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Metal-support interactions are frequently invoked to explain the enhanced catalytic activity of metal nanoparticles dispersed over reducible metal-oxide supports, yet the atomic scale mechanisms are rarely known. Here, we use scanning…

Perovskite yttrium tantalum oxynitride is theoretically proposed as a promising semiconductor for solar water splitting because of the predicted bandgap and energy positions of band edges. In experiment, however, we show here that depending…

Methane (CH4) formation from photocatalytic carbon dioxide (CO2) conversion in water is currently of interest because methane is a fuel, and it can also be transformed into other useful hydrocarbons. However, achieving high selectivity to…

Materials Science · Physics 2025-03-21 Jacqueline Hidalgo-Jiménez , Taner Akbay , Xavier Sauvage , Tatsumi Ishihara , Kaveh Edalati

We present a general fabrication strategy for freestanding single-crystalline complex oxide device arrays via wet chemical etching-based microfabrication processes and epitaxial lift-off. Here, we used…

Green hydrogen production is crucial for a sustainable future, but current catalysts for the oxygen evolution reaction (OER) suffer from slow kinetics, despite many efforts to produce optimal designs, particularly through the calculation of…

Dissolution of electrocatalysts during long-term and dynamic operation is a challenging problem in energy conversion and storage devices such as fuel cells and electrolyzers. To develop stable electrocatalysts, we adopt the design concept…

High-entropy materials have emerged as a promising class of catalysts, driven by their high configurational entropy originating from structural disorder in single-phase multicomponent systems. Despite their potential, the catalytic…

Materials Science · Physics 2025-12-23 Anjali Varshney , Aishwery J. Verma , Ritesh Dubey , Sushil Kumar , Tapas Goswami , Samar Layek

Recently, hydrogen generation by water-splitting photocatalysts is attracting attention as a sustainable and clean energy resource. Photocatalytic hydrogen-generation systems are much simpler, cheaper, and easier to scale up than the…

Chemical Physics · Physics 2022-06-28 Tatsuo Suzuki

Lithium-rich antiperovskite promise to be a compelling high-capacity cathode material due to existence of both cationic and anionic redox activity. Little is however known about the effect of separating the electrochemical cationic from the…

Heterogeneous catalysts based on sub-nanometer metal clusters often exhibit strongly size-dependent properties, and the addition or removal of a single atom can make all the difference. Identifying the most active species and deciphering…

Freestanding perovskite oxide membranes have drawn great attention recently since they offer exceptional structural tunability and stacking ability, providing new opportunities in fundamental research and potential device applications in…

Materials Science · Physics 2023-07-28 Leyan Nian , Haoying Sun , Zhichao Wang , Duo Xu , Hao Bo , Shengjun , Yan , Yueying Li , Jian Zhou , Yu Deng , Yufeng Hao , Yuefeng Nie

Nanoporous graphitic carbon membranes with defined chemical composition and pore architecture are novel nanomaterials that are actively pursued. Compared to easy-to-make porous carbon powders that dominate the porous carbon research and…

Efficient and selective CO2 electroreduction into value-added chemicals and fuels emerged as a significant approach for CO2 conversion, however, it relies on catalysts with controllable product selectivity and reaction paths. In this work,…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Wei Xun , Xiao Yang , Qing-Song Jiang , Ming-Jun Wang , Yin-Zhong Wu , Ping Li

High quality metal thin films and nanostructures are critical building blocks for next generation nanotechnologies. They comprise low-loss circuit elements in nanodevices, provide new catalytic pathways for water splitting and $CO_2$…

Applied Physics · Physics 2019-06-20 Sasan V. Grayli , Xin Zhang , Finlay C. MacNab , Saeid Kamal , Gary W. Leach

It is widely accepted that self-assembling building blocks is one of the promising ways for engineering new materials. Recent years reveal substantial progress in fabricating colloidal particles, polymer blocks and supramolecular aggregates…

Materials Science · Physics 2007-05-23 N. Berdunov , G. Mariotto , K. Balakrishnan , I. V. Shvets

Electrocatalytic CO2 reduction technology is key to mitigating greenhouse gas emissions and the energy crisis. However, controlling the selectivity of CO2RR products at low overpotential remains a challenge. In this paper, we predicted five…

Materials Science · Physics 2024-03-05 Ran Wang , Chaozheng He , Weixing Chen , Qingquan Kong , Thomas Frauenheimac

The discovery and design of new materials are paramount in the development of green technologies. High entropy oxides represent one such group that has only been tentatively explored, mainly due to the inherent problem of navigating vast…

Janus type Water-Splitting Catalysts have attracted highest attention as a tool of choice for solar to fuel conversion. AISI Ni 42 steel was upon harsh anodization converted in a bifunctional electrocatalyst. Oxygen evolution reaction-…

Atomic-scale investigations of metal oxide surfaces exposed to aqueous environments are vital to understand degradation phenomena (e.g. dissolution and corrosion) as well as the performance of these materials in applications. Here, we…

Critical to the development of improved solid oxide fuel cell (SOFC) technology are novel compounds with high oxygen reduction reaction (ORR) catalytic activity and robust stability under cathode operating conditions. Approximately 2145…

Materials Science · Physics 2019-01-10 Ryan Jacobs , Tam Mayeshiba , John Booske , Dane Morgan
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