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Accurate prediction of metal-oxide adhesion in high-entropy alloys (HEAs) is challenging because interfacial segregation, atomic environments, and macroscopic thermodynamic quantities are strongly correlated. Relying solely on…

Materials Science · Physics 2026-03-06 Dennis Boakye , Chuang Deng

Reducing the number of candidate structures is crucial to improve the efficiency of global optimization. Herein, we demonstrate that the generalized Hamiltonian can be described by the atom classification model (ACM) based on symmetry,…

Materials Science · Physics 2022-07-06 Yu-Jie Cen , Chang-chun He , Shao-Bin Qiu , Yu-Jun Zhao , Xiao-Bao Yang

The predictive accuracy of density functional theory (DFT) for alloy formation enthalpies is often limited by intrinsic energy resolution errors, particularly in ternary phase stability calculations. In this work, we present a machine…

Materials Science · Physics 2025-03-10 Sergei I. Simak , Erna K. Delczeg-Czirjak , Olle Eriksson

Exploring the vast composition space of multi-component alloys presents a challenging task for both \textit{ab initio} (first principles) and experimental methods due to the time-consuming procedures involved. This ultimately impedes the…

We develop a method combining machine learning (ML) and density functional theory (DFT) to predict low-energy polymorphs by introducing physics-guided descriptors based on structural distortion modes. We systematically generate crystal…

Materials Science · Physics 2022-09-07 Bastien F. Grosso , Nicola A. Spaldin , Aria Mansouri Tehrani

In this work, we use density functional theory (DFT) to investigate the structural and electronic properties of B$_7$Y$_2$ clusters -- boron frameworks doped with two yttrium atoms. Our results show that the most stable configuration adopts…

Materials Science · Physics 2025-04-29 Peter Ludwig Rodríguez-Kessler

We use high-throughput first-principles sampling to investigate competitive factors that determine the crystal structure of high-entropy alloys (HEAs) and the energetics dependence of the stable phase on the atomic configuration of fully…

Materials Science · Physics 2022-01-03 Hiroshi Mizuseki , Ryoji Sahara , Kenta Hongo

In this work, we employ density functional theory (DFT) to explore the structure of boron clusters doped with two chromium atoms (B$_7$Cr$_2$). The results show that the most stable structure is a bipyramidal configuration formed by a B$_7$…

Materials Science · Physics 2024-07-31 P. L. Rodríguez-Kessler

We report the effects of lattice dynamics on thermodynamic stability of binary $R_{1-x}$Fe$_x$ $(0<x<1)$ compounds ($R$: rare-earth elements, Y, Ce, Nd, Sm, and Dy) at finite temperature predicted by first-principles calculation based on…

Materials Science · Physics 2021-12-10 Guangzong Xing , Takahiro Ishikawa , Yoshio Miura , Takashi Miyake , Terumasa Tadano

The development of machine learning sheds new light on the problem of statistical thermodynamics in multicomponent alloys. However, a data-driven approach to construct the effective Hamiltonian requires sufficiently large data sets, which…

Materials Science · Physics 2020-01-01 Xianglin Liu , Jiaxin Zhang , Markus Eisenbach , Yang Wang

In this study Mo-Nb-Ta-W refractory high-entropy alloys (R-HEAs) have been studied for their phase stability for a wide temperature range (100 K to 2000 K). The equilibrium thermodynamic phases are determined by the changes in enthalpy and…

Materials Science · Physics 2021-03-16 Varnita Bajpai , Soumyadipta Maiti , Shashank Mishra , Beena Rai

The ordered structure of MgO-ZnO alloy system is a versatile tunable optical material promising for diverse optoelectronic applications. However, isovalent and isostructural alloy compositions of MgO-ZnO are generally unstable at ambient…

Materials Science · Physics 2020-02-26 K. Aziz , C. E. Ekuma

This work is motivated by the need for large-scale simulations to extract physical information on the iron-chromium system that is a binary model alloy for ferritic steels used or proposed in many nuclear applications. From first-principles…

Materials Science · Physics 2013-07-30 Maximilien Levesque , Enrique Martínez , Chu-Chun Fu , Maylise Nastar , Frédéric Soisson

We present an ab-initio-based effective interaction model (EIM) for the study of magnetism, thermodynamics, and their interplay in body-centered cubic Fe-Co alloys, with Co content from 0 to 70%. The model includes explicitly both spin and…

Materials Science · Physics 2020-01-16 Van-Truong Tran , Chu-Chun Fu , Anton Schneider

In computational materials science, a common means for predicting macroscopic (e.g., mechanical) properties of an alloy is to define a model using combinations of descriptors that depend on some material properties (elastic constants,…

Materials Science · Physics 2022-10-17 Ivan Novikov , Olga Kovalyova , Alexander Shapeev , Max Hodapp

Stacking fault energy (SFE) is an essential parameter for characterizing mechanical properties. However, in high entropy alloys (HEAs), the local chemical environment varies significantly across different stacking fault planes, resulting in…

Materials Science · Physics 2023-03-28 Cong Ma , Wang Gao , Qing Jiang

High entropy alloys (HEA) show promise as a new type of high-performance structural material. Their vast degrees of freedom provide for extensive opportunities to design alloys with tailored properties. However, the compositional…

Disordered Systems and Neural Networks · Physics 2019-04-19 Qi Jie , Andrew Cheung , S. Joseph Poon

Eutectic high entropy alloys (EHEAs) are emerging as an exciting new class of structural alloys as they have shown very promising mechanical properties. However, how to design these alloys has been a challenge. In this work, a simple…

Materials Science · Physics 2022-10-19 Ali Shafiei

In this work, high throughput DFT calculations are performed on the alkali metal-based half Heusler alloys; LiY$_p$Y$^\prime_{1-p}$S (Y, Y$^\prime$ = V, Cr, Mn, Fe, Co, Ni and $\mathit{p}$ = 0, 0.25, 0.5, 0.75, 1). Starting with 243…

Materials Science · Physics 2022-03-23 Rohit Pathak , Parul R. Raghuvanshi , Amrita Bhattacharya

Various methods going beyond density-functional theory (DFT), such as DFT+U, hybrid functionals, meta-GGAs, GW, and DFT-embedded dynamical mean field theory (eDMFT), have been developed to describe the electronic structure of correlated…

Strongly Correlated Electrons · Physics 2020-07-16 Subhasish Mandal , Kristjan Haule , Karin M. Rabe , David Vanderbilt