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In general, there are two major factors affecting bandgaps in nanostructures: (i) the enhanced electron-electron interactions due to confinement and (ii) the modified self-energy of electrons due to the dielectric screening. While recent…

The characteristics of energy band spectrum of armchair graphene nanoribbons in presence of line defect are analyzed within a simple non-interacting tight-binding framework. In metallic nanoribbons an energy gap may or may not appear in the…

Mesoscale and Nanoscale Physics · Physics 2013-07-19 Paramita Dutta , Santanu K. Maiti , S. N. Karmakar

The electronic properties of graphene zig-zag nanoribbons with electrostatic potentials along the edges are investigated. Using the Dirac-fermion approach, we calculate the energy spectrum of an infinitely long nanoribbon of finite width…

Mesoscale and Nanoscale Physics · Physics 2011-04-01 W. Apel , G. Pal , L. Schweitzer

Many are the ways of engineering the band gap of nanoribbons including application of stress, electric field and functionalization of the edges. In this article, we investigate separately the effects of these methods on armchair graphene…

Mesoscale and Nanoscale Physics · Physics 2024-03-14 Elisa Serrano Richaud , Sylvain Latil , Hakim Amara , Lorenzo Sponza

Armchair graphene nanoribbons are a highly promising class of semiconductors for all-carbon nanocircuitry. Here, we present a new perspective on their electronic structure from simple model Hamiltonians and $\textit{ab initio}$…

Mesoscale and Nanoscale Physics · Physics 2023-01-24 Nikita V. Tepliakov , Johannes Lischner , Efthimios Kaxiras , Arash A. Mostofi , Michele Pizzochero

Recently, atomically well-defined cove-shaped graphene nanoribbons have been obtained using bottom-up synthesis. These nanoribbons have an optical gap in the visible range of the spectrum which make them candidates for donor materials in…

Mesoscale and Nanoscale Physics · Physics 2014-11-18 Cesar E. P. Villegas , Pedro B. Mendonça , Alexandre Rocha

The electronic properties of a material depend on the spatial freedom of the electron wavefunction. A well-known example is graphite, which is a conventional gapless semiconductor, while a single layer of it, graphene, exhibits extremely…

Mesoscale and Nanoscale Physics · Physics 2026-01-28 Mohammadamir Bazrafshan , Thomas. D. Kühne

Optical selection rules for one-dimensional graphene nanoribbons are analytically studied and clarified based on the tight-binding model. A theoretical explanation, through analyzing the velocity matrix elements and the features of…

Mesoscale and Nanoscale Physics · Physics 2011-11-03 H. C. Chung , M. H. Lee , C. P. Chang , M. F. Lin

We investigate electronic transport in lithographically patterned graphene ribbon structures where the lateral confinement of charge carriers creates an energy gap near the charge neutrality point. Individual graphene layers are contacted…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Melinda Y. Han , Barbaros Oezyilmaz , Yuanbo Zhang , Philip Kim

In this article, we report band structure studies of zigzag graphene nanoribbons (ZGNRs) on introducing defects (sp_3 hybridized carbon atoms) in different concentrations at edges by varying the ratio of sp_3 to sp_2 hybridized carbon…

Mesoscale and Nanoscale Physics · Physics 2018-03-19 Payal Wadhwa , Shailesh Kumar , T. J. Dhilip Kumar , Alok Shukla , Rakesh Kumar

Using first-principles plane wave calculations we predict that electronic and magnetic properties of graphene nanoribbons can be affected by defect-induced itinerant states. The band gaps of armchair nanoribbons can be modified by hydrogen…

Mesoscale and Nanoscale Physics · Physics 2008-08-12 M. Topsakal , E. Akturk , H. Sevincli , S. Ciraci

The electronic and transport properties of an extended linear defect embedded in a zigzag nanoribbon of realistic width are studied, within a tight binding model approach. Our results suggest that such defect profoundly modify the…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 D. A. Bahamon , A. L. C. Pereira , P. A. Schulz

The light-like dispersion of graphene monolayer results in many novel electronic properties in it1, however, this gapless feature also limits the applications of graphene monolayer in digital electronics2. A rare working solution to…

Mesoscale and Nanoscale Physics · Physics 2016-09-02 Si-Yu Li , Mei Zhou , Jia-Bin Qiao , Wenhui Duan , Lin He

By using the tight-binding model and non-equilibrium Green's function method (NEGF), we study the band structures and transport properties of a silicene nanoribbon with a line defect where a bulk energy gap is opened due to the sublattice…

Mesoscale and Nanoscale Physics · Physics 2021-11-24 Fei Wan , Xinru Wang , Yawen Guo , Jiayan Zhang , ZhengCheng Wen , Yuan Li

A novel two-dimensional carbon allotrope, rectangular graphyne (R-graphyne) with tetra-rings and acetylenic linkages, is proposed by first-principles calculations. Although the bulk R-graphyne exhibits metallic property, the nanoribbons of…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 Wen-Jin Yin , Yue-E Xie , Li-Min Liu , Ru-Zhi Wang , Leo Lau , Jian-Xin Zhong , Yuan-Ping Chen

Developing graphene-based nanoelectronics hinges on opening a band gap in the electronic structure of graphene, which is commonly achieved by breaking the inversion symmetry of the graphene lattice via an electric field (gate bias) or…

Materials Science · Physics 2014-06-11 Liangzhi Kou , Feiming Hu , Binghai Yan , Thomas Frauenheim , Changfeng Chen

Electronic structures of graphene sheet with different defective patterns are investigated, based on the first principles calculations. We find that defective patterns can tune the electronic structures of the graphene significantly.…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 H. Y. He , Y. Zhang , B. C. Pan

Graphene is the first truly two-dimensional (2D) material, possessing a cone-like energy spectrum near the Fermi energy and treated as a gapless semiconductor. Its unique properties trigger researchers to find more applications of it, such…

Mesoscale and Nanoscale Physics · Physics 2022-06-23 Wei-Bang Li , Yu-Ming Wang , Hsien-Ching Chung , Ming-Fa Lin

Graphene as a one-atom-thick platform for infrared metamaterial plays an important role in optical science and engineering. Here we study the unique properties of some plasmonic waveguides based on graphene nano-ribbon. It is found that a…

Optics · Physics 2013-05-29 S. He , X. Zhang , Y. He

We report on the energy level alignment evolution of valence and conduction bands of armchair-oriented graphene nanoribbons (aGNR) as their band gap shrinks with increasing width. We use 4,4-dibromo-para-terphenyl as molecular precursor on…