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We have performed total-energy density-functional calculations using first-principles pseudopotentials to determine the atomic and electronic structure of neutral surface and subsurface vacancies at the GaP(110) surface. The cation as well…

Materials Science · Physics 2009-10-30 G. Schwarz , A. Kley , J. Neugebauer , M. Scheffler

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can enable novel device applications and allow for the exploration of new physical…

Mesoscale and Nanoscale Physics · Physics 2017-04-21 Bingchen Deng , Vy Tran , Hao Jiang , Cheng Li , Yujun Xie , Qiushi Guo , Xiaomu Wang , He Tian , Han Wang , Judy J. Cha , Qiangfei Xia , Li Yang , Fengnian Xia

Black phosphorus (BP) is a layered material with anisotropic properties. We study interfaces formed by a pentacene monolayer adsorbed on monolayer BP, a prototypical system for BP surface passivation. We place the pentacene monolayer along…

Materials Science · Physics 2022-12-09 Naseem Ud Din , Zhen-Fei Liu

We substitute individual Pt atoms into monolayer MoS$_2$ and study the resulting atomic structures with single-sideband (SSB) ptychography supported by ab initio simulations. We demonstrate that while high-angle annular dark-field (HAADF)…

We investigate theoretically the anisotropic electronic and optical behaviors of a monolayer black phosphorus (phosphorene) modulated by periodic potential superlattices in arbitrary directions. We demonstrate that different strength and…

Mesoscale and Nanoscale Physics · Physics 2019-12-17 Xiaojing Li , Wen Yang , Kun Luo , Zhenhua Wu

Recent experimental measurements of light absorption in few-layer black phosphorus (BP) reveal a series of high and sharp peaks, interspersed by pairs of lower and broader features. Here, we propose a theoretical model for these excitonic…

Mesoscale and Nanoscale Physics · Physics 2021-05-12 A. Chaves , G. O. Sousa , K. Khaliji , D. R. da Costa , G. A. Farias , Tony Low

Two-dimensional materials supporting deep-subwavelength plasmonic modes can also exhibit strong magneto-optical responses. Here, we theoretically investigate magnetoplasmons (MPs) in monolayer black phosphorus (BP) structures under moderate…

We propose here a two-dimensional material based on a single layer of violet or Hittorf's phosphorus. Using first-principles density functional theory, we find it to be energetically very stable, comparable to other previously proposed…

Materials Science · Physics 2016-06-13 Georg Schusteritsch , Martin Uhrin , Chris J. Pickard

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

We explore the combined impact of sulfur vacancies and electronic interactions on the optical properties of monolayer MoS$_2$. First, we present a generalized Anderson-Hubbard Hamiltonian that accounts for both randomly distributed sulfur…

Disordered Systems and Neural Networks · Physics 2018-06-06 C. E. Ekuma , D. Gunlycke

We study theoretically the structural and electronic response of layered bulk black phosphorus to in-layer strain. Ab initio density functional theory (DFT) calculations reveal that the strain energy and interlayer spacing display a strong…

Materials Science · Physics 2016-10-04 Jie Guan , Wenshen Song , Li Yang , David Tomanek

Using hybrid density functional theory combined with a semiempirical van der Waals dispersion correction, we have investigated the structural and electronic properties of vacancies and self-interstitials in defective few-layer phosphorene.…

Materials Science · Physics 2015-08-21 V. Wang , Y. Kawazoe , W. T. Geng

Black phosphorus (BP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted,…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 Mazhar Chebl , Xing He , Ding-Shyue Yang

Recently, it was demonstrated that a graphene/dielectric/metal configuration can support acoustic plasmons, which exhibit extreme plasmon confinement an order of magnitude higher than that of conventional graphene plasmons. Here, we…

Mesoscale and Nanoscale Physics · Physics 2018-06-22 In-Ho Lee , Luis Martin-Moreno , Daniel A. Mohr , Kaveh Khaliji , Tony Low , Sang-Hyun Oh

We investigate the electronic properties of $N$-layer black phosphorus by means of an analytical method based on a recently proposed tight-binding Hamiltonian involving $14$ hopping parameters. The method provides simple and accurate…

Mesoscale and Nanoscale Physics · Physics 2017-10-18 D. J. P. de Souza , L. V. de Castro , D. R. da Costa , J. Milton Pereira , Tony Low

Black phosphorus (BP) has recently emerged as an alternative 2D semiconductor owing to its fascinating electronic properties such as tunable bandgap and high charge carrier mobility. The structural investigation of few-layer BP, such as…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 Yangjin Lee , Jun-Yeong Yoon , Declan Scullion , Jeongsu Jang , Elton J G Santos , Hu Young Jeong , Kwanpyo Kim

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

Using density functional tight-binding method, we studied the mechanical properties, deformation and failure of armchair (AC) and zigzag (ZZ) phosphorene nanotubes (PNTs) with monovacancies and divacancies subjected to uniaxial tensile…

Materials Science · Physics 2018-05-09 V. Sorkin , Y. W. Zhang

We report an approach for three-dimensional imaging of single vacancies using high precision quantitative high-angle annular dark-field Z-contrast scanning transmission electron microscopy (STEM). Vacancies are identified by both the…

The possibility of an inhomogeneous charge density wave phase is investigated in a system of two coupled electron and hole monolayers separated by a hexagonal boron nitride insulating layer. The charge density wave state is induced through…

Mesoscale and Nanoscale Physics · Physics 2018-12-26 S. Saberi-Pouya , M. Zarenia , T. Vazifehshenas , F. M. Peeters