Related papers: A New Reference Chemical Composition for TMC-1

In recent years, the obsessive interest in the observation of TMC-1 has brought a boost in our knowledge of the chemistry of cold dark clouds. The number of molecules detected in this particular cloud has been more than doubled. Two…

Spectral line surveys of the Taurus Molecular Cloud-1 (TMC-1) have led to the detection of more than 100 new molecular species, making it the most prolific source of interstellar molecular discoveries. These wide-band, high-sensitivity line…

Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the basis of precise laboratory data, a rich collection of more than 200 familiar and exotic molecules have been identified in the interstellar medium, the…

Recent detections of aromatic species in dark molecular clouds suggest formation pathways may be efficient at very low temperatures and pressures, yet current astrochemical models are unable to account for their derived abundances, which…

The interplay of the chemistry and physics that exists within astrochemically relevant sources can only be fully appreciated if we can gain a holistic understanding of their chemical inventories. Previous work by Lee et al. (2021)…

Many species of complex organic molecules (COMs) have been observed in several astrophysical environments but it is not clear how they are produced, particularly in cold, quiescent regions. One process that has been proposed as a means to…

We have conducted an extensive search for nitrogen-, oxygen- and sulfur-bearing heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband centimeter-wavelength spectral line survey of the region from the GOTHAM large…

We present the first identification in interstellar space of the propargyl radical (CH2CCH). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. The six strongest hyperfine components of the 2,0,2-1,0,1…

We investigated the chemical evolutions of gas phase and grain surface species across the Taurus molecular cloud-1 (TMC-1) filament from translucent phase to dense phase. By comparing observations with modeling results from an up-to-date…

Almost 200 different species have been detected in the interstellar medium (ISM) during the last decades, revealing not only simple species but complex molecules with more than 6 atoms. Other exotic compounds, like the weakly-bound dimer…

Context: An unexpectedly complex polyatomic chemistry exists in diffuse clouds, allowing detection of species such as C2H, C3H2, H2CO and NH3 which have relative abundances that are strikingly similar to those inferred toward the dark cloud…

The presence of molecular isomers in interstellar environments has become a topic of growing interest within the astrochemical community. Contrary to predictions based on thermodynamic equilibrium, recent observations reveal a diverse array…

In recent years, a significant number of oxygen-bearing complex organic molecules (COMs) have been detected in the gas phase of cold dark clouds such as TMC-1. The formation of these COMs cannot be explained by diffusive mechanisms on…

We report the detection of the protonated form of HC7N in TMC-1. The discovery of the cation HC7NH+ was carried out via the observation of nine harmonically related lines in the Q-band using the Yebes 40m radiotelescope. The observed…

We observed high S/N, high velocity resolution NH$_3$(1,1) and (2,2) emission on an extended map in TMC-1, a filamentary cloud in a nearby quiescent star forming area. By fitting multiple hyperfine-split line profiles to the NH$_3$(1,1)…

GEMS is an IRAM 30m Large Program whose aim is determining the elemental depletions and the ionization fraction in a set of prototypical star-forming regions. This paper presents the first results from the prototypical dark cloud TMC 1.…

We present the detection of ethanol (C2H5OH), acetone (CH3COCH3), and propanal (C2H5CHO) toward the cyanopolyyne peak of TMC-1. These three O-bearing complex organic molecules are known to be present in warm interstellar clouds, but had…

We report the detection in TMC-1 of the cation HCCS+ (3Sigma-), which is the protonated form of the widespread radical CCS. This is the first time that a protonated radical has been detected in a cold dark cloud. Twenty-six hyperfine…

The results of the lowest frequency spectral survey carried out toward a molecular cloud and sensitive observations at selected frequencies are presented. The entire Arecibo C-band (4--6 GHz) was observed towards the cyanopolyyne peak of…

Aims: Interstellar molecules form early in the evolutionary sequence of interstellar material that eventually forms stars and planets. To understand this evolutionary sequence, it is important to characterize the chemical composition of its…