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Armchair graphene nanoribbons are a highly promising class of semiconductors for all-carbon nanocircuitry. Here, we present a new perspective on their electronic structure from simple model Hamiltonians and $\textit{ab initio}$…

Mesoscale and Nanoscale Physics · Physics 2023-01-24 Nikita V. Tepliakov , Johannes Lischner , Efthimios Kaxiras , Arash A. Mostofi , Michele Pizzochero

We report on the configurations and electronic properties of graphyne and graphdiyne nanoribbons with armchair and zigzag edges investigated with first principles calculations. Our results show that all the nanoribbons are semiconductors…

Mesoscale and Nanoscale Physics · Physics 2013-10-25 Lida Pan , Lizhi Zhang , Boqun Song , Shixuan Du , Hongjun Gao

The Dirac electrons of graphene, an intrinsic zero gap semiconductor, uniquely carry spin and pseudospin that give rise to many fascinating electronic and transport properties. While isolated zigzag graphene nanoribbons are…

Materials Science · Physics 2016-07-22 M. X. Chen , M. Weinert

Graphene nanoribbons are quasi-one-dimensional meterials with finite width. Characterizing a wide class of nanoribbons by edge shape and width, we make a systematic analysis of their electronic properties. The band gap structure of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Motohiko Ezawa

In this study, we investigate the electronic and magnetic properties of graphane nanoribbons. We find that zigzag and armchair graphane nanoribbons with H-passivated edges are nonmagnetic semiconductors. While bare armchair ribbons are also…

Materials Science · Physics 2010-05-20 Hasan Sahin , Can Ataca , Salim Ciraci

Two-dimensional (2D) carbon materials play an important role in nanomaterials. We propose a new carbon monolayer, named hexagonal-4,4,4-graphyne (H4,4,4-graphyne), which is a nanoporous structure composed of rectangular carbon rings and…

Materials Science · Physics 2018-03-20 Linyang Li , Xiangru Kong , François M. Peeters

Based on a first-principles approach, we present scaling rules for the band gaps of graphene nanoribbons (GNRs) as a function of their widths. The GNRs considered have either armchair or zigzag shaped edges on both sides with hydrogen…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Young-Woo Son , Marvin L. Cohen , Steven G. Louie

We study alpha, beta, and gamma graphyne, a class of graphene allotropes with carbon triple bonds, using a first-principles density-functional method and tight-binding calculation. We find that graphyne has versatile Dirac cones and it is…

Mesoscale and Nanoscale Physics · Physics 2013-03-12 Bog G. Kim , Hyoung Joon Choi

In the purpose of expanding the family of two-dimensional materials, we predict the existence of two-dimensional octa-structure of nitrogen group elements that are composed of squares and octagons in first-principle method based on density…

Materials Science · Physics 2015-12-08 Yu Zhang , Jason Lee , Wei-Liang Wang , Dao-Xin Yao

Graphene nanoribbons with sub-nanometer widths are extremely interesting for nanoscale electronics and devices as they combine the unusual transport properties of graphene with the opening of a band gap due to quantum confinement in the…

Graphene nanoribbons are widely regarded as promising building blocks for next-generation carbon-based devices. A critical issue to their prospective applications is whether and to what degree their electronic structure can be externally…

Materials Science · Physics 2021-11-11 Michele Pizzochero , Nikita V. Tepliakov , Arash A. Mostofi , Efthimios Kaxiras

This article reviews the basic theoretical aspects of graphene, a one atom thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric…

Other Condensed Matter · Physics 2009-01-15 A. H. Castro Neto , F. Guinea , N. M. R. Peres , K. S. Novoselov , A. K. Geim

We demonstrate the topological properties of the band-gap of armchair graphene nanoribbons in a spatially varying staggered sublattice potential. Several general scaling laws are presented to quantify the band gap variation. It is found…

Mesoscale and Nanoscale Physics · Physics 2011-06-13 T. E. O'Brien , Chao Zhang , Anthony R. Wright

Graphene is a famous truly two-dimensional (2D) material, possessing a cone-like energy structure near the Fermi level and treated as a gapless semiconductor. Its unique properties trigger researchers to find applications of it. The gapless…

Materials Science · Physics 2024-02-22 Wei-Bang Li , Kuang-I Lin , Yu-Ming Wang , Hsien-Ching Chung , Ming-Fa Lin

Graphene nanoribbons are semiconductor nanostructures with great potentials in nanoelectronics. Their realization particularly with small lateral dimensions below a few nanometers, however, remains challenging. Here we theoretically analyze…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Valentina Tozzini , Vittorio Pellegrini

Recently, type-II Dirac fermions characterized by strongly titled Dirac cones have been proposed. The new fermions exhibit unique physical properties different from the type-I Dirac fermions in graphene, and thus attract tremendous…

Materials Science · Physics 2016-12-28 Honghong Zhang , Yuee Xie , Chengyong Zhong , Zhongwei Zhang , Yuanping Chen

Graphene, a two dimensional (2D) carbon sheet, acquires many of its amazing properties from the Dirac point nature of its electronic structures with negligible spin-orbit coupling. Extending to 3D space, graphene networks with negative…

Mesoscale and Nanoscale Physics · Physics 2015-07-09 Hongming Weng , Yunye Liang , Qiunan Xu , Rui Yu , Zhong Fang , Xi Dai , Yoshiyuki Kawazoe

Graphene nanoribbons with perfect edges are predicted to exhibit interesting electronic and spintronic properties, notably quantum-confined bandgaps and magnetic edge states. However, graphene nanoribbons produced by lithography have, to…

Mesoscale and Nanoscale Physics · Physics 2014-10-28 Xinran Wang , Yijian Ouyang , Liying Jiao , Hailiang Wang , Liming Xie , Justin Wu , Jing Guo , Hongjie Dai

We investigate the electronic band structure of an undoped graphene armchair nanoribbon. We demonstrate that such nanoribbon always has a gap in its electronic spectrum. Indeed, even in the situations where simple single-electron…

Mesoscale and Nanoscale Physics · Physics 2009-09-30 A. V. Rozhkov , S. Savel'ev , Franco Nori

{\gamma}-graphdiyne is a 2D carbon structure beyond graphene: it is formed by sp and sp2 carbon atoms organized as hexagonal rings connected by linear links, and it is predicted to be a semiconductor. The lateral confinement of…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Patrick Serafini , Alberto Milani , Matteo Tommasini , Chiara Castiglioni , Carlo S. Casari
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