English

Clausius Inequality for Finite Baths Reveals Universal Efficiency Improvements

Quantum Physics 2021-08-25 v2 Mesoscale and Nanoscale Physics Statistical Mechanics

Abstract

We study entropy production in nanoscale devices, which are coupled to finite heat baths. This situation is of growing experimental relevance, but most theoretical approaches rely on a formulation of the second law valid only for infinite baths. We fix this problem by pointing out that already Clausius' paper from 1865 contains an adequate formulation of the second law for finite heat baths, which can be also rigorously derived from a microscopic quantum description. This Clausius' inequality shows that nonequilibrium processes are less irreversible than previously thought. We use it to correctly extend Landauer's principle to finite baths and we demonstrate that any heat engine in contact with finite baths has a higher efficiency than previously thought. Importantly, our results are easy to study, requiring only the knowledge of the average bath energy.

Keywords

Cite

@article{arxiv.2012.03262,
  title  = {Clausius Inequality for Finite Baths Reveals Universal Efficiency Improvements},
  author = {Philipp Strasberg and María García Díaz and Andreu Riera-Campeny},
  journal= {arXiv preprint arXiv:2012.03262},
  year   = {2021}
}

Comments

Small improvements in the presentation. 12.5 pages in total incl. 6 figures and supplement. Comments are welcome!

R2 v1 2026-06-23T20:45:43.580Z