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A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

Astrophysics of Galaxies · Physics 2020-08-19 Mihwa Jin , Robin T. Garrod

We investigate interstellar absorption from molecular hydrogen (H_2) and metals in an intermediate-velocity cloud (IVC) in the direction of the LMC star Sk -68 80 (HD 36521), based on data from the Far Ultraviolet Spectroscopic Explorer…

Astrophysics · Physics 2011-05-23 P. Richter , K. R. Sembach , J. C. Howk

{CircumStellar Envelopes (CSEs) of stars are complex chemical objects for which theoretical models encounter difficulties in elaborating a comprehensive overview of the occurring chemical processes. Along with photodissociation, ion-neutral…

Solar and Stellar Astrophysics · Physics 2022-12-08 Jérémy Bourgalais , David V. Bekaert , Aurore Bacmann , Bernard Marty , Nathalie Carrasco

We present a millimetre molecular line survey of seven high mass loss rate carbon stars in both the northern and southern skies. A total of 196 emission lines (47 transitions) from 24 molecular species were detected. The observed CO…

Astrophysics · Physics 2009-11-07 P. M. Woods , F. L. Schoeier , L. -A. Nyman , H. Olofsson

This work aims to study the unexplained sulfur depletion observed toward dense clouds and protostars. We made simulation experiments of the UV-photoprocessing and sublimation of H2S and H2S:H2O ice in dense clouds and circumstellar regions,…

Earth and Planetary Astrophysics · Physics 2015-06-03 A. Jiménez-Escobar , G. M. Muñoz Caro

We present numerical computations and analysis of atomic to molecular (HI-to-H$_2$) transitions in cool ($\sim$100 K) low-metallicity dust-free (primordial) gas, in which molecule formation occurs via cosmic-ray driven negative ion…

Astrophysics of Galaxies · Physics 2021-10-27 Amiel Sternberg , Alon Gurman , Shmuel Bialy

Formation of interstellar complex organic molecules is currently thought to be dominated by the barrierless coupling between radicals on the interstellar icy grain surfaces. Previous standard DFT results on the reactivity between CH$_3$ and…

Recent observations indicate that star formation occurs only in the molecular phase of a galaxy's interstellar medium. A realistic treatment of star formation in simulations and analytic models of galaxies therefore requires that one…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Mark R. Krumholz , Nickolay Y. Gnedin

We present ISO LWS observations of the proto-planetary nebula CRL 618, a star evolving very fast to the planetary nebula stage. In addition to the lines of 12CO, 13CO, HCN and HNC, we report on the detection of H2O and OH emission together…

Astrophysics · Physics 2009-10-31 F. Herpin , J. Cernicharo

We present the first detection in space of O-protonated carbonyl sulfide (\ch{HOCS+}), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the observation of all $K$$_a$ = 0 transitions ranging…

Conical intersections between electronic states often dictate the chemistry of photoexcited molecules. Recently developed sources of ultrashort extreme ultraviolet (XUV) pulses tuned to element-specific transitions in molecules allow for…

High-Velocity Clouds (HVCs) have radial velocities that cannot be explained by the global Galactic rotation; their distances remain mostly unknown, and their true nature and origin are still a mystery. Some of them could be of galactic…

Astrophysics · Physics 2007-05-23 F. Combes , V. Charmandaris

Collision-induced absorption (CIA) from molecular hydrogen is a dominant opacity source in the atmosphere of cool white dwarfs. It results in a significant flux depletion in the near-IR and IR parts of their spectra. Because of the extreme…

Solar and Stellar Astrophysics · Physics 2017-10-18 Simon Blouin , Piotr M. Kowalski , Patrick Dufour

Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…

Astrophysics of Galaxies · Physics 2020-12-02 Laurie E. U. Chu , Klaus W. Hodapp , A. C. Adwin Boogert

Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…

Astrophysics of Galaxies · Physics 2014-11-20 David A. Neufeld , Mark G. Wolfire

Recent observations of protostars with the James Webb Space Telescope have revealed unprecedented chemical complexity from their ice absorption features. However, these spectra are likely influenced by radiative transfer effects, and there…

Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…

Observations of Carbon bearing species are among the most important diagnostic probes of ongoing star formation. CO is a surrogate for H$_2$ and is found in the vicinity of star formation sites. There, [CI] emission is thought to outline…

Astrophysics · Physics 2017-01-18 H. Jakob , R. Simon , C. Kramer , B. Mookerjea , N. Schneider , S. Bontemps , J. Stutzki

At the high densities and low temperatures found in star forming regions, all molecules other than H2 should stick on dust grains on timescales shorter than the cloud lifetimes. Yet these clouds are detected in the millimeter lines of…

We present Herschel PACS observations of the [CII] 158 micron emission line in a sample of 24 intermediate mass (9<logM$_\ast$/M$_\odot$<10) and low metallicity (0.4< Z/Z$_\odot$<1.0) galaxies from the xCOLD GASS survey. Combining them with…

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