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The structure and ground state electronic structure of the recently synthesized SrPdO$_3$ perovskite [A. Galal {\em et al.}, J. Power Sources, {\bf 195}, 3806 (2010)] have been studied by means of screened hybrid functional and the GW…

Materials Science · Physics 2015-06-18 Jiangang He , Cesare Franchini

In this work we used $\textit{ab-initio}$ random structure searching (AIRSS) to carry out a systematic search for crystalline Na-Ge materials at both 0 and 10 GPa. The high-throughput structural relaxations were accelerated using a…

Materials Science · Physics 2024-02-26 James P. Darby , Angela F. Harper , Joseph R. Nelson , Andrew J. Morris

Silver-based chalcohalide anti-perovskites (CAP), Ag$_{3}$BC (B = S, Se; C = Cl, Br, I), represent an emerging family of energy materials with intriguing optoelectronic, vibrational and ionic transport properties. However, the structural…

The compressed hydrogen-rich compounds have received extensive attention as promising candidates for room temperature superconductivity, however, the high pressure required to stabilize such materials hinders their wide practical…

Superconductivity · Physics 2023-11-14 Wendi Zhao , Defang Duan , Decheng An , Qiwen Jiang , Zhengtao Liu , Tiancheng Ma , Zihao Huo , Jianhui Du , Tian Cui

Noble metals adopt close-packed structures at ambient pressure and rarely undergo structural transformation at high pressures. Platinum (Pt), in particular, is normally considered to be unreactive and is therefore not expected to form…

Superconductivity · Physics 2015-03-19 Duck Young Kim , Ralph H. Scheicher , Chris J. Pickard , R. J. Needs , R. Ahuja

The widely used crystal structures for both heptazine-based and triazine-based two-dimensional (2D) graphitic carbon nitride (g-C$_3$N$_4$) are the flat P-6m2 configurations. However, the experimentally synthesized 2D g-C$_3$N$_4$ possess…

Materials Science · Physics 2021-02-03 Luneng zhao , Xizhi Shi , Jin Li , Tao Ouyang , Chunxiao Zhang , Chao Tang , Chaoyu He , Jianxin Zhong

Lithium (Li) is a prototypical simple metal at ambient conditions, but exhibits remarkable changes in structural and electronic properties under compression. There has been intense debate about the structure of dense Li, and recent…

Materials Science · Physics 2023-06-21 Xiaoyang Wang , Zhenyu Wang , Pengyue Gao , Chengqian Zhang , Jian Lv , Han Wang , Haifeng Liu , Yanchao Wang , Yanming Ma

In materials science, it is often assumed that ground state crystal structures predicted by density functional theory are the easiest polymorphs to synthesize. Ternary nitride materials, with many possible metastable polymorphs, provide a…

Alkali doped aromatic compounds have shown evidence of metallic and superconducting phases whose precise nature is still mysterious. In potassium and rubidium doped phenanthrene, superconducting temperatures around 5 K have been detected,…

Materials Science · Physics 2014-08-28 S. Shahab Naghavi , Erio Tosatti

A multitude of observed boron-based materials have outstanding superconducting, mechanical, and refractory properties. Yet, the structure, the composition, and the very existence of some reported metal boride (M-B) compounds have been a…

Materials Science · Physics 2014-10-03 A. G. Van Der Geest , A. N. Kolmogorov

We present a structural analysis of the substituted system (Ba$_{1-x}$Sr$_{x}$)CuSi$_{2}$O$_{6}$, which reveals a stable tetragonal crystal structure down to 1.5 K. We explore the structural details with lowtemperature neutron and…

We have systematically searched for the ground state structures of bismuth hydrides based on evolutionary algorithm method and particle swarm optimization algorithm method. Given only rich-hydrogen region, except for BiH$_{3}$, other…

Superconductivity · Physics 2015-11-18 Yanbin Ma , Defang Duan , Da Li , Yunxian Liu , Fubo Tian , Hongyu Yu , Chunhong Xu , Ziji Shao , Bingbing Liu , Tian Cui

We propose three new phases of H2O under ultrahigh pressure. Our structural search was performed using an adaptive genetic algorithm which allows an extensive exploration of crystal structure. The new sequence of pressure-induced…

Materials Science · Physics 2013-05-29 Min Ji , Koichiro Umemoto , Cai-Zhuang Wang , Kai-Ming Ho , Renata M. Wentzcovitch

With the motivation of discovering high-temperature superconductors, evolutionary algorithm is employed to search for all stable compounds in the Sn-H system. In addition to the traditional SnH$_4$, new hydrides SnH$_8$, SnH$_{12}$ and…

We present a comparative study of the high-pressure behaviours of the nuclear waste immobilisation materials zirconolite-2M, -4M, -3O, and -3T. The materials are studied under high-pressure conditions using synchrotron powder X-ray…

The discovery of superconductivity at 200 K in the hydrogen sulfide system at large pressures [1] was a clear demonstration that hydrogen-rich materials can be high-temperature superconductors. The recent synthesis of LaH$_{10}$ with a…

The low-pressure stabilization of superconducting hydrides with high critical temperatures ($T_c$s) remains a significant challenge, and experimentally verified superconducting hydrides are generally constrained to a limited number of…

This paper presents the results of an extensive structural search of ternary solids containing lutetium, nitrogen and hydrogen. Based on thousands of thermodynamically stable structures, available online, the convex hull of the formation…

Superconductivity · Physics 2024-12-06 Moritz Gubler , Marco Krummenacher , Jonas A. Finkler , Stefan Goedecker

Samarium hydrides, belonging to the broad class of lanthanide polyhydrides, have yet to be experimentally tested at high pressure. In this study, we use random structure searches to explore multiple possible stoichiometries and propose…

Strongly Correlated Electrons · Physics 2023-08-23 Zelong Zhao , Siyu Chen , Bartomeu Monserrat , Evgeny Plekhanov , Cedric Weber

Zirconia (ZrO2) is an important material with technological applications which are affected by point defect physics. Ab-initio calculations are performed to understand the structural and electronic properties of oxygen vacancies and…

Materials Science · Physics 2010-09-29 Amit Samanta , Thomas Lenosky , Ju Li