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Using molecular beam epitaxy (MBE) to grow multi-elemental oxides (MEO) is generally challenging, partly due to difficulty in stoichiometry control. Occasionally, if one of the elements is volatile at the growth temperature, stoichiometry…

Materials Science · Physics 2022-11-08 Gaurab Rimal , Alessandro R. Mazza , Matthew Brahlek , Seongshik Oh

We report on the growth of epitaxial Sr2RuO4 films using a hybrid molecular beam epitaxy approach in which a volatile precursor containing RuO4 is used to supply ruthenium and oxygen. The use of the precursor overcomes a number of issues…

Materials Science · Physics 2017-10-05 Patrick B. Marshall , Honggyu Kim , Kaveh Ahadi , Susanne Stemmer

Molecular beam epitaxy enables the growth of thin film materials with novel properties and functionalities. Typically, the lattice constants of films and substrates are designed to match to minimise disorders and strains. However,…

In designing material functionalities for transition metal oxides, lattice structure and d-orbital occupancy are key determinants. However, the modulation of these two factors is inherently limited by the need to balance thermodynamic…

The epitaxial growth of complex oxides enables the production of high-quality films, yet substrate choice is restricted to certain symmetry and lattice parameters, thereby limiting the technological applications of epitaxial oxides. In…

Molecular beam epitaxy is one of the highest quality growth methods, capable of achieving theoretical material property limits and unprecedented device performance. However, such ultimate quality usually comes at the cost of painstaking…

Materials Science · Physics 2024-01-15 Stephen Schaefer , Davi Febba , Kingsley Egbo , Glenn Teeter , Andriy Zakutayev , Brooks Tellekamp

Pulsed Laser Deposition in molecular-beam epitaxy environment (Laser-MBE) has been used to grow high quality BaCuOx/CaCuO2 superlattices. In situ Reflection High Energy Electron Diffraction (RHEED) shows that the growth mechanism is…

Properties of complex oxide thin films can be tuned over a range of values as a function of mismatch, composition, orientation, and structure. Here, we report a strategy for growing structured epitaxial thermoelectric thin films leading to…

Materials Science · Physics 2013-10-08 D. Pravarthana , O. I. Lebedev , D. Chateigner , S. Hebert , P. A. Salvador , W. Prellier

We show that reflection high-energy electron diffraction (RHEED) can be used as a highly sensitive tool to track surface and resulting film stoichiometry in adsorption-limited molecular beam epitaxy of (001) SrTiO3 thin films. Even under…

Materials Science · Physics 2015-03-17 Adam P. Kajdos , Susanne Stemmer

During layer-by-layer homoepitaxial growth, both the Reflection High-Energy Electron Diffraction (RHEED) intensity and the x-ray reflection intensity will oscillate, and each complete oscillation indicates the addition of one monolayer of…

Materials Science · Physics 2015-05-19 M. C. Sullivan , M. J. Ward , Araceli Gutierrez-Llorente , Eli R. Adler , H. Joress , A. Woll , J. D. Brock

The development of high-performance photocathodes is a key challenge for future accelerator and particle physics applications. In this paper photocathode growth through molecular beam epitaxy is introduced as a promising technique to obtain…

Instrumentation and Detectors · Physics 2013-10-11 Junqi Xie , Marcel Demarteau , Robert Wagner

High temperatures promote kinetic processes which can drive crystal synthesis towards ideal thermodynamic conditions, thereby realizing samples of superior quality. While accessing very high temperatures in thin-film epitaxy is becoming…

Materials Science · Physics 2024-11-06 Jeong Rae Kim , Sandra Glotzer , Adrian Llanos , Salva Salmani-Rezaie , Joseph Falson

Understanding fundamental properties of materials is necessary for all modern electronic technologies. Toward this end, the fabrication of new ultrapure thin film materials is critical to discover and understand novel properties that can…

Molecular-beam epitaxy (MBE) provides a simple but powerful way to synthesize large-area high-quality thin films and heterostructures of a wide variety of materials including accomplished group III-V and II-VI semiconductors as well as…

Materials Science · Physics 2017-09-12 Masaki Nakano , Yue Wang , Yuta Kashiwabara , Hideki Matsuoka , Yoshihiro Iwasa

We present time-resolved high energy x-ray diffraction (tr-HEXRD), time-resolved hard x-ray photoelectron spectroscopy (tr-HAXPES) and time-resolved grazing incidence small angle x-ray scattering (tr-GISAXS) data of the reactive molecular…

We report growth of superconducting Sr2RuO4 films by oxide molecular beam epitaxy (MBE). Careful tuning of the Ru flux with an electron beam evaporator enables us to optimize growth conditions including the Ru/Sr flux ratio and also to…

Superconductivity · Physics 2019-03-21 M. Uchida , M. Ide , H. Watanabe , K. S. Takahashi , Y. Tokura , M. Kawasaki

In this work we investigate the growth of $\beta$-Ga2O3 homoepitaxial layers on top of (100) oriented substrates via indium-assisted metal exchange catalyzed molecular beam epitaxy (MEXCAT-MBE) which have exhibited prohibitively low growth…

Materials Science · Physics 2020-12-21 Piero Mazzolini , Andreas Falkenstein , Zbigniew Galazka , Manfred Martin , Oliver Bierwagen

(001)-oriented thin films of the three-dimensional Dirac semimetal cadmium arsenide can realize a quantum spin Hall insulator and other kinds of topological physics, all within the flexible architecture of epitaxial heterostructures. Here,…

Materials Science · Physics 2019-04-02 David A. Kealhofer , Honggyu Kim , Timo Schumann , Manik Goyal , Luca Galletti , Susanne Stemmer

The Pd, and Pt based ABO2 delafossites are a unique class of layered, triangular oxides with 2D electronic structure and a large conductivity that rivals the noble metals. Here, we report successful growth of the metallic delafossite PdCoO2…

The growth of wafer-scale van der Waals (vdW) thin films and heterostructures by molecular beam epitaxy (MBE) is important for future applications in quantum technologies, next generation optoelectronic devices, and fundamental physics…

Materials Science · Physics 2025-08-13 Qihua Zhang , Maria Hilse , Stephanie Law
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