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Antimonene -- a single layer of antimony atoms -- and its few layer forms are among the latest additions to the 2D mono-elemental materials family. Numerous predictions and experimental evidence of its remarkable properties including…

Two-dimensional (2D) antimony, so-called antimonene, can form antimonene oxide when exposed to air. We present different types of single- and few-layer antimony oxide structures, based on density functional theory (DFT) calculations.…

Materials Science · Physics 2020-04-01 Stefan Wolff , Roland Gillen , Mhamed Assebban , Gonzalo Abellán , Janina Maultzsch

Antimony shows promise as a two-dimensional (2D) mono-elemental crystal, referred to as antimonene. When exposed to ambient conditions, antimonene layers react with oxygen, forming new crystal structures, leading significant changes in…

Materials Science · Physics 2024-06-26 Stefan Wolff , Roland Gillen , Janina Maultzsch

Antimonene has attracted much attention for its high carrier mobility and suitable band gap for electronic, optoelectronic, and even spintronic devices. To tailor its properties for such applications, strain engineering may be adopted.…

Materials Science · Physics 2023-03-10 Yujia Tian , Devesh R. Kripalani , Ming Xue , Shaofan Li , Kun Zhou

Two-dimensional materials exhibit a variety of mechanical instabilities accompanied by spontaneous symmetry breaking. Here we develop a continuum description of the buckling instability of antimonene sheets. Regions of oppositely directed…

Mesoscale and Nanoscale Physics · Physics 2020-11-04 Joshua Chiel , Harsh Mathur , Onuttom Narayan

Liquid-phase chemical exfoliation is ideal to achieve industry scale production of two-dimensional (2D) materials for a wide range of application such as printable electronics, catalysis and energy storage. However, many impactful 2D…

In this work, we investigate the mechanical and electronic properties of monolayer antimonene in its most stable beta-phase using first-principles calculations. The upper region of its valence band is found to solely consist of lone pair…

Materials Science · Physics 2022-02-02 Devesh R. Kripalani , Andrey A. Kistanov , Yongqing Cai , Ming Xue , Kun Zhou

Group-V elemental monolayers including phosphorene are emerging as promising 2D materials with semiconducting electronic properties. Here, we present the results of first principles calculations on stability, mechanical and electronic…

Computational Physics · Physics 2015-05-12 Gaoxue Wang , Ravindra Pandey , Shashi P. Karna

Atomically thin two-dimensional (2D) crystals have gained tremendous attentions owing to their potential impacts to the future electronics technologies, as well as the exotic phenomena emerging in these materials. Monolayer of {\alpha}…

Among the large number of promising two-dimensional (2D) atomic layer crystals, true metallic layers are rare. Through combined theoretical and experimental approaches, we report on the stability and successful exfoliation of atomically…

Isolation and characterization of mechanically exfoliated black phosphorus flakes with a thickness down to two single-layers is presented. A modification of the mechanical exfoliation method, which provides higher yield of atomically thin…

We demonstrate that it is possible to mechanically exfoliate graphene under ultra high vacuum conditions on the atomically well defined surface of single crystalline silicon. The flakes are several hundred nanometers in lateral size and…

Materials Science · Physics 2015-06-05 O. Ochedowski , G. Begall , N. Scheuschner , M. El Kharrazi , J. Maultzsch , M. Schleberger

Layered two-dimensional materials like graphene are highly appealing for lithium battery applications owing to their high surface-volume ratios. However, a critical issue that limits their practical applications is the confined motion of…

Materials Science · Physics 2019-01-23 Andrey Kistanov , Devesh Kripalani , Yongqing Cai , Sergey Dmitriev , Kun Zhou , Yong-Wei Zhang

Surface contamination not only influences but in some cases even dominates the measured properties of two-dimensional materials. Although different cleaning methods are often used for contamination removal, commonly used spectroscopic…

Recently a stable monolayer of antimony in buckled honeycomb structure called antimonene was successfully grown on 3D topological insulator Bi$_2$Te$_3$ and Sb$_2$Te$_3$, which displays semiconducting properties. By first principle…

Materials Science · Physics 2017-03-22 Yuanfeng Xu , Bo Peng , Hao Zhang , Hezhu Shao , Rongjun Zhang , Hongliang Lu , David Wei Zhang , Heyuan Zhu

Antimonene, a new group-VA 2D semiconducting material beyond phosphorene, was recently synthesized through various approaches and was shown to exhibit a good structural integrity in ambient conditions and various interesting properties. In…

The synthesis of antimonene, which is a promising group-V 2D material for both fundamental studies and technological applications, remains highly challenging. Thus far, it has been synthesized only by exfoliation or growth on a few…

Materials Science · Physics 2018-03-28 Ya-Hui Mao , Li-Fu Zhang , Hui-Li Wang , Huan Shan , Xiao-Fang Zhai , Zhen-Peng Hu , Ai-Di Zhao , Bing Wang

With the technology of artificial defects creating, we can tune the band structure and transport properties of many two-dimensional (2D) layered materials. One prototype materials system is the antidoted graphene sheet, where periodical…

Materials Science · Physics 2022-01-19 Shuang Tang , Andy Juan , David Drysdale , Joseph Duarte Menjivar , Jason Guzman

Integrating layered two-dimensional (2D) materials into 3D heterostructures offers opportunities for novel material functionalities and applications in electronics and photonics. In order to build the highest quality heterostructures, it is…

Antimonene is a novel two-dimensional (2D) semiconducting material of group V elements proposed in a recent literature [Zhang et al., Angew. Chem. Int. Ed. 54, 1-5 (2015)]. Using first-principles calculations, we demonstrated that the…

Materials Science · Physics 2015-04-16 Mingwen Zhao
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