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Boron is the fifth element in the periodic table and possesses rich chemistry second only to carbon. A striking feature of boron is that B12 icosahedral cages occur as the building blocks in bulk boron and many boron compounds. This is in…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 Baojie Feng , Jin Zhang , Qing Zhong , Wenbin Li , Shuai Li , Hui Li , Peng Cheng , Sheng Meng , Lan Chen , Kehui Wu

Three typical one-dimensional (1D)/quasi-1D nanocarbons, linear carbon chains, carbon nanotubes, and graphene nanoribbons have been proven to grow inside single-wall carbon nanotubes. This gives rise to three types of hybrid materials whose…

Materials Science · Physics 2021-01-29 Weili Cui , Takeshi Saito , Paola Ayala , Thomas Pichler , Lei Shi

We predict by first principles calculations that the recently prepared borophene is a pristine two-dimensional (2D) monolayer superconductor, in which the superconductivity can be significantly enhanced by strain and charge carrier doping.…

Superconductivity · Physics 2017-01-09 R. C. Xiao , D. F. Shao , W. J. Lu , H. Y. Lv , J. Y. Li , Y. P. Sun

We study the effect of electron doping on the bonding character and stability of two-dimensional (2D) structures of elemental boron, called borophene, which is known to form many stable allotropes. Our {\em ab initio} calculations for the…

Materials Science · Physics 2019-03-27 Dan Liu , David Tomanek

A novel stable crystallographic structure is discovered in a variety of ABO3, ABF3 and A2O3 compounds (including materials of geological relevance, prototypes of multiferroics, exhibiting strong spin-orbit effects, etc...), via the use of…

Materials Science · Physics 2015-01-20 Changsong Xu , Bin Xu , Yurong Yang , Huafeng Dong , A. R. Oganov , Shanying Wang , Wenhui Duan , Binglin Gu , L. Bellaiche

Boron nitride (BN) is an exceptional material and among its polymorphs, two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and c-BN) phases are most common. The phase stability regimes of these BN phases are still…

MAB phases (MABs) are atomically-thin laminates of ceramic/metallic-like layers, having made a breakthrough in the development of 2D materials. Though theoretically offering a vast chemical and phase space, relatively few MABs have yet been…

Materials Science · Physics 2024-06-21 Nikola Koutná , Lars Hultman , Paul H. Mayrhofer , Davide G. Sangiovanni

Investigation on oxidation resistance of two-dimensional (2D) materials is critical for many of their applications, because 2D materials could have higher oxidation kinetics than their bulk counterparts due to predominant surface atoms and…

Materials Science · Physics 2014-03-06 Lu Hua Li , Jiri Cervenka , Kenji Watanabe , Takashi Taniguchi , Ying Chen

First-principles investigations on the edge energies and edge stresses of single-layer hexagonal boron-nitride (BN) are presented. The armchair edges of BN nanoribbons (BNNRs) are more stable in energy than zigzag ones. Armchair BNNRs are…

Materials Science · Physics 2010-11-30 Bing Huang , Hoonkyung Lee , Bing-Lin Gu , Feng Liu , Wenhui Duan

Currently, solid interfaces composed of two-dimensional materials (2D) in contact with metal surfaces (m-surf) have been the subject of intense research, where the borophene bilayer (BBL) has been considered a prominent material for the…

Materials Science · Physics 2023-11-21 Wanderlã L. Scopel , F. Crasto de Lima , Pedro H. Souza , José E. Padilha , Roberto H. Miwa

The structures, stability, mechanical and electronic properties of a-boron and its twined brother a*-boron have been studied by first-principles calculations. Both a-boron and a*-boron consist of equivalent icosahedra B12 clusters in…

Materials Science · Physics 2013-02-27 Chaoyu He , Jianxin Zhong

A complex interplay between the crystal structure and electron behavior within borophene renders this material an intriguing 2D system with many of its electronic properties still undiscovered. Experimental insight into those properties is…

Borophene has triggered a surge of interest due to its outstanding properties including mechanical flexibility, polymorphism, and opto-electrical anisotropy. Very recently, a novel semi-hydrogenated borophene, called $\alpha'$-4H, was…

Using density functional theory combined with a semi-empirical van der Waals dispersion correction, we have investigated the stability of lattice defects including boron vacancy, substitutional and interstitial X (X=H, C, B, N, O) and…

Materials Science · Physics 2017-05-12 V. Wang , W. T. Geng

We present a comprehensive first-principles investigation of boron fullerenes and two-dimensional boron sheets, unified under a coordination-based framework. By classifying over a dozen boron nanostructures, including B$_{12}$, B$_{40}$,…

Materials Science · Physics 2025-07-10 Nevill Gonzalez Szwacki

We introduce two-dimensional borane, a single-layered material of BH stoichiometry, with promising electronic properties. We show that, according to Density Functional Theory calculations, two-dimensional borane is semimetallic, with two…

Materials Science · Physics 2017-12-01 Miguel Martinez-Canales , Timur R. Galeev , Alexander I. Boldyrev , Chris J. Pickard

Two-dimensional (2D) Dirac cone materials exhibit linear energy dispersion at the Fermi level, where the effective masses of carriers are very close to zero and the Fermi velocity is ultrahigh, only 2 ~ 3 orders of magnitude lower than the…

Materials Science · Physics 2019-10-15 Yang Zhang , Jun Kang , Fan Zheng , Peng-Fei Gao , Sheng-Li Zhang , Lin-Wang Wang

Two dimensional allotropes of group IV substrates including silicene, germanene and stanene have recently attracted considerable attention in nanodevice fabrication industry. These materials involving the buckled structure have been…

Materials Science · Physics 2017-04-17 B Mortazavi , O Rahaman , M Makaremi , A Dianat , G Cuniberti , T Rabczuk

Honeycomb structures of group IV elements can host massless Dirac fermions with non-trivial Berry phases. Their potential for electronic applications has attracted great interest and spurred a broad search for new Dirac materials especially…

In search of substrates for adsorption of He atoms allowing for novel quantum phases in restricted geometry we study the case of borophane. We focus on two allotropes of borophane, alpha-4H and Rect-2H. With a suitable Density Functional…

Mesoscale and Nanoscale Physics · Physics 2025-04-21 Stefania De Palo , Saverio Moroni , Francesco Ancilotto , Pierluigi Silvestrelli , Luciano Reatto