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We investigated the rare-earth transition metal oxide series, Ln2CuTiO6 (Ln=Y, Dy, Ho, Er and Yb), crystallizing in the hexagonal structure with non-centrosymmetric P63cm space group for possible occurrences of multiferroic properties. Our…

We present a first-principles investigation of ferroelectricity in layered perovskite oxide La2Ti2O7 (LTO), one of the compounds with highest Curie temperature known (1770 K). Our calculations reveal that LTO's ferroelectric transition…

Materials Science · Physics 2015-05-27 Jorge Lopez-Perez , Jorge Iniguez

A single-phase 65PMN-35PT ceramic was synthesized at a relatively low temperature (875 oC) using a modified columbite method. X-ray diffraction analysis confirmed the single-phase formation of perovskite 65PMN-35PT with a tetragonal…

Materials Science · Physics 2025-07-09 B. Ramachandran , N. Sudarshan , G. Mangamma , M. S. Ramachandra Rao

We investigate the temperature evolution of the structural parameters of potential ferrotoroidic LiFeSi2O6 compound across structural and magnetic phase transitions. The structural transition (TS)is around 220K and the paramagnetic to…

Strongly Correlated Electrons · Physics 2019-09-04 R. K. Maurya , Priyamedha Sharma , R. Rawat , R. S. Singh , R. Bindu

The structural, dielectric, dynamical, elastic, piezoelectric and nonlinear optical (second-order susceptibility and Pockels tensors) properties of Bi2$WO6 in its P2_1ab ferroelectric ground state are determined using density functional…

Materials Science · Physics 2014-03-19 Hania Djani , Patrick Hermet , Philippe Ghosez

In this work, the potential to exploit Aurivillius higher order composition (n=6) given by Bi4Ti3O12-3BiFeO3 as single phase and high temperature magnetoelectric materials are well explored by elaborately studying the concerned structure…

Materials Science · Physics 2022-12-20 K. R. S. Preethi Meher , K. B. R. Varma

Ca2-xLaxFeMoO6 double perovskite with La concentration x = 0 to 0.6 was synthesized using solid state sintering route. The standard techniques of XRD, SEM and EDX were applied to characterize the material. Crystal structure of the samples…

Materials Science · Physics 2009-10-11 I. Panneer Muthuselvam , Asok Poddar , R. N. Bhowmik

Materials with a 5d4 electronic configuration are generally considered to have a nonmagnetic ground state (J=0). Interestingly, Sr2YIrO6 (Ir5+ having 5d4 electronic configuration) was recently reported to exhibit long-range magnetic order…

The La2CoMnO6 (LCMO) perovskite has received a lot of attention due to its near room temperature magnetodielectric effect. Despite the recent efforts, the mechanism ruling the correlation between its magnetic and dielectric properties is…

The polycrystalline Sm2MgMnO6 (SMMO) was synthesized at 1173K by means of sol-gel technique. Rietveld refine-ment of X-ray diffraction (XRD) pattern confirmed the formation of a single phase monoclinic structure with space group P21/n. The…

Materials Science · Physics 2017-07-03 Moumin Rudra , Ritwik Maity , T. P. Sinha

Experimental results on Bi2FeCrO6 (BFCO) epitaxial films deposited by laser ablation on SrTiO3 substrates are presented. It has been theoretically predicted using first-principles density functional theory that BFCO is ferrimagnetic (with a…

Materials Science · Physics 2009-03-12 R. Nechache , C. Harnagea , L. -P. Carignan , D. Menard , A. Pignolet

Structural, magnetic and dielectric properties have been studied for Yb$_2$CoMnO$_6$. Nano-crystalline sample of Yb$_2$CoMnO$_6$ synthesized by sol-gel method and structural analysis shows that the sample crystallizes in monoclinic crystal…

Strongly Correlated Electrons · Physics 2020-10-28 Ilyas Noor Bhatti , Imtiaz Noor Bhatti , Rabindra Nath Mahato , M. A. H. Ahsan

Ba2CaMoO6 was synthesized by solid state method. The crystal structure adopts cubic Fm-3m space group at room temperature with lattice parameters of 8.378231(5) {angstroms}. Upon cooling, Ba2CaMoO6 was determined to have a structural phase…

Materials Science · Physics 2020-11-03 Loi T. Nguyen , Robert J. Cava , Allyson M. Fry-Petit

Ceramics of A_{2}FeReO_{6} double-perovskite have been prepared and studied for A=Ba and Ca. Ba_{2}FeReO_{6} has a cubic structure (Fm3m) with $a\approx $8.0854(1) \AA whereas Ca_{2}FeReO_{6} has a distorted monoclinic symmetry with…

Materials Science · Physics 2009-10-31 W. Prellier , V. Smolyaninova , Amlan Biswas , C. Galley , R. L. Greene , K. Ramesha , J. Gopalakrishnan

Despite the great technological and scientific importance, a well-controlled coupled behavior in magnetoelectric multiferroic materials at room temperature remains challenging. We demonstrate that the self-ordered A2BBO6 (e.g., A = La, B =…

Materials Science · Physics 2015-05-14 M. P. Singh , K. D. Truong , S. Jandl , P. Fournier

Ferroelectric ceramics (Ba0.85Ca0.15)(Ti0.9Zr0.1-xSnx)O3 (x=0.00, 0.02, 0.04, 0.06) were prepared by a sol-gel method. Structural investigation revealed the co-existence of tetragonal (P4mm) and orthorhombic (Pmm2) symmetries at room…

The results of the LSDA+U calculations for pyroxenes with diverse magnetic properties (Li,Na)TM(Si,Ge)$_2$O$_6$, where TM is the transition metal ion (Ti,V,Cr,Mn,Fe), are presented. We show that the anisotropic orbital ordering results in…

Strongly Correlated Electrons · Physics 2008-02-05 S. V. Streltsov , D. I. Khomskii

New fluoropnictides BaMnPnF with Pn = As, Sb, Bi, are synthesized by stoichiometric reaction of elements with BaF\_2. The compounds crystallize in the tetragonal P4/nmm (No. 129, Z = 2) space group, with the ZrCuSiAs-type structure, as…

Strongly Correlated Electrons · Physics 2013-07-09 Bayrammurad Saparov , David J. Singh , V. Ovidiu Garlea , Athena S. Sefat

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

A new charge-ordered magnetically frustrated mixed-metal fluoride with a pyrochlore-related structure has been synthesized and characterized. The material, RbFe2F6 (RbFe2+Fe3+F6) was synthesized through mild hydrothermal conditions. The…