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Fullerene solids doped with alkali metals (A$_3$C$_{60}$, A = K, Rb, Cs) exhibit a superconducting transition temperature ($T_c$) as high as 40 K, and their unconventional superconducting properties have been a subject of debate. With…

Superconductivity · Physics 2023-10-24 Jianyu Li , Zhangkai Cao , Jiahao Su , Ruipeng Wang , Haipeng Li , Yusuke Nomura , Xiaosen Yang , Ho-Kin Tang

Upon thermal annealing at or above room temperature (RT) and high pressure $\it P$ $\sim$ 155 GPa, H$_3$S exhibits superconductivity at $\it T_C$ $\sim$ 200 K. Various theoretical frameworks with strong electron-phonon coupling and Coulomb…

Superconductivity · Physics 2018-08-03 Dale R. Harshman , Anthony T. Fiory

The superconducting transition temperatures of high-Tc compounds based on copper, iron, ruthenium and certain organic molecules are discovered to be dependent on bond lengths, ionic valences, and Coulomb coupling between electronic bands in…

Superconductivity · Physics 2012-07-03 Dale R. Harshman , Anthony T. Fiory

In their article, Zhang et al. [Phys. Rev. B 86, 024516 (2012)] present a remarkable result for A$_x$(S)$_y$TiNCl compounds ($\alpha$-phase TiNCl partially intercalated with alkali A and optionally co-intercalated molecular species S),…

Superconductivity · Physics 2015-06-23 Dale R. Harshman , Anthony T. Fiory

Unconventional superconductivity in bilayer graphene has been reported for twist angles $\theta$ near the first magic angle and charged electrostatically with holes near half filling of the lower flat bands. A maximum superconducting…

Superconductivity · Physics 2019-08-06 Dale R. Harshman , Anthony T. Fiory

It is demonstrated that the transition temperature (Tc) of high-Tc superconductors is determined by their layered crystal structure, bond lengths, valency properties of the ions, and Coulomb coupling between electronic bands in adjacent,…

Superconductivity · Physics 2012-02-03 Dale R. Harshman , Anthony T. Fiory , John D. Dow

In a recent contribution to this journal, it was shown that the transition temperatures of optimal high-Tc compounds obey the algebraic relation, Tc0 = kB-1{\beta}/\ell{\zeta}, where \ell is related to the mean spacing between interacting…

Superconductivity · Physics 2014-08-01 Dale R. Harshman , Anthony T. Fiory

The uniquely characteristic macrostructures of binary hydrogen-clathrate compounds $M$H$_\textrm{n}$ formed at high pressure, a cage of hydrogens surrounding a central-atom host, is theoretically predicted in various studies to include…

Superconductivity · Physics 2020-06-22 Dale R. Harshman , Anthony T. Fiory

Behavior consistent with Coulomb-mediated high-T$_C$ superconductivity is shown to be present in the intercalated group-4-metal nitride halides A$_x$(S)$_y$MNX, where the MNX host (M = Ti, Zr, Hf; X = Cl, Br) is partially intercalated with…

Superconductivity · Physics 2015-09-15 Dale R. Harshman , Anthony T. Fiory

Former extensive studies of superconductivity in the \textit{A}$_{3}$C$_{60}$ compounds, where \textit{A} is an alkali, have led to consider that Bardeen Cooper Schrieffer (BCS) electron-phonon pairing prevails in those compounds, though…

Superconductivity · Physics 2014-02-20 P. Wzietek , T. Mito , H. Alloul , D. Pontiroli , M. Aramini , M. Riccò

A maximum superconductive transition temperature $T_\textrm{C}$ = 203.5 K has recently been reported for a sample of the binary compound tri-hydrogen sulfide (H$_\textrm{3}$S) prepared at high pressure and with room temperature annealing.…

Superconductivity · Physics 2017-03-14 Dale R. Harshman , Anthony T. Fiory

The alkali-doped fulleride Cs$_{3}$C$_{60}$, crystallized in the space group Fm$\overline 3$m or Pm$\overline 3$n, exhibits unconventional $s$-wave superconductivity under pressure with a maximum $T_c\sim 38$ K. Recently, a new…

Superconductivity · Physics 2024-03-08 Changming Yue , Yusuke Nomura , Kosmas Prassides , Philipp Werner

Alkali-fulleride superconductors with a maximum critical temperature Tc of 40 K exhibit similar electronic phase diagram with unconventional high-Tc superconductors where the superconductivity resides proximate to a magnetic Mott-insulating…

Superconductivity · Physics 2020-05-13 Ming-Qiang Ren , Sha Han , Shu-Ze Wang , Jia-Qi Fan , Can-Li Song , Xu-Cun Ma , Qi-Kun Xue

Alkali-doped fullerides A3C60 (A=K, Rb, Cs) are surprising materials where conventional phonon-mediated superconductivity and unconventional Mott physics meet, leading to a remarkable phase diagram as a function of the volume per C60…

Superconductivity · Physics 2015-08-27 Yusuke Nomura , Shiro Sakai , Massimo Capone , Ryotaro Arita

Alkali-doped fullerides (A3C60 with A=K, Rb, Cs) show a surprising phase diagram, in which a high transition-temperature (Tc) s-wave superconducting state emerges next to a Mott insulating phase as a function of the lattice spacing. This is…

Superconductivity · Physics 2016-03-17 Yusuke Nomura , Shiro Sakai , Massimo Capone , Ryotaro Arita

Pressure as a clean and efficient tool can bring about unexpected extraordinary physical and chemical properties of matters. The recent discoveries of superconductivity at nearly room temperature in hydrides highlight the power of pressure…

Superconductivity · Physics 2022-08-22 Di Peng , Ren-Shu Wang , Li-Na Zong , Xiao-Jia Chen

Chromium (Cr) is a transition metal element with 3$d$ orbital electrons. In most compounds containing Cr, due to the correlation effect, twofold features of localization and itinerancy are expected. The localization gives rise to a magnetic…

Superconductivity · Physics 2022-10-10 Zhengyan Zhu , Ying-Jie Zhang , Yiwen Li , Qing Li , Wen Duan , Hai-Hu Wen

Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…

Superconductivity · Physics 2009-11-13 K. Miyoshi , Y. Takaichi , Y. Takamatsu , M. Miura , J. Takeuchi

It has been proposed that the superconducting transition temperature $T_{\mathrm{c}}$ of an unconventional superconductor with a large pairing scale but strong phase fluctuations can be enhanced by coupling it to a metal. However, the…

Superconductivity · Physics 2022-12-05 Philip M. Dee , Steven Johnston , Thomas Maier

The empirical relation of T_co(K)=2740/<q>_c^4 between the transition temperature of optimum doped superconductors T_co and the mean cationic charge <q>_c, a physical paradox, can be recast to strongly support fractal theories of high-T_c…

General Physics · Physics 2016-04-07 Hans Hermann Otto
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