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Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…

Statistical Mechanics · Physics 2009-11-07 Chih-Yuan Tseng , Ariel Caticha

We live in the information age. Claude Shannon, as the father of the information age, gave us a theory of communications that quantified an "amount of information," but, as he pointed out, "no concept of information itself was defined."…

Information Theory · Computer Science 2021-12-06 David Ellerman

The ultimate purpose of the statistical analysis of ordinal patterns is to characterize the distribution of the features they induce. In particular, knowing the joint distribution of the pair Entropy-Statistical Complexity for a large class…

The chain rule for the Shannon and von Neumann entropy, which relates the total entropy of a system to the entropies of its parts, is of central importance to information theory. Here we consider the chain rule for the more general smooth…

Quantum Physics · Physics 2013-10-25 Alexander Vitanov , Frederic Dupuis , Marco Tomamichel , Renato Renner

All of the basic microsopic physical laws are time reversible. In contrast, the second law of thermodynamics, which is a macroscopic physical representation of the world, is able to describe irreversible processes in an isolated system…

Chemical Physics · Physics 2015-06-19 Roland Riek

In classical Hamiltonian theories, entropy may be understood either as a statistical property of canonical systems, or as a mechanical property, that is, as a monotonic function of the phase space along trajectories. In classical mechanics,…

General Relativity and Quantum Cosmology · Physics 2016-10-14 Marius Oltean , Luca Bonetti , Alessandro D. A. M. Spallicci , Carlos F. Sopuerta

Calculations of entropy fluxes and production rate have been evaluated with some success to study atmospheric processes. However, recurring questions arise as to how best to take into account entropy flux due to radiation, for example. This…

Atmospheric and Oceanic Physics · Physics 2019-11-12 Pascal Marquet

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…

Statistical Mechanics · Physics 2014-03-26 Leo P. Kadanoff

In this paper, some general properties of Shannon information measures are investigated over sets of probability distributions with restricted marginals. Certain optimization problems associated with these functionals are shown to be…

Information Theory · Computer Science 2020-08-13 Mladen Kovačević , Ivan Stanojević , Vojin Šenk

In a paper [8] the authors classify entropy into three categories, as a thermodynamics quantity, as a measure of information production, and as a means of statistical inference. An entropy measure introduced by Mathai falls into the second…

Statistical Mechanics · Physics 2024-10-31 Hans J. Haubold

In a previous paper, we introduced an axiomatic system for information thermodynamics, deriving an entropy function that includes both thermodynamic and information components. From this function we derived an entropic probability…

Quantum Physics · Physics 2024-12-18 Benjamin Schumacher , Michael D. Westmoreland

We define a diagonal entropy (d-entropy) for an arbitrary Hamiltonian system as $S_d=-\sum_n \rho_{nn}\ln \rho_{nn}$ with the sum taken over the basis of instantaneous energy states. In equilibrium this entropy coincides with the…

Statistical Mechanics · Physics 2012-08-10 Anatoli Polkovnikov

I address the question whether the origin of the observed arrow of time can be derived from quantum cosmology. After a general discussion of entropy in cosmology and some numerical estimates, I give a brief introduction into quantum…

General Relativity and Quantum Cosmology · Physics 2012-07-27 Claus Kiefer

We provide a simple physical interpretation, in the context of the second law of thermodynamics, to the information inequality (a.k.a. the Gibbs' inequality, which is also equivalent to the log-sum inequality), asserting that the relative…

Information Theory · Computer Science 2009-03-29 Neri Merhav

We revisit textbook claims that entropy must increase and show that, under time-reversal invariant microscopic dynamics, no universal trajectory-wise or statistical assertion that the coarse-grained entropy $S(t)$ is non-decreasing can…

Statistical Mechanics · Physics 2026-03-06 Ting Peng

Based on Landauer's principle, we provide a geometrical definition for the entropy of a given static, spherically symmetric spacetime. Considering a congruence of geodesics across a surface, one defines the entropy of a congruence as the…

General Relativity and Quantum Cosmology · Physics 2026-05-29 J. M. Isidro , B. Koch , A. Rincon

J.M.R. Parrondo at al. in arXiv:0904.1573 continue numerous efforts to unify the concepts of the arrow of time and entropy production with the concept of time invariance in physics. This is a wrong way.

General Physics · Physics 2009-07-27 V. A. Kuz'menko

This letter reports two moment extensions of the entropy of a distribution. By understanding the traditional entropy as the average of the original distribution up to a random variable transformation, the traditional moments equation become…

Statistical Mechanics · Physics 2008-03-25 Luciano da Fontoura Costa

After presenting possible motives for fighting against the second law of thermodynamics, several attempts to beat this law are analyzed. The second law wins, but an interesting interpretation of it emerges. This interpretation uses the…

adap-org · Physics 2015-06-30 Jorge Berger