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We study the significance and characteristics of interfacial dynamical charge transfer at metal-organic interfaces for the organic semiconductor model system 1,4,5,8-naphthalene-tetracarboxylic dianhydride (NTCDA) on Ag(111) quantitatively.…

Chemical Physics · Physics 2016-05-26 Phil Rosenow , Peter Jakob , Ralf Tonner

Organic semiconductors offer an unprecedented flexibility to control the electronic state of interfacial electronic systems. Here we present a first step in realizing organic charge transfer interfaces that combine both a large electrical…

Materials Science · Physics 2016-03-01 Yulia Krupskaya , Florian Rückerl , Martin Knupfer , Alberto F. Morpurgo

Transport of charge carriers can be controlled by doping through chemical and physical means. Unlike chemical doping, physical doping is carried out by a special technique through gate voltages in a field-effect transistor geometry. This…

Superconductivity · Physics 2007-05-23 M. P. Das , F. Green

The control over material properties attainable through molecular doping is essential to many technological applications of organic semiconductors, such as OLED or thermoelectrics. These excitonic semiconductors typically reach the…

Materials Science · Physics 2021-07-14 Massimiliano Comin , Simone Fratini , Xavier Blase , Gabriele D'Avino

We use the Local Density Approximation in combination with the Dynamical Mean Field Theory to investigate intermediate energy properties of the copper oxides. We identify coherent and incoherent spectral features that results from doping a…

Strongly Correlated Electrons · Physics 2013-05-29 Cédric Weber , Kristjan Haule , Gabriel Kotliar

Organic solar cells are a promising avenue for renewable energy, and our study introduces a comprehensive model to investigate exciton dissociation processes at the donor-acceptor interface. Examining quantum efficiency and emitted phonons…

Materials Science · Physics 2025-02-05 Jouda Jemaa Khabthani , Khouloud Chika , Alexandre Perrin , Didier Mayou

A method has been developed to inject mobile charges at the surface of organic molecular crystals, and the DC transport of field-induced holes has been measured at the surface of pentacene single crystals. To minimize damage to the soft and…

Condensed Matter · Physics 2009-11-10 J. Takeya , C. Goldmann , S. Haas , K. P. Pernstich , B. Ketterer , B. Batlogg

Using a representative translational dimer model, high throughput calculations are implemented for fast screening of a total of 74 diacenaphtho-extended heterocycle (DAH) derivatives as hole transport layer (HTL) materials in perovskite…

Solution-processable interlayers are an important building block for the commercialization of organic electronic devices such as organic solar cells. Here, the potential of cross-linking to provide an insoluble, stable and versatile charge…

Hybrid materials are crucial in photovoltaics where the overall efficiency of the heterostructure is closely related to the level of charge transfer at the interface. Here, using various metal / poly(3-hexylthiophene)(P3HT) heterostructure…

Materials Science · Physics 2019-08-20 V. Ongun Özçelik , Yingmin Li , Wei Xiong , Francesco Paesani

Density functional theory calculations are used to show that it is possible to dope semiconducting transition metal dichalcogenides (TMD) such as MoS$_2$ and WS$_2$ with electrons and/or holes either by chemical substitution or by…

Mesoscale and Nanoscale Physics · Physics 2014-09-16 A. Carvalho , A. H. Castro Neto

Motivated by recent transport experiments and proposed atomic-scale semiconductor devices, we present measurements that extend the reach of scanned-probe methods to discern the properties of individual dopants tens of nanometers below the…

Mesoscale and Nanoscale Physics · Physics 2009-12-07 M. Gasseller , R. Loo , J. F. Harrison , M. Caymax , S. Rogge , S. H. Tessmer

The doping of semiconductor materials is a fundamental part of modern technology, but the classical approaches have in many cases reached their limits both in regard to achievable charge carrier density, as well as mobility. Modulation…

Materials Science · Physics 2019-07-08 Mirko Weidner , Anne Fuchs , Thorsten J. M. Bayer , Karsten Rachut , Getnet K. Deyu , Andreas Klein

Atomically thin materials such as graphene are uniquely responsive to charge transfer from adjacent materials, making them ideal charge transport layers in phototransistor devices. Effective implementation of organic semiconductors as a…

Two-dimensional materials represented by graphene and transition metal dichalcogenides undergo charge transfer (CT) processes and become hole-doped in strong mineral acids. Nonetheless, their mechanisms remain unclear or controversial. This…

Materials Science · Physics 2021-10-06 Kwnaghee Park , Sunmin Ryu

An electrode contact-related mechanism for the operational instability of organic electronic devices is proposed and confirmed via observation of a water-induced change in charge-injection barrier eights at the…

Applied Physics · Physics 2020-01-28 Ryo Nouchi

Inducing an inversion layer in organic semiconductors is a highly nontrivial, but critical, achievement for producing organic field-effect transistor (OFET) devices, which rely on the generation of inversion, accumulation, and depletion…

Mesoscale and Nanoscale Physics · Physics 2021-06-03 Zeno Schumacher , Rasa Rejali , Megan Cowie , Andreas Spielhofer , Yoichi Miyahara , Peter Grutter

In an organic blend the vibrational normal mode excited by exciton splitting is the same as the one coupled to charge hopping. Excess driving force for exciton splitting can therefore aid charge transfer, if vibrational relaxation is slow…

Mesoscale and Nanoscale Physics · Physics 2010-04-05 James Kirkpatrick

Silicon can be heavily doped with phosphorus in a single atomic layer (a $\delta$ layer), significantly altering the electronic structure of the conduction bands within the material. Recent progress has also made it possible to further dope…

Materials Science · Physics 2026-02-26 Quinn T. Campbell , Andrew D. Baczewski , Shashank Misra , Evan M. Anderson

The contact resistance between two dissimilar semiconductors is determined by the carrier transmission through their interface. Despite the ubiquitous presence of interfaces, quantitative simulation of charge transport across such…

Mesoscale and Nanoscale Physics · Physics 2022-05-25 Qichen Song , Jiawei Zhou , Gang Chen