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We have performed ab-initio band structure calculations on more than two thousand half-Heusler compounds in order to search for new candidates for topological insulators. Herein, LiAuS and NaAuS are found to be the strongest topological…

Materials Science · Physics 2015-08-17 Shi-Yuan Lin , Xiao-Bao Yang , Yu-Jun Zhao , Shu-Chun Wu , Claudia Felser , Binghai Yan

We assessed four exchange-correlation functionals (LDA CA-PZ, GGA parametrized by PBE, PBEsol, and WC) in predicting the lattice parameters of SrTi$_{1-\mathit{x}}$Mn$_{\mathit{x}}$O$_{3}$ perovskites, assuming cubic structures. Predictions…

We assess the performance of recent density functionals for the exchange-correlation energy of a nonmolecular solid, by applying accurate calculations with the GAUSSIAN, BAND, and VASP codes to a test set of 24 solid metals and non-metals.…

Fe$_{2}$VAl and Fe$_{2}$TiSn are full Heusler compounds with non-magnetic ground state. The two compouds are good thermoelectric materials. PBE and LDA(PW92) are the two most commonly used density functionals to study the Heusler compounds.…

Strongly Correlated Electrons · Physics 2017-08-04 Shivprasad S. Shastri , Sudhir K. Pandey

We have performed density functional calculations using a range of local and semi-local as well as hybrid density functional approximations of the structure and elastic constants of 18 semiconductors and insulators. We find that most of the…

Materials Science · Physics 2015-10-12 M. Råsander , M. A. Moram

The bulk properties (lattice constants, bulk moduli, and cohesive energies) of alkali, alkaline-earth, and transition metals are studied within the framework of the recently developed meta-GGA (meta-Generalized Gradient Approximation)…

Materials Science · Physics 2018-11-14 Subrata Jana , Kedar Sharma , Prasanjit Samal

Electronic correlations are crucial to the low energy physics of metallic systems with localized $d$ and $f$ states; however, their effect on band insulators and semiconductors is typically negligible. Here, we measure the electronic…

Taking into considerations the wide compositional stretch of Heusler alloys, the first principles density functional theory based calculations are excellently suitable for estimating the multifaceted properties of alkali metal based LiVSb…

Materials Science · Physics 2024-07-03 Diwaker , Shyam L. Gupta , Anupam , Sumit Kumar , Aadil Fayaz , Ashwani Kumar

We test the accuracy of the revised Perdew-Burke-Ernzerhof exchange-correlation density functional (PBEsol) for metallic bulk and surface systems. It is shown that, on average, PBEsol yields equilibrium volumes and bulk moduli in close…

Materials Science · Physics 2009-11-13 M. Ropo , K. Kokko , L. Vitos

An alternative type of approximation for the exchange and correlation functional in density functional theory is proposed. This approximation depends on a variable $u$ that is able to detect inhomogeneities in the electron density $\rho$…

Materials Science · Physics 2019-01-02 Fabien Tran , Peter Blaha

We systematically investigate the topological band structures of half-Heusler compounds using first-principles calculations. The modified Becke-Johnson exchange potential together with local density approximation for the correlation…

Materials Science · Physics 2011-01-28 Wanxiang Feng , Di Xiao , Ying Zhang , Yugui Yao

We assess the validity of various exchange-correlation functionals for computing the structural, vibrational, dielectric, and thermodynamical properties of materials in the framework of density-functional perturbation theory (DFPT). We…

We present theoretical and experimental results exploring a half-Heusler compound TmPdSb with unusual band order and metallic surface states. Typically, the half-Heusler systems exhibit topological features in a semimetallic state, and…

Materials Science · Physics 2025-04-29 Shovan Dan , Andrzej Ptok , Orest Pavlosiuk , Karan Singh , Piotr Wiśniewski , Dariusz Kaczorowski

Following Hollins et al. [J. Phys.: Condens. Matter 29, 04LT01 (2017)], we invert the electronic ground state densities for various semiconducting and insulating solids calculated using several density functional approximations within the…

Chemical Physics · Physics 2025-11-05 Visagan Ravindran , Nikitas I. Gidopoulos , Stewart J. Clark

Density functional theory augmented with Hubbard-$U$ corrections (DFT+$U$) is currently one of the widely used methods for first-principles electronic structure modeling of insulating transition metal oxides (TMOs). Since $U$ is relatively…

Computational Physics · Physics 2018-05-09 Samara Keshavarz , Johan Schött , Andrew J. Millis , Yaroslav O. Kvashnin

First-principles calculation has led to significant discoveries in materials science. Half heusler (HH) alloys, which are potential thermoelectric materials have demonstrated significant improvements in thermoelectric performance owing to…

Materials Science · Physics 2022-04-11 Lynet Allan , Winfred M. Mulwa , Robinson J. Musembi , Bernard O. Aduda

We have performed accurate ab initio total energy calculations using the full-potential linearized augmented plane wave (FP-LAPW) method with the generalized gradient approximation (GGA) for the exchange-correlation potential to…

Materials Science · Physics 2009-11-13 I. R. Shein , A. L. Ivanovskii

First-principles calculations using the plane-wave pseudopotential method within the generalized gradient approximation method were performed to study the pressure dependence of the structural, elastic, electronic and optical properties for…

Materials Science · Physics 2021-12-21 M. Radjai , A. Bouhemadou , D. Maouche

The alloys with 8/18/24 valence electron count (VEC) are promising candidates for efficient energy conversion and refrigeration applications at low as well as high temperatures. The full potential linearized augmented plane wave method as…

Materials Science · Physics 2022-05-17 Mukesh K. Choudhary , H. Fjellvåg , P. Ravindran

By carefully choosing parameters and including more semi-core orbitals as valence electrons, we have constructed a high quality projected augmented wave (PAW) dataset that yields results comparable to existing full-potential linearized…

Strongly Correlated Electrons · Physics 2010-12-30 Chao Cao , Yu-ning Wu , Rashid Hamdan , Yun-Peng Wang , Hai-Ping Cheng
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