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Designing lithium-ion batteries for long service life remains a challenge, as most cells are optimized for beginning-of-life metrics such as energy density, often overlooking how design and operating conditions shape degradation. This work…

Understanding battery degradation in electric vehicles (EVs) under real-world conditions remains a critical yet under-explored area of research. Central to this investigation is the challenge of estimating the specific degradation modes in…

Optimization and Control · Mathematics 2024-05-20 Raja Abhishek Appana , Faissal El Idrissi , Prashanth Ramesh , Marcello Canova , Chun Yong Kang , Kimoon Um

As an anode material for lithium-ion batteries, amorphous silicon offers a significantly higher energy density than the graphite anodes currently used. Alloying reactions of lithium and silicon, however, induce large deformation and lead to…

Numerical Analysis · Mathematics 2024-08-07 Raphael Schoof , Johannes Niermann , Alexander Dyck , Thomas Böhlke , Willy Dörfler

A data-driven solution is provided for the fast-charging problem of lithium-ion batteries with multiple safety and aging constraints. The proposed method optimizes the charging current based on the observed history of measurable battery…

Systems and Control · Electrical Eng. & Systems 2024-05-20 Hamed Taghavian , Malin Andersson , Mikael Johansson

The properties of rechargeable lithium-ion batteries are determined by the electrochemical and kinetic properties of their constituent materials as well as by their underlying microstructure. Microstructural design can be leveraged to…

Materials Science · Physics 2022-03-11 Giovanna Bucci , Tushar Swamy , W. Craig Carter , Morad Behandish

Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a…

Systems and Control · Electrical Eng. & Systems 2021-06-25 Anirudh Allam , Simona Onori

Lithium-ion technologies are increasingly employed to electrify transportation and provide stationary energy storage for electrical grids, and as such their development has garnered much attention. However, their deployment is still…

Physics and Society · Physics 2021-04-26 Micah S. Ziegler , Jessika E. Trancik

Accurate modeling of lithium ion (li-ion) batteries is essential for enhancing the safety, and efficiency of electric vehicles and renewable energy systems. This paper presents a data-inspired approach for improving the fidelity of…

Systems and Control · Electrical Eng. & Systems 2024-11-21 Samuel Filgueira da Silva , Mehmet Fatih Ozkan , Faissal El Idrissi , Prashanth Ramesh , Marcello Canova

Battery degradation, which is the reduction of performance over time, is one of the main roadblocks to the wide deployment of lithium-ion batteries. Physics-based models, such as those based on the Doyle-Fuller-Newman model, are invaluable…

Chemical Physics · Physics 2023-06-06 Ferran Brosa Planella , W. Dhammika Widanage

Accurately predicting the lifespan of lithium-ion batteries is crucial for optimizing operational strategies and mitigating risks. While numerous studies have aimed at predicting battery lifespan, few have examined the interpretability of…

Machine Learning · Computer Science 2024-04-12 Jaewook Lee , Seongmin Heo , Jay H. Lee

Electrochemical devices often consist of multicomponent electrolyte solutions. Two processes influence the overall dynamics of these devices: the formation of electrical double layers and chemical conversion due to redox reactions. However,…

Chemical Physics · Physics 2022-06-20 Nathan Jarvey , Filipe Henrique , Ankur Gupta

Capacity degradation of lithium-ion batteries under long-term cyclic aging is modelled via a flexible sigmoidal-type regression set-up, where the regression parameters can be interpreted. Different approaches known from the literature are…

Applications · Statistics 2019-07-31 Marcus Johnen , Simon Pitzen , Udo Kamps , Maria Kateri , Dirk Uwe Sauer

We review recent ab initio molecular dynamics studies of electrode/electrolyte interfaces in lithium ion batteries. Our goals are to introduce experimentalists to simulation techniques applicable to models which are arguably most faithful…

Materials Science · Physics 2013-04-23 Kevin Leung

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

We study two thermo-electrochemical models for lithium-ion batteries. The first is based on volume averaging the electrode microstructure whereas the second is based on the pseudo-two-dimensional (P2D) approach which treats the electrode as…

Applied Physics · Physics 2019-07-08 Matthew G. Hennessy , Iain R. Moyles

Mathematical modeling of lithium-ion batteries (LiBs) is a primary challenge in advanced battery management. This paper proposes two new frameworks to integrate physics-based models with machine learning to achieve high-precision modeling…

Computational Engineering, Finance, and Science · Computer Science 2024-08-23 Hao Tu , Scott Moura , Yebin Wang , Huazhen Fang

We propose a dynamical theory of how the chemical energy stored in a battery generates the electromotive force (emf). In this picture, the battery's half-cell acts as an engine, cyclically extracting work from its underlying chemical…

Chemical Physics · Physics 2021-04-23 Robert Alicki , David Gelbwaser-Klimovsky , Alejandro Jenkins , Elizabeth von Hauff

Charge unbalance is one of the key issues for series-connected Lithium-ion cells. Within this context, model-based optimization strategies have proven to be the most effective. In the present paper, an ad-hoc electrochemical model, tailored…

Systems and Control · Computer Science 2019-02-07 Andrea Pozzi , Massimo Zambelli , Antonella Ferrara , Davide Martino Raimondo

Lithium-ion batteries (LIBs) of high energy density and light-weight design, have found wide applications in electronic devices and systems. Degradation mechanisms that caused by lithiation is a main challenging problem for LIBs with high…

Computational Engineering, Finance, and Science · Computer Science 2020-06-26 Masoud Ahmadi

The correct assessment of battery states is essential to maximize battery pack performances while ensuring reliable and safe operation. This work introduces EIS2MOD, a novel modelling framework for Li-ion cells based on Distribution of…

Systems and Control · Electrical Eng. & Systems 2022-03-17 Pietro Iurilli , Claudio Brivio , Rafael E. Carrillo , Vanessa Wood