Related papers: A New Reference Chemical Composition for TMC-1
We observed the 9-cm Lambda-doubling lines of CH along the dense filament of TMC-1. The CH column densities were compared with the total H2 column densities derived using the 2MASS NIR data and previously published SCUBA maps and with OH…
We present observations and analysis of the low-mass star-forming region, Taurus Molecular Cloud-1 (TMC-1). CS ($J$=2-1)/N$_2$H$^+$ ($J$=1-0) and C$^{17}$O ($J$=2-1)/C$^{18}$O ($J$=2-1) were observed with FCRAO (Five College Radio Astronomy…
It is currently assumed that infrared dark clouds (IRDCs) represent the earliest evolutionary stages of high-mass stars ($>$ 8 M$_{\odot}$). Submillimeter and millimeter-wave studies performed over the past 15 years show that IRDCs possess…
We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement…
The molecule 1,3-butadiene (CH2CHCHCH2) could play a key role in the synthesis of the cyclic molecules cyclopentadiene and benzene in cold dense clouds. Since 1,3-butadiene is non-polar, we searched for its cyano derivative, which exists in…
Based on a novel laboratory method, 14 mm-wave lines of the molecular ion H$_2$CCCH$^+$ have been measured in high resolution, and the spectroscopic constants of this asymmetric rotor determined with high accuracy. Using the Yebes 40 m and…
Accurate thermochemical data with sub-chemical accuracy (within 1 kcal mol$^{-1}$ of the empirical ground truth) are essential for advancing computational chemistry methods. However, existing datasets that reach this level of accuracy…
The data from the Nobeyama Radio Observatory 45 m telescope Galactic Center CO survey have been analyzed to generate a compilation of molecular clouds with intense CO emission in this region. Clouds are identified in an automated manner…
We clarify the line-of-sight structure of the Taurus Molecular Cloud 1 (TMC-1) on the basis of the CCS($J_N=4_3-3_2$) and HC$_3$N($J=5-4$) spectral data observed at a very high velocity resolution and sensitivity of $\Delta V \simeq 0.0004$…
We report the first detection in space of the cumulene carbon chain $l$-H$_2$C$_5$. A total of eleven rotational transitions, with $J_{up}$ = 7-10 and $K_a$ = 0 and 1, were detected in TMC-1 in the 31.0-50.4 GHz range using the Yebes 40m…
Context. It is almost banal to say that the interstellar medium (ISM) is structurally and thermodynamically complex. But the variety of the governing processes, including stellar feedback, renders the investigation challenging. High…
Using the Yebes 40m radio telescope, we report the detection of a series of seven lines harmonically related with a rotational constant B0=1295.81581 +/- 0.00026 MHz and a distortion constant D0=27.3 +/- 0.5 Hz towards the cold dense cloud…
We present Yebes 40m telescope observations of the three most stable C4H3N isomers towards the cyanopolyyne peak of TMC-1. We have detected 13 transitions from CH3C3N (A and E species), 16 lines from CH2CCHCN, and 27 lines (a-type and…
We present an IRAM 30m line survey of the dense core L483 in the 3 mm band. We detected 71 molecules (140 including different isotopologs), most of which are present in the cold and quiescent ambient cloud. Of particular interest among the…
We present a highly sensitive 2D line survey of TMC-1 obtained with the Yebes 40m radio telescope in the Q-band (31.13-49.53 GHz). These maps cover a region of 320 arcsec x 320 arcsec centred on the position of the QUIJOTE line survey with…
Complex organic molecules (COMs) have been detected in a variety of interstellar sources. The abundances of these COMs in warming sources can be explained by syntheses linked to increasing temperatures and densities, allowing quasi-thermal…
We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…
Nine HII regions of the LMC were mapped in 13CO(1--0) and three in 12CO(1--0) to study the physical properties of the interstellar medium in the Magellanic Clouds. For N113 the molecular core is found to have a peak position which differs…
We present the detection of cyanothioketene, NCCHCS, in the laboratory and toward TMC-1. This transient species was produced through a discharge of a gas mixture of CH2CHCN and CS2 using argon as carrier gas, and its rotational spectrum…
Context: Dark cloud chemical models usually predict large amounts of O2, often above observational limits. Aims: We investigate the reason for this discrepancy from a theoretical point of view, inspired by the studies of Jenkins and Whittet…