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Lithium-ion (Li-ion) batteries are ubiquitous in modern energy storage systems, highlighting the critical need to comprehend and optimize their performance. Yet, battery models often exhibit poor parameter identifiability which hinders the…

Systems and Control · Electrical Eng. & Systems 2024-06-14 Jorge Espin , Yuichi Kajiura , Dong Zhang

We consider the problem of parameterizing Newman-type models of Li-ion batteries focusing on quantifying the inherent uncertainty of this process and its dependence on the discharge rate. In order to rule out genuine experimental error and…

Computational Physics · Physics 2021-04-14 Jose Morales Escalante , Smita Sahu , Jamie M. Foster , Bartosz Protas

Accurate identification of lithium-ion battery parameters is essential for estimating battery states and managing performance. However, the variation of battery parameters over the state of charge (SOC) and the nonlinear dependence of the…

Systems and Control · Electrical Eng. & Systems 2025-09-26 Yang Wang , Riccardo M. G. Ferrari

Parameter estimation in electrochemical models remains a significant challenge in their application. This study investigates the impact of different operating profiles on electrochemical model parameter estimation to identify the optimal…

Systems and Control · Electrical Eng. & Systems 2025-12-09 Feng Guo , Luis D. Couto , Khiem Trad , Grietus Mulder , Keivan Haghverdi , Guillaume Thenaisie

Battery management systems may rely on mathematical models to provide higher performance than standard charging protocols. Electrochemical models allow us to capture the phenomena occurring inside a lithium-ion cell and therefore, could be…

Computational Engineering, Finance, and Science · Computer Science 2020-05-12 Andrea Pozzi , Xiangzhong Xie , Davide M Raimondo , René Schenkendorf

This paper examines the problem of estimating the parameters of a Lithium-Sulfur (LiS) battery from experimental cycling data. LiS batteries are attractive compared to traditional Lithium-Ion batteries, thanks largely to their potential to…

Systems and Control · Electrical Eng. & Systems 2021-02-17 Chu Xu , Timothy Cleary , Guoxing Li , Donghai Wang , Hosam K. Fathy

Accurate parameter dependent electro-chemical numerical models for lithium-ion batteries are essential in industrial application. The exact parameters of each battery cell are unknown and a process of estimation is necessary to infer them.…

Statistics Theory · Mathematics 2024-04-25 Andrea Petrocchi , Matthias K. Scharrer , Franz Pichler , Stefan Volkwein

This study evaluates numerical discretization methods for the Single Particle Model (SPM) used in electrochemical modeling. The methods include the Finite Difference Method (FDM), spectral methods, Pad\'e approximation, and parabolic…

Systems and Control · Electrical Eng. & Systems 2025-06-03 Feng Guo , Luis D. Couto

This work presents a comparative study of optimization techniques for parameter identification in equivalent electrical models of lithium-ion batteries. The 2RC model is applied to a set of twelve batteries using four publicly available…

Optimization and Control · Mathematics 2025-12-03 Johan Sebastian Suarez Sepúlveda , Edgar Hernando Sepúlveda-Oviedo , Bruno Jammes , Corinne Alonso

The feasibility of uniquely estimating parameters of dynamical systems from observations is a widely discussed aspect of mathematical modelling. Several approaches have been published for analyzing identifiability. However, they are…

Methodology · Statistics 2017-08-14 Clemens Kreutz

Interpreting data with mathematical models is an important aspect of real-world industrial and applied mathematical modeling. Often we are interested to understand the extent to which a particular set of data informs and constrains model…

Methodology · Statistics 2025-03-06 Matthew J Simpson , Ruth E Baker

Electrochemical Impedance Spectroscopy (EIS) and Equivalent Circuit Models (ECMs) are widely used to characterize the impedance and estimate parameters of electrochemical systems such as batteries. We use a generic ECM with ten parameters…

Systems and Control · Electrical Eng. & Systems 2024-03-18 Vladimir Sovljanski , Mario Paolone

Accurately predicting aging of lithium-ion batteries would help to prolong their lifespan, but remains a challenge owing to the complexity and interrelation of different aging mechanisms. As a result, aging prediction often relies on…

Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a…

Systems and Control · Electrical Eng. & Systems 2021-06-25 Anirudh Allam , Simona Onori

Batteries are nonlinear dynamical systems that can be modeled by Porous Electrode Theory models. The aim of optimal fast charging is to reduce the charging time while keeping battery degradation low. Most past studies assume that model…

Systems and Control · Electrical Eng. & Systems 2024-10-14 Minsu Kim , Joachim Schaeffer , Marc D. Berliner , Berta Pedret Sagnier , Rolf Findeisen , Richard D. Braatz

This paper investigates the identification of observable low-frequency (LF) parameters of battery cell's equivalent circuit models (ECMs) using time-domain voltage and current measurements sampled at low frequency by built-in battery…

Systems and Control · Electrical Eng. & Systems 2026-05-29 Vladimir Sovljanski , Mario Paolone

This contribution presents a diagnosis scheme for batteries to detect and isolate internal faults in the form of small parameter changes. This scheme is based on an electrochemical reduced-order model of the battery, which allows the…

Systems and Control · Electrical Eng. & Systems 2021-03-19 Luis D. Couto , Jorn M. Reniers , David A. Howey , Michel Kinnaert

Electrochemical hybrid battery models have major potential to enable advanced physics-based control, diagnostic, and prognostic features for next-generation lithium-ion battery management systems. This is due to the physical significance of…

Systems and Control · Electrical Eng. & Systems 2025-05-13 Jackson Fogelquist , Xinfan Lin

This paper presents experimental validation of a time-domain load parameter determination method for single-phase circuits. The verification is performed in a state-of-the-art smart grid laboratory equipped with power hardware and real-time…

This letter proposes a lightweight, model-free online diagnostic framework for detecting internal short circuits (ISC) in single lithium-ion cells under dynamic operating conditions. The core of the method lies in computing the first-order…

Systems and Control · Electrical Eng. & Systems 2025-06-17 Yangyang Xu , Chenglin Liao