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Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…

Quantum Physics · Physics 2024-02-28 Lucas Chibebe Céleri , Łukasz Rudnicki

In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy…

Quantum Physics · Physics 2026-05-20 Mario Reis , Maron F. Anka , Vinicius Gomes de Paula , Clebson Cruz

Even after over 150 years of discussion, the interpretation of the second law of thermodynamics continues to be a source of confusion and controversy in physics. This confusion has been accentuated by recent challenges to the second law and…

Statistical Mechanics · Physics 2015-06-24 T. Duncan , J. Semura

By generalizing the traditional concept of heat dQ and work dW to also include their time-dependent irreversible components d_{i}Q and d_{i}W allows us to express them in terms of the instantaneous internal temperature T(t) and pressure…

Chemical Physics · Physics 2011-05-30 P. D. Gujrati

It is shown that the structure of thermodynamics is "form invariant", when it is derived using maximum entropy principle for various choices of entropy and even beyond equilibrium. By the form invariance of thermodynamics, it is meant that…

Quantum Physics · Physics 2015-11-12 Avijit Misra , Uttam Singh , Manabendra Nath Bera , A. K. Rajagopal

Some general considerations on the notion of entropy in physics are presented. An attempt is made to clarify the question of the differentiation between physical entropy (the Clausius-Boltzmann one) and quantities called entropies…

Statistical Mechanics · Physics 2007-05-23 Roberto Luzzi , Áurea R. Vasconcellos , J. Galvão Ramos

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal, but have an amount of coherence proportional to a…

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

This paper revisits Brownian motion from the perspective of Information Theory, aiming to explore the connections between Information Theory, Thermodynamics, and Complex Science. First, we propose a single-particle discrete Brownian motion…

Statistical Mechanics · Physics 2024-12-10 Hongzheng Liu , Zhiyue Wu

We introduce the concept of {\em information compressibility}, $K_I$, which measures the relative change of number of available microstates of an open system in response to an energy variation. We then prove that at the time in which the…

Statistical Mechanics · Physics 2009-11-13 M. Di Ventra , Y. Dubi

A new thermodynamic inequality is derived which leads to the maximum work that can be extracted from multi-heat baths with the assistance of discrete quantum feedback control. The maximum work is determined by the free-energy difference and…

Quantum Physics · Physics 2009-11-13 Takahiro Sagawa , Masahito Ueda

Equilibrium thermodynamics is grounded in the law of energy conservation, with a specific focus on how systems exchange energy with their environment during transitions between equilibrium states. These transitions are typically…

Statistical Mechanics · Physics 2024-08-19 Karol Makuch

We present a pedagogical review of the fundamental concepts in thermodynamics of information, by focusing on the second law of thermodynamics and the entropy production. Especially, we discuss the relationship among thermodynamic…

Statistical Mechanics · Physics 2017-12-20 Takahiro Sagawa

We review the fundamental properties of the quantum relative entropy for finite-dimensional Hilbert spaces. In particular, we focus on several inequalities that are related to the second law of thermodynamics, where the positivity and the…

Statistical Mechanics · Physics 2023-04-18 Takahiro Sagawa

Compared to other formulations of the second law of thermodynamics, the Clausius statement that heat does not spontaneously flow from cold to hot concerns a system in non-equilibrium states, and in that respect is more ambitious but also…

Statistical Mechanics · Physics 2020-12-18 Alex V. Plyukhin

We study entropy production in nanoscale devices, which are coupled to finite heat baths. This situation is of growing experimental relevance, but most theoretical approaches rely on a formulation of the second law valid only for infinite…

Quantum Physics · Physics 2021-08-25 Philipp Strasberg , María García Díaz , Andreu Riera-Campeny

From the Horowitz-Esposito stochastic thermodynamical description of information flows in dynamical systems [J. M. Horowitz and M. Esposito, Phys. Rev. X4, 031015 (2014)], it is known that while the second law of thermodynamics is satisfied…

Statistical Mechanics · Physics 2016-03-23 Carlo Cafaro , Sean Alan Ali , Adom Giffin

As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…

General Physics · Physics 2008-11-23 Shu-Kun Lin

Second law of thermodynamics can be apparently violated for systems whose dynamics depends on acquired information by measurement. However, when one consider measurement and erasure process together along with the system it saves the second…

Statistical Mechanics · Physics 2016-11-08 Shubhashis Rana , A. M. Jayannavar