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Magnetoelectric multiferroics are highly sought after for applications in low-power electronics and for advancing fundamental research, including axion insulators and dark matter detection. However, achieving a combination of ferroic spin…

Materials Science · Physics 2024-12-02 Libor Šmejkal

Neutron diffraction and 7Li-NMR have been applied to determine the multiferroic system LiCu2O2, which has four chains (ribbon chains) of edge-sharing CuO4 square planes in a unit cell. We have confirmed that there are successive magnetic…

Materials Science · Physics 2015-05-13 Yoshiaki Kobayashi , Kenji Sato , Yukio Yasui , Taketo Moyoshi , Masatoshi Sato , Kazuhisa Kakurai

The magnetic and multiferroic phase diagram of Mn$_{0.85}$Co$_{0.15}$WO$_4$ single crystals is investigated by means of magnetic, heat capacity, dielectric, polarization, and neutron scattering experiments. Three magnetic phase transitions…

Strongly Correlated Electrons · Physics 2010-12-01 R. P. Chaudhury , F. Ye , J. A. Fernandez-Baca , Y. -Q. Wang , Y. Y. Sun , B. Lorenz , H. A. Mook , C. W. Chu

Motivated by the recently discovered superconductivity in Sr-doped nickelate oxides NdNiO$_2$, we predict a material BiNiO$_2$ that provides an opportunity to study the intertwined ferroelectricity, metallicity, and magnetism in a crystal…

Strongly Correlated Electrons · Physics 2024-04-22 Hu Zhang , RuiFeng Zhang , Lulu Zhao , Chendong Jin , Ruqian Lian , Peng-Lai Gong , RuiNing Wang , JiangLong Wang , Xing-Qiang Shi

Lithium nitrate LiNO$_3$ is identified to possess a dielectric constant $\epsilon$' larger than 6x10$^6$ at 1 kHz in powder samples above the critical temperature $T$$_W$ = 306 K. For single crystalline samples, $\epsilon$' can be sustained…

Materials Science · Physics 2025-05-07 Na Du , Yan Zhao , Enting Xu , Jianwei Han , Peng Ren , Fei Yen

Neutron spherical polarimetry, which is directly sensitive to the absolute magnetic configuration and domain population, has been used in this work to unambiguously prove the multiferroicity of (ND4)2[FeCl5(D2O)]. We demonstrate that the…

The magnetic properties of $\alpha$-NaFeO$_2$ are studied by neutron diffraction and magnetization measurements. An ordered phase with spins aligned along the b$_hex$ axis exists at low temperatures (T < 4 K). At intermediate temperatures…

Strongly Correlated Electrons · Physics 2009-02-02 T. M. McQueen , Q. Huang , J. W. Lynn , R. F. Berger , T. Klimczuk , B. G. Ueland , P. Schiffer , R. J. Cava

A proper understanding of the mechanism for cuprate superconductivity can emerge only by comparing materials in which physical parameters vary one at a time. Here we present a variety of bulk, resonance, and scattering measurements on the…

Superconductivity · Physics 2015-05-14 Amit Keren

Two-dimensional van der Waals magnets show strong interconnection between their electrical, magnetic, and structural properties. Here we reveal the emergence of a luminescent transition upon crossing the N\'eel transition temperature of…

Materials Science · Physics 2025-03-25 Volodymyr Multian , Fan Wu , Dirk van der Marel , Nicolas Ubrig , Jérémie Teyssier

High-field phase diagram of a chiral-lattice antiferromagnet Sr(TiO)Cu4(PO4)4 is studied by means of the ultrasound, dielectric, and magnetocaloric-effect measurements. These experimental techniques reveal two new phase transitions at high…

Composite multiferroics are materials exhibiting the interplay of ferroelectricity, magnetism, and strong electron correlations. Typical example --- magnetic nano grains embedded in a ferroelectric matrix. Coupling of ferroelectric and…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 O. G. Udalov , N. M. Chtchelkatchev , I. S. Beloborodov

Li et al. (Science Advances, 29 January, p. eabe3068) claim the discovery of two improper ferroelectrics, dabcoHClO4 and dabcoHBF4 (dabco = 1,4-diazabicyclo[2.2.2]octane), and that these materials exhibit superior pyroelectric figures of…

Materials Science · Physics 2021-07-02 Marek Szafrański , Andrzej Katrusiak

A ferroelectric transition occurring simultaneously with helical spin order has been found in both the polycrystalline and single crystal samples of LiCuVO4. The system has Cu2+ spins (s=1/2) of the CuO2 chains formed of edge-sharing CuO4…

Strongly Correlated Electrons · Physics 2015-06-25 Yutaka Naito , Kenji Sato , Yukio Yasui , Yusuke Kobayashi , Yoshiaki Kobayashi , Masatoshi Sato

Two dimensional multiferroics inherit prominent physical properties from both low dimensional materials and magnetoelectric materials, and can go beyond their three dimensional counterparts for their unique structures. Here, based on…

Materials Science · Physics 2021-09-29 Mingyu Zhao , Jun Chen , Shan-Shan Wang , Ming An , Shuai Dong

Tungstates $A$WO$_4$ with the wolframite structure characterized by the $A$O$_6$ octahedral zigzag chains along the $c$-axis, can be magnetic if $A$=Mn, Fe, Co, Cu, Ni. Among them, MnWO$_4$ is a unique member with a cycloid Mn$^{2+}$ spin…

Recent dielectric and magnetic studies of (Ca0.5Mn1.5)MnWO6 ceramics [A.A. Belik, Chem. Mater. 36, 7604 (2024)] have classified this material as a rare hybrid multiferroic, with both antiferromagnetic and (anti)ferroelectric ordering…

Single phase multiferroics in which ordered magnetic and ferroelectricity coexist, are of great interest for new multifunctional devices, and among them Y-type hexaferrites are good candidates. Transverse susceptibility measurements, which…

Materials Science · Physics 2024-03-03 P. Hernández-Gómez , D. Martín-González , C. Torres , J. M. Muñoz

Co4Nb2O9 (CNO) having {\alpha}-Al2O3 crystal structure with Co chains along c-direction shows gigantic magnetoelelctric coupling below antiferromagnetic ordering temperature of 27 K but above a spin flop field of 1.6 T. We have investigated…

Materials Science · Physics 2016-06-16 C. Dhanasekhar , S. K. Mishra , R. Rawat , A. K. Das , A. Venimadhav

We investigated the rare-earth transition metal oxide series, Ln2CuTiO6 (Ln=Y, Dy, Ho, Er and Yb), crystallizing in the hexagonal structure with non-centrosymmetric P63cm space group for possible occurrences of multiferroic properties. Our…

We report the discovery of a complete suppression of ferroelectricity in $MnWO_4$ by 10 % iron substitution and its restoration in external magnetic fields. The spontaneous polarization in $Mn_{0.9}Fe_{0.1}WO_4$ arises below 12 K in…

Strongly Correlated Electrons · Physics 2008-03-08 R. P. Chaudhury , B. Lorenz , Y. Q. Wang , Y. Y. Sun , C. W. Chu