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Obtaining full control over the internal and external quantum states of molecules is the central goal of ultracold chemistry and allows for the study of coherent molecular dynamics, collisions and tests of fundamental laws of physics. When…

We demonstrate Rydberg blockade due to the charge-dipole interaction between a single Rb atom and a single RbCs molecule confined in optical tweezers. The molecule is formed by magnetoassociation of a Rb+Cs atom pair and subsequently…

We study the Rydberg blockade in a system of three atoms arranged in different 2D geometries (linear and triangular configurations). In the strong blockade regime, we observe high-contrast, coherent collective oscillations of the single…

We report the observation of spin-singlet ultra-long range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}$Rb Rydberg electrons from $^{87}$Rb(5s) atoms. A three-photon…

The internal electric field of a Rydberg atom electron can bind a polar molecule to form a giant ultralong-range stable polyatomic molecule. Such molecules not only share their properties with Rydberg atoms, they possess huge permanent…

Atomic Physics · Physics 2015-05-27 Seth T. Rittenhouse , M. Mayle , P. Schmelcher , H. R. Sadeghpour

Resonant laser excitation of multiple Rydberg atoms are prohibited, leading to Rydberg blockade, when the long-range van der Waals interactions are stronger than the laser-atom coupling. Rydberg blockade can be violated, i.e. simultaneous…

Quantum Physics · Physics 2021-10-04 Shi-Lei Su , Weibin Li

We present the experimental observation of the antiblockade in an ultracold Rydberg gas recently proposed by Ates et al. [Phys. Rev. Lett. 98, 023002 (2007)]. Our approach allows the control of the pair distribution in the gas and is based…

Atomic Physics · Physics 2015-05-14 Thomas Amthor , Christian Giese , Christoph S. Hofmann , Matthias Weidemüller

One of the most striking features of the strong interactions between Rydberg atoms is the dipole blockade effect, which allows only a single excitation to the Rydberg state within the volume of the blockade sphere. Here we present a method…

Quantum Gases · Physics 2015-06-16 M. M. Valado , N. Malossi , S. Scotto , D. Ciampini , E. Arimondo , O. Morsch

Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…

Atomic Physics · Physics 2023-02-23 Frederic Hummel , Peter Schmelcher , Matthew T. Eiles

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

We investigate the collective excitation effect in a scheme where three identical Rydberg atoms are arranged in an equilateral triangular lattice. By using a static electric field polarizing the atomic dipoles, the dipole-dipole…

Atomic Physics · Physics 2016-08-24 Jing Qian

We review here the studies performed about interactions in an assembly of cold Rydberg atoms. We focus more specially the review on the dipole-dipole interactions and on the effect of the dipole blockade in the laser Rydberg excitation,…

Atomic Physics · Physics 2010-06-07 Daniel Comparat , Pierre Pillet

We present a combined experimental and theoretical study of the effects of Rydberg interactions on Autler-Townes spectra of ultracold gases of atomic strontium. Realizing two-photon Rydberg excitation via a long-lived triplet state allows…

Cold atomic gases resonantly excited to Rydberg states can exhibit strong optical nonlinearity at the single photon level. We observe that in such samples radiation trapping leads to an additional mechanism for Rydberg excitation.…

Atomic Physics · Physics 2017-03-16 D. P. Sadler , E. M. Bridge , D. Boddy , A. D. Bounds , N. C. Keegan , G. Lochead , M. P. A. Jones , B. Olmos

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

Atomic Physics · Physics 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

We explore the external electric field control of a species of ultralong-range molecules that emerge from the interaction of a ground state polar molecule with a Rydberg atom. The external field mixes the Rydberg electronic states and…

Atomic Physics · Physics 2012-06-01 M. Mayle , S. T. Rittenhouse , P. Schmelcher , H. R. Sadeghpour

Recent developments in the study of ultracold Rydberg gases demand an advanced level of experimental sophistication, in which high atomic and optical densities must be combined with excellent control of external fields and sensitive Rydberg…

The resonant dipole-dipole interaction between highly excited Rydberg levels dominates the interaction of neutral atoms at short distances scaling as $1/r^3$. Here we take advantage of the combined effects of strong dipole-dipole…

Quantum Physics · Physics 2020-12-30 Xiao-Qiang Shao

We discuss laser dressed dipolar and Van der Waals interactions between atoms and polar molecules, so that a cold atomic gas with laser admixed Rydberg levels acts as a designed reservoir for both elastic and inelastic collisional…

Atomic Physics · Physics 2012-05-15 Bo Zhao , Alexander Glätzle , Guido Pupillo , Peter Zoller

The formation of ultralong-range Rydberg molecules is a result of the attractive interaction between Rydberg electron and polarizable ground state atom in an ultracold gas. In the nondegenerate case the backaction of the polarizable atom on…

Atomic Physics · Physics 2015-07-10 A. Gaj , A. T. Krupp , P. Ilzhöfer , R. Löw , S. Hofferberth , T. Pfau
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