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We present an efficient scheme for accurate electronic structure interpolations based on the systematically improvable optimized atomic orbitals. The atomic orbitals are generated by minimizing the spillage value between the atomic basis…

Materials Science · Physics 2015-05-20 Mohan Chen , G-C Guo , Lixin He

Solving partial differential equations for extremely large-scale systems within a feasible computation time serves in accelerating engineering developments. Quantum computing algorithms, particularly the Hamiltonian simulations, present a…

Quantum Physics · Physics 2024-09-10 Yuki Sato , Ruho Kondo , Ikko Hamamura , Tamiya Onodera , Naoki Yamamoto

We introduce an intermediate quantum computing model built from translation-invariant Ising-interacting spins. Despite being non-universal, the model cannot be classically efficiently simulated unless the polynomial hierarchy collapses.…

Quantum Physics · Physics 2017-02-01 Xun Gao , Sheng-Tao Wang , Lu-Ming Duan

We study the complexity of classically sampling from the output distribution of an Ising spin model, which can be implemented naturally in a variety of atomic, molecular, and optical systems. In particular, we construct a specific example…

Quantum Physics · Physics 2017-09-20 Bill Fefferman , Michael Foss-Feig , Alexey V. Gorshkov

The practical application of quantum technologies to chemical problems faces significant challenges, particularly in the treatment of realistic basis sets and the accurate inclusion of electron correlation effects. A direct approach to…

An architecture for a quantum computer is presented in which spins associated with donors in silicon function as qubits. Quantum operations on the spins are performed using a combination of voltages applied to gates adjacent to the spins…

Quantum Physics · Physics 2015-06-26 B. E. Kane

Quantum computing has recently exhibited great potentials in predicting chemical properties for various applications in drug discovery, material design, and catalyst optimization. Progress has been made in simulating small molecules, such…

Despite their rich information content, electronic structure data amassed at high volumes in $ab$ $initio$ molecular dynamics simulations are generally under-utilized. We introduce a transferable high-fidelity neural network representation…

Materials Science · Physics 2022-02-22 Qiangqiang Gu , Linfeng Zhang , Ji Feng

We represent low dimensional quantum mechanical Hamiltonians by moderately sized finite matrices that reproduce the lowest O(10) boundstate energies and wave functions to machine precision. The method extends also to Hamiltonians that are…

Quantum Physics · Physics 2015-06-03 Johann Foerster , Alejandro Saenz , Ulli Wolff

Recent years have shown steady progress in research towards molecular electronics [1,2], where molecules have been investigated as switches [3-5], diodes [6], and electronic mixers [7]. In much of the previous work a Scanning Tunnelling…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 R. H. M. Smit , Y. Noat , C. Untiedt , N. D. Lang , M. van Hemert , J. M. van Ruitenbeek

Combinatorial optimization problems are ubiquitous in industrial applications. However, finding optimal or close-to-optimal solutions can often be extremely hard. Because some of these problems can be mapped to the ground-state search of…

Quantum Physics · Physics 2025-09-04 Junpeng Hou , Amin Barzegar , Helmut G. Katzgraber

This work collects the spin-dependent leading-order relativistic and quantum-electrodynamical corrections for the electronic structure of atoms and molecules within the non-relativistic quantum electrodynamics framework. We report the…

Chemical Physics · Physics 2025-09-03 Péter Jeszenszki , Péter Hollósy , Ádám Margócsy , Edit Mátyus

Oscillator based Ising machines are non-von-Neumann machines ideally suited for solving combinatorial problems otherwise intractable on classic stored-program digital computers due to their run-time complexity. Possible future applications…

Emerging Technologies · Computer Science 2024-10-02 Bernd Ulmann , Shrish Roy

It is challenging to scale Ising machines for industrial-level problems due to algorithm or hardware limitations. Although higher-order Ising models provide a more compact encoding, they are, however, hard to physically implement. This work…

Artificial Intelligence · Computer Science 2024-12-19 Yunuo Cen , Zhiwei Zhang , Zixuan Wang , Yimin Wang , Xuanyao Fong

The recent emergence of novel computational devices, such as quantum computers, coherent Ising machines, and digital annealers presents new opportunities for hardware-accelerated hybrid optimization algorithms. Unfortunately, demonstrations…

Optimization and Control · Mathematics 2020-10-21 Yuchen Pang , Carleton Coffrin , Andrey Y. Lokhov , Marc Vuffray

We have shown that quantum systems on finite-dimensional Hilbert spaces are equivalent under local transformations. Using these transformations give rise to a gauge group that connects the hamiltonian operators associated with each quantum…

Quantum Physics · Physics 2022-03-02 M. Caruso

Simulating the time evolution of a physical system at quantum mechanical levels of detail -- known as Hamiltonian Simulation (HS) -- is an important and interesting problem across physics and chemistry. For this task, algorithms that run on…

We propose an efficient and almost optimal scheme for measuring molecular Hamiltonians in quantum chemistry on quantum computers, which requires $2N^2$ distinct measurements in the leading order with $N$ being the number of molecular…

Quantum Physics · Physics 2024-04-02 Wataru Inoue , Koki Aoyama , Yusuke Teranishi , Keita Kanno , Yuya O. Nakagawa , Kosuke Mitarai

Arrays of optically trapped atoms excited to Rydberg states have recently emerged as a competitive physical platform for quantum simulation and computing, where high-fidelity state preparation and readout, quantum logic gates and controlled…

Quantum Physics · Physics 2021-05-19 M. Morgado , S. Whitlock

The one-dimensional Ising model with its connections to several physical concepts plays a vital role in comprehension of several principles, phenomena and numerical methods. The Hamiltonian of a coupled one-dimensional dissipative spin…