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Electronic structure calculations are used to examine the magnetic properties of Fe$_2$P-based alloys and the mechanisms through which the Curie temperature and magnetocrystalline anisotropy can be optimized for specific applications. It is…

Materials Science · Physics 2017-10-18 I. A. Zhuravlev , V. P. Antropov , A. Vishina , M. van Schilfgaarde , K. D. Belashchenko

Multi-principal-element alloys, including high-entropy alloys, experience segregation or partially-ordering as they are cooled to lower temperatures. For Ti$_{0.25}$CrFeNiAl$_{x}$, experiments suggest a partially-ordered B2 phase, whereas…

Materials Science · Physics 2021-05-11 Prashant Singh , A. V. Smirnov , Aftab Alam , Duane D. Johnson

Active, selective and stable catalysts are imperative for sustainable energy conversion, and engineering materials with such properties are highly desired. High-entropy alloys (HEAs) offer a vast compositional space for tuning such…

Surface energies of metal-based systems are important for determining the Wulff-constructed shapes of metal nanoparticles and understanding the stability. We have developed a coordination number-based model to predict the total energy of…

Materials Science · Physics 2025-06-19 Shyama Charan Mandal , Frank Abild-Pedersen

Multi-principal element alloys open large composition spaces for alloy development. The large compositional space necessitates rapid synthesis and characterization to identify promising materials, as well as predictive strategies for alloy…

In this study, we employ density functional theory (DFT) to investigate the structural and electronic properties B$_8$Cu$_3^-$ clusters -- boron-based frameworks doped with three copper atoms. The results indicate that the lowest-energy…

Materials Science · Physics 2025-05-22 P. L. Rodríguez-Kessler

In the present work, the ideal shear strength ({\tau}_is) of dilute Ni34XZ ternary alloys (X or Z = Al, Co, Cr, Fe, Mn, Mo, Nb, Si, Ti) are predicted by first-principles calculations based on density functional theory (DFT) in terms of pure…

Materials Science · Physics 2024-12-12 Shuang Lin , Shun-Li Shang , John D. Shimanek , Yi Wang , Allison M. Beese , Zi-Kui Liu

It has been known that even though two elemental metals, $X$ and $Y$, are immiscible, they can form alloys on surfaces of other metal $Z$. In order to understand such surface alloying of immiscible metals, we study the energetic stability…

Materials Science · Physics 2021-02-01 Shota Ono , Junji Yuhara , Jun Onoe

The Work function (f)is fundamental for chemistry and electronics. Additionally, f can be used to examine the validity of the theoretical surfaces by comparing it with experimental f, even in the absence of long-range orders. In the…

Materials Science · Physics 2025-07-10 Yukio Watanabe , S. Miyauchi , S. Kaku , T. Yamada , A. Horiguchi

We employ a descriptor based machine-learning approach to assess the effect of chemical alloying on formation-enthalpy of rare-earth intermetallics. Application of machine-learning approaches in rare-earth intermetallic design have been…

Materials Science · Physics 2022-03-07 Prashant Singh , Tyler Del Rose , Guillermo Vazquez , Raymundo Arroyave , Yaroslav Mudryk

Among the ferromagnetic binary alloys, body centered cubic (bcc) Fe-Co is the one showing the highest magnetization. It is known experimentally that ordered Fe-Co structures show a larger magnetization than the random solid solutions with…

Materials Science · Physics 2019-03-28 Van-Truong Tran , Chu-Chun Fu , Kangming Li

Machine learning has emerged as a novel tool for the efficient prediction of materials properties, and claims have been made that machine-learned models for the formation energy of compounds can approach the accuracy of Density Functional…

Materials Science · Physics 2020-07-14 Christopher J. Bartel , Amalie Trewartha , Qi Wang , Alexander Dunn , Anubhav Jain , Gerbrand Ceder

Herein, the structure and stability of double icosahedron Ag$_{17}$M$_2$ (M = Ni, Cu, Zn) clusters are investigated using density functional theory (DFT) computations. The results indicate that the clusters favor endohedral configurations…

Atomic and Molecular Clusters · Physics 2025-03-10 Peter Ludwig Rodríguez-Kessler

The binary manganese aluminium (MnAl) alloy with L$1_0$ crystal structure is a promising rare earth element-free permanent magnetic material because of its exceptional magnetic properties. However, experimentally synthesizing it in a stable…

Materials Science · Physics 2024-08-01 Churna Bhandari , Gavin N. Nope , T. Lograsso , Durga Paudyal

Density functional theory (DFT) is the de facto approach for predicting self-consistent-field electronic structures of ground-state configurations of complex atoms, molecules, and solids and providing their property data for materials…

Materials Science · Physics 2024-01-30 Zi-Kui Liu

Entropic contributions to the stability of solids are very well understood and the mixing entropy has been used for forming various solids, for instance such as inverse spinels. A particular development was related to high entropy alloys in…

Materials Science · Physics 2019-10-23 David Berardan , Sylvain Franger , Diana Dragoe , Arun Kumar Meena , Nita Dragoe

We show that the magnetic properties of high-entropy alloys (HEAs) can be captured by \textit{ab initio} calculations within the coherent potential approximation, where the atomic details of the high-entropy mixing are considered as an…

Materials Science · Physics 2025-12-30 Dinesh Bista , Willie B. Beeson , Turbasu Sengupta , Jerome Jackson , Shiv N Khanna , Kai Liu , Gen Yin

To quickly screen for single-phased multi-principal-element materials, a so-called entropy forming ability (EFA) parameter is sometimes used as a descriptor. The higher the EFA, the higher is the propensity to form a single-phase structure,…

Materials Science · Physics 2023-05-12 Andreas Kretschmer , Paul Heinz Mayrhofer

The performance of density functional theory (DFT) approximations for predicting materials thermodynamics is typically assessed by comparing calculated and experimentally determined enthalpies of formation from elemental phases, {\Delta}Hf.…

Materials Science · Physics 2019-01-08 Christopher J. Bartel , Alan W. Weimer , Stephan Lany , Charles B. Musgrave , Aaron M. Holder

In pursuit of a colloidal analogue to quantum density functional theory (DFT) predictions of atomic crystal structures, we report a new, classical DFT that predicts the relative thermodynamic stability of colloidal crystals of hard, convex…

Soft Condensed Matter · Physics 2026-01-15 Kristi Pepa , Isaac R. Spivack , Trevor F. G. Teague , Ryn Y. Oliphant , Domagoj Fijan , Sharon C. Glotzer