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Related papers: Tetragonal CH3NH3PbI3 Is Ferroelectric

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Hybrid perovskites (CH3NH3PbI3) is one of the most promising novel materials for solar harvesting. Toxicity of lead (Pb), however, has always remained a concern. We investigated the electronic structure of complete replacement of Pb by…

Materials Science · Physics 2016-10-18 Jiban Kangsabanik , Vikram , Aftab Alam

Recent advances of highly efficient solar cells based on organic-inorganic halide perovskites have triggered intense research efforts to establish the fundamental properties of these materials. In this work, we utilized diamond anvil cell…

Materials Science · Physics 2015-09-15 Kai Wang , Ran Liu , Yuancun Qiao , Jinxing Cui , Bo Song , Bingbing Liu , Bo Zou

Hybrid organic-inorganic halide perovskites with the prototype material of CH$_{3}$NH$_{3}$PbI$_{3}$ have recently attracted intense interest as low-cost and high-performance photovoltaic absorbers. Despite the high power conversion…

Materials Science · Physics 2017-05-30 Xin-Gang Zhao , Ji-Hui Yang , Yuhao Fu , Dongwen Yang , Qiaoling Xu , Liping Yu , Su-Huai Wei , Lijun Zhang

Hybrid AMX3 perovskites (A=Cs, CH3NH3; M=Sn, Pb; X=halide) have revolutionized the scenario of emerging photovoltaic technologies. Introduced in 2009 by Kojima et al., a rapid evolution very recently led to 15% efficient solar cells.…

Materials Science · Physics 2014-10-08 Paolo Umari , Edoardo Mosconi , Filippo De Angelis

Metal halide perovskites APbX3 (A+ = FA+ (formamidinium), MA+ (methylammonium) or Cs+, X- = I-, Br-) are considered as prominent innovative components in nowadays perovskite solar cells. Crystallization of these materials is often…

We report a model describing the molecular orientation disorder in CH3NH3PbI3, solving a classical Hamiltonian parametrised with electronic structure calculations, with the nature of the motions informed by ab-initio molecular dynamics. We…

Mesoscale and Nanoscale Physics · Physics 2014-12-15 Jarvist M. Frost , Keith T. Butler , Aron Walsh

Despite the widespread use of solution-processable hybrid organic-inorganic perovskites in photovoltaic and light-emitting applications, determination of their intrinsic charge transport parameters has been elusive due to the variability of…

Materials Science · Physics 2019-06-26 Xin Yu Chin , Daniele Cortecchia , Jun Yin , Annalisa Bruno , Cesare Soci

Methylammonium lead iodide (MAPI) is a benchmark hybrid organic perovskite material, which is used for the low-cost, printed solar cells with over 20 percent power conversion efficiency. Yet, the nature of light-matter interaction in MAPI…

Organic-inorganic metal halide perovskite devices have generated significant interest for LED, photodetector, and solar cell applications due to their attractive optoelectronic properties and substrate-choice flexibility1-4. These devices…

Modern photovoltaic devices are often based on a heterojunction structure where two components with different optoelectronic properties are interfaced. The properties of each side of the junction can be tuned by either utilizing different…

Organic-inorganic metal halide perovskites have recently attracted increasing attention as highly efficient light harvesting materials for photovoltaic applications. However, the precise control of crystallization and morphology of…

Great success has been achieved in improving the photovoltaic energy conversion efficiency of the organic-inorganic perovskite-based solar cells, but with very limited knowledge on the thermal transport in hybrid perovskites, which would…

Materials Science · Physics 2016-03-02 Xin Qian , Xiaokun Gu , Ronggui Yang

Stability and toxicity issues with the hybrid lead iodide perovskite MAPbI$_3$ necessitate a hunt for potential alternatives. Here, we shed light on promising photovoltaic properties of gold mixed-valence halide perovskites…

Materials Science · Physics 2020-01-07 Jiban Kangsabanik , Supriti Ghorui , M. Aslam , Aftab Alam

The fabrication of high-quality organic-inorganic hybrid halide perovskite layers is the key prerequisite for the realization of high efficient photon energy harvest and electric energy conversion in their related solar cells. In this…

Materials Science · Physics 2017-08-18 Hao Zhang , Mian Tao , Baizhi Gao , Wei Chen , Qi Li , Qingyu Xu , Shuai Dong

In recent years, halide perovskite-based solar cells have received intensive attention, and demonstrated power conversion efficiency as high as 25.8%. With regard to the toxicity of Pb and the instability of organic elements, all inorganic…

Materials Science · Physics 2022-05-04 Dibyajyoti Saikia , Mahfooz Alam , Jayanta Bera , Atanu Betal , Appala Naidu Gandhi , Satyajit Sahu

Organic-inorganic hybrid perovskites such as methylammonium lead iodide (CH3NH3PbI3) are game-changing semiconductors for solar cells and light-emitting devices owing to their exceptionally long carrier lifetime and diffusion length.…

Halide perovskite solar cells based on CH3NH3PbI3 and related materials have emerged as the most exciting development in the next generation photovoltaic technologies, yet the microscopic phenomena involving photo-carriers, ionic defects,…

Materials Science · Physics 2017-10-17 Jiangyu Li , Boyuan Huang , Ehsan Nasr Esfahani , Linlin Wei , Jianjun Yao , Jinjin Zhao , Wei Chen

Hybrid-halide perovskite (HHP) films exhibit exceptional photo-electric properties. These materials are utilized for highly efficient solar cells and photoconductive technologies. Both ion migration and polarization have been proposed as…

Applied Physics · Physics 2021-04-21 Rohit Saraf , Cecile Saguy , Vivek Maheshwari , Hemaprabha Elangovan , Yachin Ivry

Lead halide perovskites (MAPbX3) are known to have high refractive index and controllable bandgap, making them attractive for all-dielectric and tunable metasurfaces. Till now, perovskite metasurfaces have only been used in structural…

Applied Physics · Physics 2019-04-03 Chen Zhang , Yuhan Wang , Yisheng Gao , Yubin Fan , Can Huang , Nan Zhang , Wenhong Yang , Qinghai Song , Shumin Xiao

We report a more than 10-fold enhancement of the piezoelectric coefficient $d_{33}$ of polycrystalline CH$_3$NH$_3$PbI$_3$ (MAPbI$_3$) films when interfacing them with ferroelectric PbZr$_{0.2}$Ti$_{0.8}$O$_3$ (PZT). Piezo-response force…

Materials Science · Physics 2018-06-12 Jingfeng Song , Zhiyong Xiao , Bo Chen , Spencer Prockish , Xuegang Chen , Jinsong Huang , Xia Hong