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Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…

Chemical Physics · Physics 2024-08-20 Liying Chen , Ashley P. Fidler , Alexander M. McKillop , Marissa L. Weichman

Strong light-matter coupling in optical waveguides provides a versatile platform for engineering hybrid polaritonic modes and their dispersion. Here we investigate multimode exciton-photon coupling in visible semiconductor waveguides…

The vacuum Rabi splitting (VRS) in molecular polaritons stands as a fundamental measure of collective light-matter coupling. Despite its significance, the impact of molecular disorder on VRS is not fully understood yet. This study delves…

Chemical Physics · Physics 2024-04-18 Kai Schwennicke , Noel C. Giebink , Joel Yuen-Zhou

The rate of non-radiative decay between two molecular electronic states is succinctly described by the energy gap law, which suggests an approximately-exponential dependence of the rate on the electronic energy gap. Here, we inquire whether…

Chemical Physics · Physics 2023-04-14 Yong Rui Poh , Sindhana Pannir-Sivajothi , Joel Yuen-Zhou

Cavity dressing of molecular vibrational dynamics expands the role of characteristic vibrations as spectroscopic markers of underlying ultrafast dynamics. Interacting vibrational modes exhibit a pronounced excited state delocalization due…

Quantum Physics · Physics 2026-01-06 Arunangshu Debnath

Strong coupling between a single quantum emitter and an electromagnetic mode is one of the key effects in quantum optics. In the cavity QED approach to plasmonics, strongly coupled systems are usually understood as single-transition…

This letter demonstrates the formation of vibro-polaritonic states by strong coupling gaseous nitrous oxide molecules at room temperature. The ro-vibrational features of the molecule is utilized to understand the nature of the strong…

Chemical Physics · Physics 2024-01-15 Akhila Kadyan , Jino George

Strong light-matter coupling has recently been demonstrated in sub-wavelength volumes by coupling engineered optical transitions in semiconductor heterostructures (e.g., quantum wells) to metasurface resonances via near fields. It has also…

Coherent light-matter interaction at the single photon and electronic qubit level promises the remarkable potential for nonclassical information processing. Against the efforts of improving the figure of merit of the cavities, here we…

Quantum Physics · Physics 2015-06-19 Yong-Chun Liu , Xingsheng Luan , Hao-Kun Li , Qihuang Gong , Chee Wei Wong , Yun-Feng Xiao

We discuss the equilibrium and out of equilibrium dynamics of cavity QED in presence of dissipation beyond the standard perturbative treatment of losses. Using the dynamical polaron \emph{ansatz} and Matrix Product State simulations, we…

Quantum Physics · Physics 2019-01-09 David Zueco , Juanjo García-Ripoll

Strong molecule-light interaction enables the control of molecular structures and dynamical processes. A model with strong laser drive is proposed to greatly enhance the intermolecular distance of resonant energy transfer, where the…

Quantum Physics · Physics 2021-01-27 Xuanhua Wang , Zhedong Zhang , Jin Wang

The quantum Rabi model is in the scientific spotlight due to the recent theoretical and experimental progress. Nevertheless, a full-fledged classification of its coupling regimes remains as a relevant open question. We propose a spectral…

Quantum Physics · Physics 2017-07-27 Daniel Z. Rossatto , Celso J. Villas-Bôas , Mikel Sanz , Enrique Solano

Hybridization of excitons with photons to form hybrid quasiparticles, exciton-polaritons (EPs), has been widely investigated in a range of semiconductor material systems coupled to photonic cavities. Self-hybridization occurs when the…

We study the resonant electronic excitation dynamics for ultracold atoms trapped in a deep optical lattice prepared in a Mott insulator state. Excitons in these artificial crystals are similar to Frenkel excitons in Noble atom or molecular…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

Propagation of light through dielectrics lies at the heart of optics. However, this ubiquitous process is commonly described using phenomenological dielectric function $\varepsilon$ and magnetic permeability $\mu$, i.e. without addressing…

Quantum Physics · Physics 2016-11-30 Harald R. Haakh , Sanli Faez , Vahid Sandoghdar

The collective dynamics of two non-interacting two-level emitters, which are coupled to a structured wave guide that supports two-photon bound states, is investigated. Tuning the energy of the two emitters such that they are in resonance…

Quantum Gases · Physics 2023-01-25 J. Talukdar , D. Blume

Understanding the dynamical behavior of quasiparticles is essential for uncovering novel quantum many-body phenomena. Among these phenomena, the polaron in ultracold atomic gases has attracted considerable interest due to its precise…

Quantum Gases · Physics 2025-04-21 Zeyu Liu , Pengfei Zhang

We extend the model of exciton-plasmon materials to include a ro-vibrational structure of molecules using wave-packet propagations on electronic potential energy surfaces. The new model replaces conventional two-level emitters with more…

Mesoscale and Nanoscale Physics · Physics 2017-08-18 Maxim Sukharev , Eric Charron

We simulate the near-field effects of strong coupling between molecular excitons and localized surface plasmons, supported by aluminum nanodisks. The simulations are done using a simple model of a two-level system, implemented in a…

Mesoscale and Nanoscale Physics · Physics 2020-01-29 Nadav Fain , Tal Ellenbogen , Tal Schwartz

Strong coupling between various kinds of material excitations and optical modes has recently shown potential to modify chemical reaction rates in both excited and ground states. The ground-state modification in chemical reaction rates has…

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