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The chemical bulk reductive covalent functionalization of thin layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP is achieved…

Phosphorene and its components are highly reactive to oxygen when exposed to ambient conditions due to the presence of lone pairs of electrons on phosphorus atoms. Functionalization serves as a solution to prevent the chemical degradation…

The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other…

We investigate the electro-optic properties of black phosphorus (BP) thin films for optical modulation in the mid-infrared frequencies. Our calculation indicates that an applied out-of-plane electric field may lead to red-, blue-, or…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Charles Lin , Roberto Grassi , Tony Low , Amr S. Helmy

Two-dimensional materials and their heterostructures have emerged as a new class of materials for not only fundamental physics but also for electronic and optoelectronic applications. Black phosphorus (BP) is a relatively new addition to…

Mesoscale and Nanoscale Physics · Physics 2015-11-23 Manabendra Kuiri , Chandan Kumar , Biswanath Chakraborty , Satyendra N Gupta , Mit H. Naik , Manish Jain , A. K. Sood , Anindya Das

Black phosphorus (BP) offers considerable promise for infrared and visible photonics. Efficient tuning of the bandgap and higher subbands in BP by modulation of the Fermi level or application of vertical electric fields has been previously…

Black phosphorus (BP), an emerging two-dimensional (2D) material with intriguing optical properties, forms a promising building block in optics and photonics devices. In this work, we propose a simple structure composed of BP sandwiched by…

Optics · Physics 2019-09-18 Tingting Liu , Xiaoyun Jiang , Chaobiao Zhou , Shuyuan Xiao

The electronic structure and functionality of 2D materials is highly sensitive to structural morphology, opening the possibility for manipulating material properties, but also making predictable and reproducible functionality challenging.…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Prakriti P. Joshi , Ruiyu Li , Joseph L. Spellberg , Liangbo Liang , Sarah B. King

Black phosphorus (BP) is an emerging two-dimensional semiconducting material with great potential for nanoelectronic and nanophotonic applications, especially owing to its unique anisotropic electrical and optical properties. Many…

Functionalization of atomically thin nanomaterials enables the tailoring of their chemical, optical, and electronic properties. Exfoliated black phosphorus, a layered two-dimensional semiconductor exhibiting favorable charge carrier…

Black phosphorus (BP) stands out from other 2D materials by the wide amplitude of the band-gap energy (Delta(Eg)) that sweeps an optical window from Visible (VIS) to Infrared (IR) wavelengths, depending on the layer thickness. This…

We report analytic results on quantum capacitance (C$_{q}$) measurements and their optical tuning in dual-gated device with potassium-doped multi-layered black phosphorous (BP) as the channel material. The two-dimensional (2D) layered BP is…

Materials Science · Physics 2017-08-09 Parijat Sengupta , Shaloo Rakheja

Atomically-thin black phosphorus (BP) is an emerging two dimensional (2D) material exhibiting bright photoluminescence in the near infrared. Coupling its radiation to photonic nanostructures will be an important step toward the realization…

Mesoscale and Nanoscale Physics · Physics 2018-10-01 Yasutomo Ota , Rai Moriya , Naoto Yabuki , Miho Arai , Masahiro Kakuda , Satoshi Iwamoto , Tomoki Machida , Yasuhiko Arakawa

We numerically investigate the high-efficiency photovoltaic effect in lateral p-n homojunction based on monolayer black phosphorus (MBP) by using the non-equilibrium Green's function combined with the density functional theory. Due to the…

Mesoscale and Nanoscale Physics · Physics 2023-08-15 Xueying Zuo , Jingjing Cheng , Yulin Liang , Fuming Xu , Yanxia Xing

Black phosphorous (BP) is a layered semiconductor with high carrier mobility, anisotropic optical response and wide bandgap tunability. In view of its application in optoelectronic devices, understanding transient photo-induced effects is…

Mesoscale and Nanoscale Physics · Physics 2022-09-07 H. Hedayat , A. Ceraso , G. Soavi , S. Akhavan , A. Cadore , C. Dallera , G. Cerullo , A. C. Ferrari , E. Carpene

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla

The discovery of graphene triggered a rapid rise of unexplored two-dimensional materials and heterostructures having optoelectronic and photonics properties that can be tailored on the nanoscale. Among these materials, black phosphorus (BP)…

Applied Physics · Physics 2019-03-18 Leonardo Viti , Antonio Politano , Miriam Serena Vitiello

Phosphorus atomic chains, the utmost-narrow nanostructures of black phosphorus (BP), are highly relevant to the in-depth development of BP into one-dimensional (1D) regime. In this contribution, we report a top-down route to prepare atomic…

Materials Science · Physics 2017-04-21 Zhangru Xiao , Jingsi Qiao , Wanglin Lu , Guojun Ye , Xianhui Chen , Ze Zhang , Wei Ji , Jixue Li , Chuanhong Jin

Black phosphorus is a very promising material for telecommunication due to its direct bandgap and strong resonant absorption in near-infrared wavelength range. However, ultrafast nonlinear photonic applications relying on the ultrafast…

Black phosphorous (BP) is one of the most interesting layered materials, bearing promising potential for emerging electronic and optoelectronic device technologies. The crystalline structure of BP displays in-plane anisotropy in addition to…

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