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The Metal-Insulator transition (MIT) in VO2 is characterized by the complex interplay among lattice, electronic and orbital degrees of freedom. In this contribution we investigated the strain-modulation of the orbital hierarchy and the…

The optical/infrared properties of films of vanadium dioxide (VO2) and vanadium sesquioxide (V2O3) have been investigated via ellipsometry and near-normal incidence reflectance measurements from far infrared to ultraviolet frequencies.…

Strongly Correlated Electrons · Physics 2009-11-13 M. M. Qazilbash , A. A. Schafgans , K. S. Burch , S. J. Yun , B. G. Chae , B. J. Kim , H. T. Kim , D. N. Basov

The effect of electron correlation (EC) on the electronic structure in MgB$_2$, AlB$_2$ and ZrB$_2$, is studied by examining the partial density of states (PDOS) of B-2$p\sigma$ and $p\pi$ orbitals using the polarization dependence of x-ray…

Correlated oxides, such as BiMnO$_3$ and LaMnO$_3$, show complex interplay of electronic correlations and crystal structure exhibiting multiple first order phase transitions, some without a clear order parameter. The quantitative…

Strongly Correlated Electrons · Physics 2022-12-12 Gheorghe Lucian Pascut , Kristjan Haule

We present cluster-DMFT (CTQMC) calculations based on a downfolded tight-binding model in order to study the electronic structure of vanadium dioxide (VO_2) both in the low-temperature (M_1) and high-temperature (rutile) phases. Motivated…

Strongly Correlated Electrons · Physics 2015-05-18 Bence Lazarovits , Kyoo Kim , Kristjan Haule , Gabriel Kotliar

We studied the changes in the electronic structure of V2O3 using a cluster model. The calculations included fluctuations from the coherent band in the metallic phase, and non-local Mott-Hubbard fluctuations in the insulating phase. The…

Strongly Correlated Electrons · Physics 2015-06-25 R. J. O. Mossanek , M. Abbate

The interplay of Coulomb and electron-phonon interactions with thermal and quantum fluctuations facilitates rich phase diagrams in two-dimensional electron systems. Layered transition metal dichalcogenides hosting charge, excitonic, spin…

Strongly Correlated Electrons · Physics 2018-07-03 E. G. C. P. van Loon , M. Rösner , G. Schönhoff , M. I. Katsnelson , T. O. Wehling

We investigate the electronic and structural changes at the nanoscale in vanadium dioxide (VO2) in the vicinity of its thermally driven phase transition. Both electronic and structural changes exhibit phase coexistence leading to…

Density functional electronic structure studies of tetragonal PbVO$_3$ are reported. The results show a an important role for both Pb 6$p$ - O 2$p$ and V $d$ - O $p$ bonding, with an interplay between these. This is discussed in relation to…

Materials Science · Physics 2009-11-11 D. J. Singh

The metal-insulator transition in VO2 was investigated using the three-band Hubbard model, in which the degeneracy of the 3d orbitals, the on-site Coulomb and exchange interactions, and the effects of lattice distortion were considered. A…

Condensed Matter · Physics 2009-11-10 Arata Tanaka

Layered van der Waals materials are exciting as they often host multiple, competing electronic phases. This article reports experimental observation of the co-existence of insulating and metallic phases deep within the commensurate charge…

Mesoscale and Nanoscale Physics · Physics 2021-12-23 Sruthi S , Hemanta Kumar Kundu , Prasad Vishnubhotla , Aveek Bid

The effect of electronic correlations on the orbital magnetization in real materials has not been explored beyond a static mean-field level. Based on the dynamical mean-field theory, the effect of electronic correlations on the orbital…

Strongly Correlated Electrons · Physics 2021-01-27 Zhimou Zhou , Shishir Kumar Pandey , Ji Feng

We describe the ground- and excited-state electronic structure of bulk MnO and NiO, two prototypical correlated electron materials, using coupled cluster theory with single and double excitations (CCSD). As a corollary, this work also…

Electrons in correlated insulators are prevented from conducting by Coulomb repulsion between them. When an insulator-to-metal transition is induced in a correlated insulator by doping or heating, the resulting conducting state can be…

Electronic band structures usually remain unaffected by doping via a chemical-potential shift or by increasing the temperature in conventional band insulators. In contrast, it has been shown that those of Mott and Kondo insulators can be…

Strongly Correlated Electrons · Physics 2025-12-05 Masanori Kohno

The electronic structure of Nickel dichalcogenides, NiS$_2$ and NiSe$_2$, in monolayer form, is studied employing first-principles methods. We assess the importance of band ordering, covalency and Coulomb interactions in the ground state of…

Mesoscale and Nanoscale Physics · Physics 2023-12-19 Sergio Bravo , P. A. Orellana , L. Rosales

Based on first-principles calculations, we explored the interplay between stacking effect and electron-electron correlation in the layered vdW material of bulk 1T-NbS2 with a 2D charge density wave (CDW) order. Without considering the…

Strongly Correlated Electrons · Physics 2022-01-19 Wei Wang , Chen Si , Wen Lei , Feng Xiao , Yunhui Liu , Carmine Autieri , Xing Ming

Bulk MnBi$_2$Te$_4$ (MBT) is an intrinsic antiferromagnetic topological insulator. However, its low N\'eel temperature of $\sim 25\,\mathrm{K}$ severely restricts its practical applications. Here, we propose a van der Waals heterostructure…

Materials Science · Physics 2025-08-12 Yuanhao Zhu , Xixi Yuan , Ying Zhao , Jin Zhang , Zijing Ding , Huixia Fu

Comparison is made of the electronic structure of the little-studied layered transition metal oxide LiNbO$_2$ with that of Na$_x$CoO$_2$, which has attracted tremendous interest since superconductivity was discovered in its hydrate.…

Superconductivity · Physics 2007-05-23 E. R. Ylvisaker , K. -W. Lee , W. E. Pickett

LDA+DMFT method in the framework of the iterative perturbation theory (IPT) with full LDA Hamiltonian without mapping onto the effective Wannier orbitals. We then apply this LDA+DMFT method to ferromagnetic bcc-Fe and fcc-Ni as a test of…

Strongly Correlated Electrons · Physics 2008-09-26 Oki Miura , Takeo Fujiwara