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Ferrovalley materials with spontaneous valley polarization are crucial to valleytronic application. Based on first-principles calculations, we demonstrate that two-dimensional (2D) YX$_2$(X= I, Br,and Cl) in 2H structure constitute a series…

Materials Science · Physics 2022-02-17 Wen-Yu Liu , Bo Huang , Xu-Cai Wu , Shu-Zong Li , Hongxing Li , Zhixiong Yang , Wei-Bing Zhang

Coexistence of intrinsic ferromagnetism and piezoelectricity, namely piezoelectric ferromagnetism (PFM), is crucial to advance multifunctional spintronic technologies. In this work, we demonstrate that Janus monolayer YBrI is a PFM, which…

Materials Science · Physics 2023-01-04 San-Dong Guo , Meng-Xia Wang , Yu-Ling Tao , Bang-Gui Liu

Recent advances in the synthesis of polar molecular materials have produced practical alternatives to ferroelectric ceramics, opening up exciting new avenues for their incorporation into modern electronic devices. However, in order to…

In this Letter, a tunable valley polarization is investigated for honeycomb systems with broken inversion symmetry such as transition-metal dichalcogenide MX2 (M = Mo, W; X = S, Se) monolayers through elliptical pumping. As compared to…

Mesoscale and Nanoscale Physics · Physics 2014-11-26 Zhigang Song , Ruge Quhe , Yan Li , Ji Feng , Jing Lu , Jinbo Yang

We develop a theory of circular photogalvanic effect in non-gyrotropic two-dimensional transition metal dichalcogenide monolayers under interband optical transitions. Oblique incidence of circularly-polarized electromagnetic field or normal…

Mesoscale and Nanoscale Physics · Physics 2021-08-18 M. V. Entin , V. M. Kovalev

Vertically stacked layers derived from non-ferroelectric monolayers offer a promising route to two-dimensional (2D) ferroelectrics, where polarization switching occurs via interlayer sliding at sub-unit cell scales. Here, we develop a…

Materials Science · Physics 2025-03-03 Byeoksong Lee , Minki Lee , Joongoo Kang

Although multiferroics have undergone extensive examination for several decades, the occurrence of ferroelectricity induced by orbital order is only scarcely documented. In this study, we propose the existence of spontaneous ferroelectric…

Materials Science · Physics 2025-01-07 Xiao-Feng Luo , Xu He , Rui Wang , Hongjun Xiang , Jin-Zhu Zhao

In this work, we use density functional theory calculations to demonstrate how spontaneous electric polarizations can be induced \textit{via} a hybrid improper ferroelectric mechanism in iodide perovskites, a family well-known to display…

Materials Science · Physics 2018-06-27 Joshua Young , James M. Rondinelli

A crystalline solid is a periodic sequence of identical cells, each containing one or more atoms. If the constituting unit cell is not centrosymmetric, charge may distribute unevenly between the atoms, resulting in internal electric…

Two-dimensional materials that exhibit spontaneous electric polarization are of notable interest for functional materials. However, despite many two-dimensional polar materials are predicted in theory, the number of experimentally confirmed…

Materials Science · Physics 2020-11-04 Weiwei Gao , James R Chelikowsky

Ferroelectricity and metallicity are usually believed not to coexist because conducting electrons would screen out static internal electric fields. In 1965, Anderson and Blount proposed the concept of 'ferroelectric metal', however, it is…

Materials Science · Physics 2020-09-22 Xing-Yu Ma , Hou-Yi Lyu , Kuan-Rong Hao , Yi-Ming Zhao , Xiaofeng Qian , Qing-Bo Yan , Gang Su

Achieving multiferroic two-dimensional (2D) materials should enable numerous functionalities in nanoscale devices. Until now, however, predicted 2D multiferroics are very few and with coexisting yet only loosely coupled (type-I)…

Materials Science · Physics 2019-07-11 Jun-Jie Zhang , Linfang Lin , Yang Zhang , Menghao Wu , Boris I. Yakobson , Shuai Dong

In conventional ferroelectric materials, polarization is an intrinsic property limited by bulk crystallographic structure and symmetry. Recently, it has been demonstrated that polar order can also be accessed using inherently non-polar van…

Single layers of transition metal dichalcogenides are two-dimensional direct bandgap semiconductors with degenerate, but inequivalent, `valleys' in the electronic structure that can be selectively excited by polarized light. Coherent…

Materials Science · Physics 2017-07-21 Yen-Jung Chen , Jeffrey D. Cain , Teodor K. Stanev , Vinayak P. Dravid , Nathaniel P. Stern

Two-dimensional (2D) ferroelectric semiconductors present opportunities for integrating ferroelectrics into high-density ultrathin nanoelectronics. Among the few synthesized 2D ferroelectrics, $\alpha$-In$_2$Se$_3$, known for its…

Materials Science · Physics 2024-02-29 Liyi Bai , Changming Ke , Zhongshen Luo , Tianyuan Zhu , Lu You , Shi Liu

Valley, the energy extrema in the electronic band structure at momentum space, is regarded as a new degree of freedom of electrons, in addition to charge and spin. The studies focused on valley degree of freedom now form an emerging field…

Materials Science · Physics 2020-02-13 He Hu , Wen-Yi Tong , Yu-Hao Shen , Xiangang Wan , Chun-Gang Duan

The remarkable advances achieved in two-dimensional materials are now being directly transposed to low-dimensional oxides. Here we show using first-principles-based atomistic simulations that ultrathin freestanding ferroelectric layers host…

Materials Science · Physics 2026-04-28 Franco N. Di Rino , Tim Verhagen

Two-dimensional (2D) ferroelectricity has attracted extensive attention since its discovery in the monolayers of van der Waals materials. Here we show that 2D ferroelectricity induced by octahedral rotation distortion is widely present in…

Materials Science · Physics 2022-02-11 Ying Zhou , Shuai Dong , Changxun Shan , Ke Ji , Junting Zhang

Modern electronic devices heavily rely on the accurate control of charge and spin of electrons. The emergence of controllable valley degree of freedom brings new possibilities and presents a promising prospect towards valleytronics.…

Tunable polarization over a wide spectral range is a required feature of light sources employed to investigate the properties of local symmetry in both condensed and low-density matter. Among new-generation sources, free-electron lasers…

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