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A pressure-induced topological quantum phase transition has been theoretically predicted for the semiconductor BiTeI with giant Rashba spin splitting. In this work, the evolution of the electrical transport properties in BiTeI and BiTeBr is…

We report the observation of two signatures of a pressure-induced topological quantum phase transition in the polar semiconductor BiTeI using x-ray powder diffraction and infrared spectroscopy. The x-ray data confirm that BiTeI remains in…

Materials Science · Physics 2013-10-09 Xiaoxiang Xi , Chunli Ma , Zhenxian Liu , Zhiqiang Chen , Wei Ku , H. Berger , C. Martin , D. B. Tanner , G. L. Carr

We study the possibility of pressure-induced transitions from a normal semiconductor to a topological insulator (TI) in bismuth tellurohalides using density functional theory and tight-binding method. In BiTeI this transition is realized…

Materials Science · Physics 2016-11-23 I. P. Rusinov , T. V. Menshchikova , I. Yu. Sklyadneva , R. Heid , K. -P. Bohnen , E. V. Chulkov

In recent years, a low pressure transition around P $\sim$ 3 GPa exhibited by the A$_2$B$_3$-type 3D topological insulators is attributed to an electronic topological transition (ETT) for which there is no direct evidence either from theory…

Materials Science · Physics 2016-03-23 Achintya Bera , Koushik Pal , D V S Muthu , U V Waghmare , A K Sood

One approach to discovering topological superconductor is establishing superconductivity based on well-identified topological insulators. However, the coexistence of superconductivity and topological state is always arcane. In this paper,…

Superconductivity · Physics 2022-09-30 Lei Kang , Zi-Yu Cao , Bo Wang

The pressure-induced phase transition of bismuth telluride, Bi2Te3, has been studied by synchrotron x-ray diffraction measurements at room temperature using a diamond-anvil cell (DAC) with loading pressures up to 29.8 GPa. We found a…

Materials Science · Physics 2015-05-20 Mari Einaga , Ayako Ohmura , Atsuko Nakayama , Fumihiro Ishikawa , Yuh Yamada , Satoshi Nakano

We report a theoretical \textit{ab-initio} study of $\beta$-As$_2$Te$_3$ ($R\bar{3}m$ symmetry) at hydrostatic pressures up to 12 GPa. We have systematically characterized the vibrational and electronic changes of the system induced by the…

Simultaneous low-temperature electrical resistivity and Hall effect measurements were performed on single-crystalline Bi2Se3 under applied pressures up to 50 GPa. As a function of pressure, superconductivity is observed to onset above 11…

Electrical resistivity measurements on La$_{1-x}$Sm$_{x}$O$_{0.5}$F$_{0.5}$BiS$_{2}$ ($x$ = 0.1, 0.3, 0.6, 0.8) have been performed under applied pressures up to 2.6 GPa from 2 K to room temperature. The superconducting transition…

Superconductivity · Physics 2015-10-28 Y. Fang , D. Yazici , B. D. White , M. B. Maple

Recent progress in understanding the electronic band topology and emergent topological properties encourage us to reconsider the band structure of well-known materials including elemental substances. Controlling such a band topology by…

A topological phase transition from a trivial insulator to a $\mathbb{Z}_2$ topological insulator requires the bulk band gap to vanish. In the case of noncentrosymmetric materials, these phases are separated by a gapless Weyl semimetal…

Materials Science · Physics 2020-05-20 Véronique Brousseau-Couture , Gabriel Antonius , Michel Côté

Pressure induced electronic topological transitions in the wide band gap semiconductor Sb2S3 (Eg = 1.7-1.8 eV) with similar crystal symmetry (SG: Pnma) to its illustrious analog, Sb2Se3, has been studied using Raman spectroscopy,…

Materials Science · Physics 2016-01-20 Y. A. Sorb , V. Rajaji , P. S. Malavi , U. Subbarao , P. Hadappa , S. Karmakar , Sebastian C. Peter , C. Narayana

As a new type of topological materials, ZrTe5 shows many exotic properties under extreme conditions. Utilizing resistance and ac magnetic susceptibility measurements under high pressure, while the resistance anomaly near 128 K is completely…

Measurements of temperature-dependent resistance and magnetization under hydrostatic pressures up to 2.13 GPa are reported for single-crystalline, superconducting BaBi$_3$. A temperature - pressure phase diagram is determined and the…

We report x-ray diffraction, electrical resistivity, and magnetoresistance measurements on Bi2Se3 under high pressure and low temperature conditions. Pressure induces profound changes in both the room temperature value of the electrical…

Materials Science · Physics 2015-06-03 J. J. Hamlin , J. R. Jeffries , N. P. Butch , P. Syers , D. A. Zocco , S. T. Weir , Y. K. Vohra , J. Paglione , M. B. Maple

We report the structural, vibrational and electrical transport properties up to 16 GPa of the 1T-TiTe2, a prominent layered 2D system, which is predicted to show a series of topologically trivial - nontrivial transitions under hydrostatic…

We here report a detailed high-pressure infrared transmission study of BiTeCl and BiTeBr. We follow the evolution of two band transitions: the optical excitation $\beta$ between two Rashba-split conduction bands, and the absorption $\gamma$…

Materials Science · Physics 2017-01-18 I. Crassee , F. Borondics , M. K. Tran , G. Autès , A. Magrez , P. Bugnon , H. Berger , J. Teyssier , O. V. Yazyev , M. Orlita , A. Akrap

Topological quantum phase transitions (TQPTs) in a material induced by external perturbations are often characterized by band touching points in the Brillouin zone. The low-energy excitations near the degenerate band touching points host…

Materials Science · Physics 2018-05-07 Rinkle Juneja , Ravindra Shinde , Abhishek K. Singh

Recently, the natural heterostructure of (PbSe)5(Bi2Se3)6 has been theoretically predicted and experimentally confirmed as a topological insulator. In this work, we induce superconductivity in (PbSe)5(Bi2Se3)6 by implementing high pressure.…

We report the pressure (p_max = 1.5 GPa) evolution of the crystal structure of the Weyl semimetal T_d-MoTe_2 by means of neutron diffraction experiments. We find that the fundamental non-centrosymmetric structure T_d is fully suppressed and…

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