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We present a universal thermodynamic framework for quantum systems that may be strongly coupled to thermal environments. Unlike previous approaches, our method enables a clear definition of thermostatic properties while preserving the same…

Quantum Physics · Physics 2026-04-16 Ignacio González , Sagnik Chakraborty , Ángel Rivas

From the principle of maximum entropy for a closed system in thermal equilibrium, for the first instance a clear relation is shown to exist between total entropy S (in terms of arrangements of particles) and the classical expression for the…

Classical Physics · Physics 2009-11-07 Mario J. Pinheiro

The controversial existence of negative temperatures has stirred interesting debates that have reached the foundations of thermodynamics, including questions on the second law, the Carnot efficiency and the statistical definition of…

Statistical Mechanics · Physics 2019-06-26 Salvatore Calabrese , Amilcare Porporato

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…

Statistical Mechanics · Physics 2009-11-13 Sumiyoshi Abe , Christian Beck , E. G. D. Cohen

The generalized second laws of quantum thermodynamics are usually formulated in terms of R\'enyi divergences and the associated family of generalized free energies. In catalytic thermal transformations, this framework typically certifies…

Quantum Physics · Physics 2026-04-24 Ali Can Günhan , Onur Pusuluk , Thomas Oikonomou , G. Baris Bagci

The entropy of classical thermodynamics is uniquely determined by the relation of adiabatical accessibilty between equilibrium states of thermodynamical systems. This review outlines the logical path leading to this results and the…

Mathematical Physics · Physics 2022-02-17 Jakob Yngvason

We analyze the time-resolved energy transport and the entropy production in ac-driven quantum coherent electron systems coupled to multiple reservoirs at finite temperature. At slow driving we formulate the first and second laws of…

Mesoscale and Nanoscale Physics · Physics 2016-07-27 Maria Florencia Ludovico , Michael Moskalets , David Sanchez , Liliana Arrachea

Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…

Statistical Mechanics · Physics 2020-11-17 Stefan Floerchinger , Tobias Haas

In this paper we study a class of physical systems that combine a finite number of mechanical and thermodynamic observables. We call them finite dimensional thermo-mechanical systems. We introduce these systems by means of simple examples.…

Mathematical Physics · Physics 2016-09-29 Hernán Cendra , Sergio Grillo , Maximiliano Palacios Amaya

The Second Law of Thermodynamics states that the entropy of a closed system is non-decreasing. Discussing the Second Law in the quantum world poses new challenges and provides new opportunities, involving fundamental…

Quantum Physics · Physics 2016-12-01 A. V. Lebedev , D. Oehri , G. B. Lesovik , G. Blatter

Theory of bipartite entanglement shares profound similarities with thermodynamics. In this letter we extend this connection to multipartite quantum systems where entanglement appears in different forms with genuine entanglement being the…

Quantum Physics · Physics 2022-08-31 Samgeeth Puliyil , Manik Banik , Mir Alimuddin

The out-of-equilibrium character of active systems is often twofold, arising from both the activity itself and from non-reciprocal couplings between constituents. A well-established measure to quantify the system's distance from equilibrium…

Statistical Mechanics · Physics 2026-02-13 Kim L. Kreienkamp , Sabine H. L. Klapp

The chemical reactions are very complex, and include oscillation, condensation, catalyst and self-organization, etc. In these case changes of entropy may increase or decrease. The second law of thermodynamics is based on an isolated system…

General Physics · Physics 2008-07-03 Yi-Fang Chang

We extend classical coarse-grained entropy, commonly used in many branches of physics, to the quantum realm. We find two coarse-grainings, one using measurements of local particle numbers and then total energy, and the second using local…

Quantum Physics · Physics 2019-01-17 Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

Far-from-equilibrium thermodynamics underpins the emergence of life, but how has been a long-outstanding puzzle. Best candidate theories based on the maximum entropy production principle could not be unequivocally proven, in part due to…

Quantitative Methods · Quantitative Biology 2017-10-10 Robert G. Endres

Claims of exceptions to the second law of thermodynamics are generally met with extreme skepticism that is quite reasonable given the great confidence placed in the second law. But what specifically is the basis for that confidence? The…

Statistical Mechanics · Physics 2009-11-07 Todd L. Duncan

A general, uniform, rigorous and constructive thermodynamic approach to weakly nonlocal non-equilibrium thermodynamics is reviewed. A method is given to construct and restrict the evolution equations of physical theories according to the…

Classical Physics · Physics 2010-03-15 P. Ván

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

Mathematical Physics · Physics 2022-08-16 Walter F. Wreszinski

We study the nonextensive thermodynamics for open systems. On the basis of the maximum entropy principle, the dual power-law q-distribution functions are re-deduced by using the dual particle number definitions and assuming that the…

Statistical Mechanics · Physics 2020-02-26 Yahui Zheng , Haining Yu , Jiulin Du