangbin Gong

The Jarzynski equality is a cornerstone of nonequilibrium thermodynamics, linking work statistics to equilibrium free-energy differences. Although it has been extensively verified in classical and quantum Hermitian settings, its status in…

Quantum Physics · Physics 2026-05-12 Zongru Yang , Teng Liu , Xiaodong Tan , Feng Zhu , Le Luo

Understanding and manipulating work fluctuations in microscale and nanoscale systems are of both fundamental and practical interest. For example, in considering the Jarzynski equality $\langle e^{-\beta W} \rangle=e^{-\beta \Delta F}$, a…

Statistical Mechanics · Physics 2015-08-26 Gaoyang Xiao , Jiangbin Gong

We formulate a statistical model of two sequential measurements and prove a so-called J-equation that leads to various diversifications of the well-known Jarzynski equation including the Crooks dissipation theorem. Moreover, the J-equation…

Quantum Physics · Physics 2020-03-18 Heinz-Jürgen Schmidt , Jochen Gemmer

We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data…

Statistical Mechanics · Physics 2018-08-01 Naoto Tsuji , Masahito Ueda

We derive exact fluctuation equalities for open systems that recover free energy differences between two equilibrium endpoints connected by nonequilibrium processes with arbitrary dynamics and coupling. The exponential of the free energy…

Statistical Mechanics · Physics 2025-12-15 Mohammad Rahbar , Christopher J. Stein

A quantum fluctuation theorem for a driven quantum subsystem interacting with its environment is derived based solely on the assumption that its reduced density matrix obeys a closed evolution equation i.e. a quantum master equation (QME).…

Statistical Mechanics · Physics 2010-03-01 Massimiliano Esposito , Shaul Mukamel

In this work, I derive the time-dependent probability density function of classical observables using the Hamiltonian mechanics approach, extending the notion of fluctuation theorems for any observables. In particular, the time-dependent…

Statistical Mechanics · Physics 2023-10-13 Pierre Nazé

A central topic in the emerging field of quantum thermodynamics is the definition of thermodynamic work in the quantum regime. One widely used solution is to define work for a closed system undergoing non-equilibrium dynamics according to…

Quantum Physics · Physics 2017-06-16 Harry J. D. Miller , Janet Anders

In the derivation of fluctuation relations, and in stochastic thermodynamics in general, it is tacitly assumed that we can measure the system perfectly, i.e., without measurement errors. We here demonstrate for a driven system immersed in a…

Statistical Mechanics · Physics 2016-11-30 C. W. Wächtler , P. Strasberg , T. Brandes

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

Fluctuation theorems are relations constraining the out-of-equilibrium fluctuations of thermodynamic quantities like the entropy production that were initially introduced for classical or quantum systems in contact with a thermal bath. Here…

Quantum Physics · Physics 2019-02-27 Sreenath K. Manikandan , Cyril Elouard , Andrew N. Jordan

We derive the differential equation describing the time evolution of the work probability distribution function of a stochastic system which is driven out of equilibrium by the manipulation of a parameter. We consider both systems described…

Statistical Mechanics · Physics 2007-05-23 A. Imparato , L. Peliti

Two-state models provide phenomenological descriptions of many different systems, ranging from physics to chemistry and biology. We investigate work fluctuations in an ensemble of two-state systems driven out of equilibrium under the action…

Statistical Mechanics · Physics 2009-11-10 F. Ritort

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo