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A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

Photon recycling is required for a solar cell to achieve an open-circuit voltage ($V_{OC}$) and power conversion efficiency (PCE) approaching the Shockley-Queisser theoretical limit. In metal halide perovskite solar cells, the achievable…

Applied Physics · Physics 2019-07-17 Roberto Brenes , Madeleine Laitz , Joel Jean , Dane W. deQuilettes , Vladimir Bulovic

The theoretical analysis of photovoltaic conversion efficiency of highly effective silicon solar cells (SC) is performed for n-type and p-type bases. The case is considered when the Shockley-Read-Hall recombination in the silicon bulk is…

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination…

Mesoscale and Nanoscale Physics · Physics 2021-03-23 Ting Xu , Zi-Shuai Wang , Xuan-Hua Li , Wei E. I. Sha

With the consideration of photon recycling effect, the efficiency limit of methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells is predicted by a detailed balance model. To obtain convincing predictions, both AM 1.5 spectrum of…

Materials Science · Physics 2015-07-01 Wei E. I. Sha , Xingang Ren , Luzhou Chen , Wallace C. H. Choy

Fundamental electronic processes such as charge-carrier transport and recombination play a critical role in determining the efficiency of hybrid perovskite solar cells. The presence of mobile ions complicates the development of a clear…

Materials Science · Physics 2020-12-17 Sebastian Reichert , Katelyn Goetz , Christopher Wöpke , Yana Vaynzof , Carsten Deibel

Charge carrier recombination in the perovskite solar cells (PSCs) has a deep influence on the electrical performance, such as open circuit voltage, short circuit current, fill factor and ultimately power conversion efficiency. The impacts…

Mesoscale and Nanoscale Physics · Physics 2018-03-28 Lin Xing Shi , Zi Shuai Wang , Zengguang Huang , Wei E. I. Sha , Haoran Wang , Zhen Zhou

While the performance enhancement witnessed in the field of perovskite solar cells over the recent years has been impressive, it is now evident that further optimization beyond the existing literature would require detailed analysis of…

Applied Physics · Physics 2018-12-05 Sumanshu Agarwal , Pradeep R. Nair

Perovskite semiconductors have demonstrated outstanding external luminescence quantum yields, enabling high power conversion efficiencies (PCE). However, the precise conditions to advance to an efficiency regime above monocrystalline…

The Shockley equation (SE), originally derived to describe a p--n junction, was frequently used in the past to simulate current--voltage (j/V) characteristics of organic solar cells (OSC). In order to gain a more detailed understanding of…

Materials Science · Physics 2012-09-06 A. Foertig , J. Rauh , V. Dyakonov , C. Deibel

To accurately calculate efficiencies $\eta$ of experimentally produced multijunction solar cells (MJSCs) and optimize their parameters, we offer semi-analytical photoconversion formalism that incorporates radiative recombination,…

Materials Science · Physics 2016-11-17 A. V. Sachenko , A. I. Shkrebtii , V. P. Kostylyov , M. R. Kulish , I. O. Sokolovskyi

Perovskite solar cells have reached power conversion efficiencies that rival those of established silicon photovoltaics. Nanotextures in perovskite solar cells scatter the incident light, thereby improving optical absorption. In addition,…

Since the photoconversion efficiency $\eta$ of the silicon-based solar cells (SCs) under laboratory conditions is approaching the theoretical fundamental limit, further improvement of their performance requires theoretical modeling and/or…

Materials Science · Physics 2024-09-04 V. P. Kostylyov , A. V. Sachenko , M. Evstigneev , I. O. Sokolovskyi , A. I. Shkrebtii

Drift-diffusion model is an indispensable modeling tool to understand the carrier dynamics (transport, recombination, and collection) and simulate practical-efficiency of solar cells (SCs) through taking into account various carrier…

Mesoscale and Nanoscale Physics · Physics 2017-04-20 Xingang Ren , Zishuai Wang , Wei E. I. Sha , Wallace C. H. Choy

In this perspective, we explore the insights into the device physics of perovskite solar cells gained from modeling and simulation of these devices. We discuss a range of factors that influence the modeling of perovskite solar cells,…

Applied Physics · Physics 2020-08-04 Nir Tessler , Yana Vaynzof

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies…

Here, we report an experimental demonstration of perovskite solar cells dominated by bimolecular recombination and critically analyse their performance against radiative limits. To this end, we first establish a set of quantitative…

Materials Science · Physics 2024-04-23 Kashimul Hossain , Dhyana Sivadas , Dinesh Kabra , Pradeep R. Nair

To be able to increase the efficiency of perovskite solar cells which is one of the most substantial challenges ahead in photovoltaic industry, the structural and optical properties of perovskite CH3NH3PbI3-xBrx for values x=1-3 have been…

Perovskite solar cells (PSCs) without a hole transport layer (HTL) offer a cost-effective and stable alternative to conventional architectures, utilizing only an absorber layer and an electron transport layer (ETL). This study presents a…

Machine Learning · Computer Science 2025-05-27 Ihtesham Ibn Malek , Hafiz Imtiaz , Samia Subrina

The ideality factor determined by measuring the open circuit voltage (VOC) as function of light intensity is often used as a means to identify the dominant recombination mechanism in solar cells. However, applying this Suns-VOC technique to…

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