A novel two-dimensional carbon allotrope, rectangular graphyne (R-graphyne) with tetra-rings and acetylenic linkages, is proposed by first-principles calculations. Although the bulk R-graphyne exhibits metallic property, the nanoribbons of R-graphyne show distinct electronic structures from the bulk. The most intriguing feature is that band gaps of R-graphene nanoribbons oscillate between semiconductor and metal as a function of width. Particularly, the zigzag edge nanoribbons with half-integer repeating unit cell exhibits unexpected Dirac-like fermions in the band structures. The Dirac-like fermions of the R-graphyne nanoribbons originate from the central symmetry and two sub-lattices. The extraordinary properties of R-graphene nanoribbons greatly expand our understanding on the origin of Dirac-like point. Such findings uncover a novel fascinating property of nanoribbons, which may have broad potential applications for carbon-based nano-size electronic devices.
@article{arxiv.1601.02221,
title = {R-graphyne: a new two-dimension carbon allotrope with versatile Dirac-like point in nanoribbons},
author = {Wen-Jin Yin and Yue-E Xie and Li-Min Liu and Ru-Zhi Wang and Leo Lau and Jian-Xin Zhong and Yuan-Ping Chen},
journal= {arXiv preprint arXiv:1601.02221},
year = {2016}
}