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Room-temperature ionic liquids (RTIL) are a new class of organic salts whose melting temperature falls below the conventional limit of 100C. Their low vapor pressure, moreover, has made these ionic compounds the solvents of choice of the…

Chemical Physics · Physics 2019-04-05 Antonio Benedetto

Electronic polarization and charge transfer effects play a crucial role in thermodynamic, structural and transport properties of room-temperature ionic liquids (RTILs). These non-additive interactions constitute a useful tool for tuning…

Materials Science · Physics 2014-09-09 Vitaly V. Chaban , Oleg V. Prezhdo

Based on classical molecular dynamics simulations, we discuss the impact of Coulombic interactions on a comprehensive set of properties of room temperature ionic liquids (RTILs) containing 1,3 dimethylimidazolium (MMIM+), N butylpyridinium…

Materials Science · Physics 2017-09-13 Vitaly V. Chaban

An optically-induced thermal non-linear effect in a nematic liquid-crystal (E7) cell is evidenced through weak light-absorption by the ITO coating of an infrared pulsed femtosecond laser (m). Strong spatial self-phase modulation is…

Room temperature ionic liquids (RTILs) are solvent with unusual properties, which are difficult to characterize experimentally because of their intrinsic complexity (large number of atoms, strong Coulomb interactions). Molecular simulations…

Chemical Physics · Physics 2015-06-01 Mathieu Salanne

There is growing interest in strongly correlated insulator thin films because the intricate interplay of their intrinsic and extrinsic state variables causes memristive behavior that might be used for bio-mimetic devices in the emerging…

Room-temperature ionic liquids (RTILs) constitute a fine-tunable class of compounds. Morpholinium-based cations are new to the field. They are promising candidates for electrochemistry, micellization and catalytic applications. We…

Materials Science · Physics 2015-06-01 Vitaly V. Chaban , Oleg V. Prezhdo

A wide variety of feed gases are used to generate low-temperature plasmas for the microelectronics and the sustainability applications. These plasmas often have a complex combination of reactive and non-reactive species which may have…

The complex interaction between the intrinsic and extrinsic state variables of strongly correlated insulator thin films is drawing interest as it shows memristive behavior that may be used in neuromorphic computing. In this study, we have…

Materials Science · Physics 2024-10-04 Mousri Paul , Sabyasachi Karmakar , Jay Sharma , Satyaban Bhunia , Supratic Chakraborty

Room-temperature ionic liquids (RTILs) exhibit large difference between melting and boiling points. They are highly tunable thanks to numerous accessible combinations of the cation and the anion. On top of that, cations can be…

Materials Science · Physics 2015-06-18 Vitaly Chaban

Room Temperature Ionic Liquids (RTILs) have attracted much of the attention of the scientific community in the past decade due the their novel and highly customizable properties. Nonetheless their high viscosities pose serious limitations…

Chemical Physics · Physics 2012-08-09 Oliviero Andreussi , Nicola Marzari

Based on the fundamental Bogolyubov chain of equations, a model relating the structural and thermophysical properties of the nonequilibrium liquid systems under irradiation in stationary state is introduced. The obtained results suggest…

Statistical Mechanics · Physics 2016-03-28 L. A. Bulavin , K. V. Cherevko , D. A. Gavryushenko , V. M. Sysoev , T. S. Vlasenko

Highly non-equilibrium conditions in femtosecond-laser excited solids cause a variety of ultrafast phenomena that are not accessible by thermal conditions, like sub-picosecond solid-to-liquid or solid-to-solid phase transitions. In recent…

Materials Science · Physics 2024-09-13 Christelle Inès K. Mebou , Martin E. Garcia , Tobias Zier

The photodynamic properties of molecules determine their ability to survive in harsh radiation environments. As such, the photostability of heterocyclic aromatic compounds to electromagnetic radiation is expected to have been one of the…

The ultrafast dynamics of ions in solids following intense femtosecond laser excitation is governed by two fundamentally distinct yet interplaying effects. On one hand, the significant generation of hot electron-hole pairs by the light…

Computational Physics · Physics 2024-01-22 Bernd Bauerhenne , Martin E. Garcia

We investigated experimentally and theoretically angular momentum alignment-to-orientation conversion created by the joint interaction of laser radiation and an external magnetic field with atomic rubidium at room temperature. In particular…

Atomic Physics · Physics 2020-11-11 A. Mozers , L. Busaite , D. Osite , M. Auzinsh

Ionic liquids constrained at interfaces or restricted in subnanometric pores are increasingly employed in modern technologies, including energy applications. Understanding the details of their behavior in these conditions is therefore…

Materials Science · Physics 2018-09-25 Stefano Mossa

Phase transitions driven by ultrashort laser pulses have attracted interest both for understanding the fundamental physics of phase transitions and for potential new data storage or device applications. In many cases these transitions…

Optothermal interaction of active colloidal matter can facilitate environmental cues which can influence the dynamics of active soft matter systems. The optically induced thermal effect can be harnessed to study non-equilibrium…

Soft Condensed Matter · Physics 2022-09-07 Diptabrata Paul , Rahul Chand , G V Pavan Kumar

It is well-known that room temperature ionic liquids (RTILs) often adopt a charge-separated layered structure, i.e., with alternating cation- and anion-rich layers, at electrified interfaces. However, the dynamic response of the layered…

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