Related papers: Trans-cis molecular photoswitching in interstellar…
A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed…
Bose condensed light can form new phases [1] in a dye filled cavity due to the presence of the orientational disorder created by dye molecules which are essentially frozen on the time scale of the photonic thermalization (few ps). At longer…
The opacity due to photodissociation of 24MgH is investigated in the atmospheres of cool stars. The lowest two electronic transitions A 2Pi -- X 2Sigma+ and B' 2Sigma+ -- X 2 Sigma+ are considered where the cross sections for the latter…
A numerical calculation of properties of finite absorbers and of intergalactic medium based on photoionization equilibrium is performed to confront alternative UV sources in addition to quasars. It is seen that a spectrum including a large…
The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compounds toward the Galactic Centre quiescent…
(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…
The UV photon escape fraction from molecular clouds is a key parameter for understanding the ionization of the Interstellar Medium (ISM), and extragalactic processes, such as cosmic reionization. We present the ionizing photon flux and the…
The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…
Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average,…
The Epoch of Reionization marks the last major phase transition in the early Universe, during which the majority of neutral hydrogen once filling the intergalactic medium was ionized by the first galaxies. The James Webb Space Telescope…
We present a detailed calculation of the propagation of AGN-like ionizing radiation through the intergalactic space. We model the ionization state of absorbing clouds, and show that the universe will be more opaque above $4\,$Ryd than…
Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column…
Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is…
We study the chemical evolution of H2O:CO:NH3 ice mixtures irradiated with soft X-rays, in the range 250-1250 eV. We identify many nitrogen-bearing molecules such as e.g., OCN-, NH4+ , HNCO, CH3CN, HCONH2, and NH2COCONH2. Several infrared…
The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…
The Central Molecular Zone (CMZ) contains a substantial reservoir of dense molecular gas, where numerous young stellar objects (YSOs) and dense cloud cores have been identified. However, the large distance and severe foreground extinction…
Aims: Interstellar molecules form early in the evolutionary sequence of interstellar material that eventually forms stars and planets. To understand this evolutionary sequence, it is important to characterize the chemical composition of its…
We wish to relate the degree scale structure of galactic diffuse clouds to sub-arcsecond atomic and molecular absorption spectra obtained against extragalactic continuum background sources. To do this, we used the ARO 12m telescope to map…
Ice mantles detected on the surface of dust grains toward the coldest regions of the interstellar medium can be photoprocessed by the secondary ultraviolet (UV) field present in dense cloud interiors. In this work, we present UV-irradiation…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…