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Defects play a significant role in optical properties of semiconducting two-dimensional transition metal dichalcogenides (TMDCs). In ultra-thin MoSe2, a remarkable feature at ~250 cm-1 in Raman spectra is ascribed to be a defect-related…

Materials Science · Physics 2019-04-23 Shudong Zhao , Meilin Lu , ShaSha Xue , Lin Yan , Peng Miao , Yan Hang , Xianjie Wang , Zhiguo Liu , Yi Wang , Lei Tao , Yu Sui , Yang Wang

Typical Raman spectra of transition metal dichalcogenides (TMDs) display two prominent peaks, E2g and A1g, that are well separated from each other. We find that these modes are degenerate in bulk WSe2 yielding one single Raman peak. As the…

Materials Science · Physics 2013-04-10 H. Sahin , S. Tongay , S. Horzum , W. Fan , J. Zhou , J. Li , J. Wu , F. M. Peeters

The remarkable properties of (1T-)TiSe$_2$ among the transition metal dichalcogenides have attracted the attention of many researchers due to its peculiar behavior during the charge density wave (CDW) transition. Therefore, it is highly…

Materials Science · Physics 2024-02-08 Shin-ichiro Tanaka , Shigemasa Suga , Keiji Ueno , Keisuke Fukutani , Fumihiko Matsui

Tantalum diselenide (TaSe$_{2}$) is a metallic transition metal dichalcogenide whose equilibrium structure and vibrational behavior strongly depends on temperature and thickness, including the emergence of charge density wave (CDW) states…

Germanium Selenide (GeSe) is a van der Waals-bonded layered material with promising optoelectronic properties, which has been experimentally synthesized for 2D semiconductor applications. In the monolayer, due to reduced dimensionality and,…

Materials Science · Physics 2020-07-29 Arielle Cohen , D. Kirk Lewis , Tianlun Huang , Sahar Sharifzadeh

Room temperature ferromagnetism is observed in undoped TiO2 films deposited on Si substrates using pulsed laser deposition (PLD). The ferromagnetic properties of the samples depend on the oxygen partial pressure during the PLD synthesis.…

Materials Science · Physics 2009-11-13 Abdul K Rumaiz , Bakhtyar Ali , Abdullah Ceylan , M. Boggs , T. Beebe , S. Ismat Shah

Layered indium selenide (InSe), a new two-dimensional (2D) material with a hexagonal structure and semiconducting characteristic, is gaining increasing attention owing to its intriguing electronic properties. Here, by using first-principles…

Materials Science · Physics 2017-12-19 Andrey A. Kistanov , Yongqing Cai , Kun Zhou , Sergey V. Dmitriev , Yong-Wei Zhang

Crystal structure imperfections in solids often act as efficient carrier trapping centers which, when suitably isolated, act as sources of single photon emission. The best known examples of such attractive imperfections are wellwidth or…

Mesoscale and Nanoscale Physics · Physics 2014-11-14 M. Koperski , K. Nogajewski , A. Arora , J. Marcus , P. Kossacki , M. Potemski

We conducted a tip-enhanced Raman scattering spectroscopy (TERS) and photoluminescence (PL) study of quasi-1D TaSe3 nanoribbons exfoliated onto gold substrates. At a selenium deficiency of ~0.25 (Se/Ta=2.75,), the nanoribbons exhibit a…

2H-TaSe2 is a model transition metal dichalcogenide material that develops charge density waves (CDWs).Here we present variable-temperature Raman spectroscopy study on both incommensurate charge density waves (ICDW) and optical phonon modes…

Materials Science · Physics 2017-12-13 Lin Cui , Qiaoling Huang , Gaomin Li , Yumeng You , Mingyuan Huang

We investigate the interlayer phonon modes in $N$-layer rhenium diselenide (ReSe$_2$) and rhenium disulfide (ReS$_2$) by means of ultralow-frequency micro-Raman spectroscopy. These transition metal dichalcogenides exhibit a stable distorted…

Mesoscale and Nanoscale Physics · Physics 2016-02-10 Etienne Lorchat , Guillaume Froehlicher , Stéphane Berciaud

We report on the coherent phonon spectroscopy of polymorphic $\mathrm{MoTe_2}$ single crystals using a femtosecond-pulsed laser to investigate the relationship between structural phase transitions and photo-thermal effects induced by…

Materials Science · Physics 2022-09-21 Takumi Fukuda , Ryota Kaburauchi , Yuta Saito , Kotaro Makino , Paul Fons , Keiji Ueno , Muneaki Hase

Platinum diselenide (PtSe2) is a newly discovered 2D material which is of great interest for applications in electronics and catalysis. PtSe2 films were synthesized by thermally-assisted selenization of predeposited platinum films and…

Optical properties of thin layers of rhenium diselenide (ReSe$_2$) with thickness ranging from mono- (1 ML) to nona-layer (9 MLs) are demonstrated. The photoluminescence (PL) and Raman scattering were measured at low ($T$=5 K) and room…

Mesoscale and Nanoscale Physics · Physics 2020-08-03 Ł. Kipczak , M. Grzeszczyk , K. Olkowska-Pucko , A. Babiński , M. R. Molas

We present first principles calculations of the electronic properties of trigonal selenium with emphasis on photovoltaic applications. The band gap and optical absorption spectrum of pristine selenium is calculated from many-body…

Defects in two-dimensional (2D) semiconductors play a decisive role in determining their electronic, optical, catalytic and quantum properties. Understanding how defect energy levels respond to variations in layer thickness is essential for…

Materials Science · Physics 2026-04-08 Nikhilesh Maity , Shibu Meher , Manoj Dey , Abhishek Kumar Singh

The electrical performance of two dimensional transitional metal dichalcogenides (TMDs) is strongly influenced by the amount of structural defects inside. In this work, we provide an optical spectroscopic characterization approach to…

We report on the phonon and thermal properties of thin films of tantalum diselenide (2H-TaSe2) obtained via the graphene-like mechanical exfoliation of crystals grown by chemical vapor transport. The ratio of the intensities of the Raman…

Materials Science · Physics 2015-06-17 Z. Yan , C. Jiang , T. R. Pope , C. F. Tsang , J. L. Stickney , P. Goli , J. Renteria , T. T. Salguero , A. A. Balandin

Layered two-dimensional (2D) materials display great potential for a range of applications, particularly in electronics. We report the large-scale synthesis of thin films of platinum diselenide (PtSe2), a thus far scarcely investigated…

We investigate the air-induced degradation of few-layer hafnium diselenide (HfSe$_2$) through combined experimental and theoretical approaches. AFM and SEM reveal the formation of selenium-rich spherical features upon ambient exposure,…

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