Related papers: Carbon Monoxide Affecting Planetary Atmospheric Ch…
Chemical kinetics plays an important role in controlling the atmospheric composition of all planetary atmospheres, including those of extrasolar planets. For the hottest exoplanets, the composition can closely follow…
Studying exoplanet atmospheres is essential for assessing their potential to host liquid water and their capacity to support life (their habitability). Each atmosphere uniquely influences the likelihood of surface liquid water, defining the…
The evidence for abundant liquid water on early Mars despite the faint young Sun is a long-standing problem in planetary research. Here we present new ab initio spectroscopic and line-by-line climate calculations of the warming potential of…
We have developed the first gas-grain chemical model for oxygen fractionation (also including sulphur fractionation) in dense molecular clouds, demonstrating that gas-phase chemistry generates variable oxygen fractionation levels, with a…
Thermochemical models have been used in the past to constrain the deep oxygen abundance in the gas and ice giant planets from tropospheric CO spectroscopic measurements. Knowing the oxygen abundance of these planets is a key to better…
The elemental ratios of carbon, nitrogen, and oxygen in the atmospheres of hot Jupiters may hold clues to their formation locations in the protostellar disc. In this work, we adopt gas phase chemical abundances of C, N and O from several…
Exoplanets that receive stellar irradiance of approximately Earth's or less have been discovered and many are suitable for spectral characterization. Here we focus on the temperate planets that have massive H2-dominated atmospheres, and…
Earth is expected to have acquired a reduced proto-atmosphere enriched in H2 and CH4 through the accretion of building blocks that contain metallic Fe and/or the gravitational trapping of surrounding nebula gas. Such an early, wet, reduced…
Planet formation models suggest broad compositional diversity in the sub-Neptune/super-Earth regime, with a high likelihood for large atmospheric metal content (> 100 x Solar). With this comes the prevalence of numerous plausible bulk…
To study the chemical evolution during the formation of molecular clouds, we model three types of clouds with different density structures: collapsing spherical, collapsing ellipsoidal, and static spherical profiles. The collapsing models…
The Trappist-1 planets provide a unique opportunity to test the current understanding of rocky planet evolution. The James Webb Space Telescope is expected to characterize the atmospheres of these planets, potentially detecting CO$_2$, CO,…
Fundamental inorganic chemistry shows that increasing concentrations of atmospheric CO2 will have no harmful effect on organisms that live in the natural waters of the Earths, and may well benefit them. Alkalinity and dissolved CO2 give…
Gas in protostellar disks provides the raw material for giant planet formation and controls the dynamics of the planetesimal-building dust grains. Accurate gas mass measurements help map the observed properties of planet-forming disks onto…
Understanding the gas abundance distribution is essential when tracing star formation using molecular line observations. Changing density and temperature conditions cause gas to freeze-out onto dust grains, and this needs to be taken into…
Context. Carbon monoxide (CO) is arguably the most important molecule for interstellar organic chemistry. Its binding to amorphous solid water (ASW) ice regulates both diffusion and desorption processes. Accurately characterizing the CO…
Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…
In the study presented here, we model the gas phase chemistry induced by plasma discharge at low temperature (150 K) in the NASA Ames COSmIC Simulation Chamber (COSmIC) using a 1-dimensional multi-fluid plasma model named CO-PRISM (COSmIC…
We model the formation of silicate atmospheres on hot volatile-free super-Earths. Our calculations assume that all volatile elements such as H, C, N, S, and Cl have been lost from the planet. We find that the atmospheres are composed…
Numerous solar system atmospheres possess aerosols including the characteristic organic hazes of Titan and Pluto. Haze particles substantially impact atmospheric temperatures structures and may provide organic material to the surface of a…
The atmospheres of the terrestrial planets are known to have been modified as a consequence of the impact degassing and atmospheric erosion during the late accretion. Despite the commonality of these processes, there are distinct gaps --…