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Electron cooling, in which free electrons lose energy to vibrational excitation of gases, has been identified as a significant process in the atmospheres of Mars and Venus for electron impact on CO2. This process does not appear to have…
Although non-greenhouse gases can vary substantially in abundance in Earth-like atmospheres, their climatic influences remain insufficiently understood. To investigate how such gases regulate climate, we vary the abundance of N$_2$ as a…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial…
Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present…
We propose a mechanism for the oxidation of gaseous CO into CO2 occurring on the surface mineral hematite (Fe2O3(s)) in hot, CO2-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of…
Characterizing the bulk atmosphere of a terrestrial planet is important for determining surface pressure and potential habitability. Molecular nitrogen (N$_2$) constitutes the largest fraction of Earth$'$s atmosphere and is likely to be a…
We explore CO-CH4 quench kinetics in the atmospheres of substellar objects using updated time-scale arguments, as suggested by a thermochemical kinetics and diffusion model that transitions from the thermochemical-equilibrium regime in the…
A magma ocean (MO) is thought to be a ubiquitous stage in the early evolution of rocky planets and exoplanets. During the lifetime of the MO, exchanges between the interior and exterior envelopes of the planet are very efficient. In…
The chemical makeup of Earth's atmosphere during the Archean (4 Ga-2.5 Ga) and Proterozoic eon (2.5 Ga-0.5 Ga) contrast considerably with the present-day: the Archean was rich in carbon dioxide and methane and the Proterozoic had…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric…
We present the next step in a series of papers devoted to connecting the composition of the atmospheres of forming planets with the chemistry of their natal evolving protoplanetary disks. The model presented here computes the coupled…
The disequilibrium combination of abundant methane and carbon dioxide has been proposed as a promising exoplanet biosignature that is readily detectable with upcoming telescopes such as the James Webb Space Telescope. However, few studies…
This paper provides a brief summary and overview of the astrochemistry associated with the formation of stars and planets. It is aimed at new researchers in the field to enable them to obtain a quick overview of the landscape and key…
Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…
We present results from high-resolution three-dimensional simulations of turbulent interstellar gas that self-consistently follow its coupled thermal, chemical and dynamical evolution, with a particular focus on the formation and…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial…
Grain-surface chemistry plays a crucial role in the formation of molecules of astrobiological interest, including H$_{2}$S and complex organic molecules (COMs). They are commonly observed in the gas phase toward star-forming regions, but…
We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…
Impacts by rocky and icy bodies are thought to have played a key role in shaping the composition of solar system objects, including the Earth's habitability. Hence, it is likely that they play a similar role in exoplanetary systems. We…
The atmospheres of gaseous giant exoplanets orbiting close to their parent stars (hot Jupiters) have been probed for nearly two decades. They allow us to investigate the chemical and physical properties of planetary atmospheres under…