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We report the discovery of a bulk superconducting transition at 3.4 K in the ternary phosphide, ScIrP, which crystallizes in a hexagonal ZrNiAl-type structure without spatial inversion symmetry. On the basis of heat capacity data in a zero…

Superconductivity · Physics 2015-12-15 Yoshihiko Okamoto , Takumi Inohara , Youichi Yamakawa , Ai Yamakage , Koshi Takenaka

For the first time, we have reported in this study an ab initio investigation on elastic properties, Debye temperature, Mulliken population, Vickers hardness, and charge density of superconducting ScRhP and ScIrP phosphides. The optimized…

We report the synthesis, crystal structure, superconductivity and physical property characterizations of the ternary equiatomic compound ScRuSi. Polycrystalline samples of ScRuSi were prepared by an arc-melting method. The as-prepared…

Superconductivity · Physics 2017-11-16 Bin-Bin Ruan , Xiao-Chuan Wang , Jia Yu , Bo-Jin Pan , Qing-Ge Mu , Tong Liu , Gen-Fu Chen , Zhi-An Ren

The electronic properties of ScPdGe and ScPdSi, crystallizing in the hexagonal ZrNiAl and orthorhombic TiNiSi structures, respectively, are investigated. ScPdGe and ScPdSi are found to show bulk superconductivity below 0.9 and 1.7 K,…

The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted lots of interests in ternary hydrogen rich materials. In this report, ternary hydride P-S-H has been synthesized through…

Materials Science · Physics 2022-06-15 Tingting Ye , Hong Zeng , Peng Cheng , Deyuan Yao , Xiaomei Pan , Xiao Zhang , Junfeng Ding

We designed and investigated a series of ternary hydride compounds MXH$_{12}$ crystallizing in the cubic $Pm\overline{3}m$ structure as potential rare-earth and alkaline-earth superconductors. First-principles calculations were performed on…

Superconductivity · Physics 2024-08-02 Yuxiang Fan , Bin Li , Cong Zhu , Jie Cheng , Shengli Liu , Zhixiang Shi

Satterthwaite and Toepke (1970 Phys. Rev. Lett. 25 741) predicted high-temperature superconductivity in hydrogen-rich metallic alloys, based on an idea that these compounds should exhibit high Debye frequency of the proton lattice, which…

Superconductivity · Physics 2021-09-21 E. F. Talantsev

Evolutionary structure searches revealed a plethora of stable and low-enthalpy metastable phases in the S-P-H ternary phase diagram under pressure. A wide variety of crystalline structure types were uncovered ranging from those possessing…

Superconductivity · Physics 2022-05-04 Nisha Geng , Tiange Bi , Eva Zurek

While great scientific efforts focus on the synthesis and studies of near-room-temperature (NRT) superconductors exhibited record superconducting transition temperatures (for instance, laser annealed H3S, LaH10 and YHn (n = 4,6,7,9) with Tc…

Superconductivity · Physics 2020-04-21 E. F. Talantsev

The large single crystals of SrSnP were prepared using Sn self-flux method. The superconductivity in the tetragonal SrSnP is observed with the critical temperature of ~2.3 K. The results of a crystallographic analysis, superconducting…

Heat capacity, resistivity, and magnetic susceptibility measurements confirm bulk superconductivity in single crystals of BaIr$_2$P$_2$ (T$_c$=2.1K) and BaRh$_2$P$_2$ (T$_c$ = 1.0 K). These compounds form in the ThCr$_2$Si$_2$ (122)…

Superconductivity · Physics 2009-05-06 N. Berry , C. Capan , G. Seyfarth , A. D. Bianchi , J. Ziller , Z. Fisk

This article reports the experimentally clarified crystal structure of a recently discovered sulfur hydride in high temperature superconducting phase which has the highest critical temperature Tc over 200 K which has been ever reported. For…

Discovery of high-temperature superconductivity in hydrogen-rich compounds has fuelled the enthusiasm for finding materials with more promising superconducting properties among hydrides. However, the ultrahigh pressure needed to synthesize…

Superconductivity · Physics 2021-09-22 Miao Gao , Xun-Wang Yan , Zhong-Yi Lu , Tao Xiang

Superconducting properties of the polycrystalline Zr2Ru3Si4 were investigated by the electrical resistivity, magnetization and specific heat. By these measurements, bulk superconductivity with transition temperature Tc = 5.5 K was…

Superconductivity · Physics 2014-01-09 Soshi Ibuka , Motoharu Imai , Takashi Naka , Mitsuaki Nishio

We studied chemical interaction of Sn with H$_2$ by X-ray diffraction methods at pressures of 180-210 GPa. A previously unknown tetrahydride SnH$_4$ with a cubic structure (${fcc}$) exhibiting superconducting properties below ${T}$$_C$ = 72…

Recently, the thorium hydride ThH9 possessing an H-rich clathrate structure has been experimentally synthesized to exhibit a superconducting transition temperature Tc of 146 K at 170-175 GPa, while the more H-rich clathrate thorium hydride…

Superconductivity · Physics 2023-02-15 Shichang Yao , Chongze Wang , Hyunsoo Jeon , Liangliang Liu , Jin Mo Bok , Yunkyu Bang , Yu Jia , Jun-Hyung Cho

New stable thorium decahydride $Fm\bar{3}m$-$ThH_{10}$, a record high-temperature superconductor with $T_C$ up to 241 K ($-32^{\circ}C$), critical field $H_C$ up to 71T and superconducting gap ${\Delta_0}$ = 52 meV at 80-100 GPa was…

Experimental discovery that compressed sulphur hydride exhibits superconducting transition temperature Tc=203 K (Drozdov et al 2015 Nature 525 73) sparked intensive studies of superconducting hydrides. However, this discovery was not a…

Superconductivity · Physics 2022-11-14 E. F. Talantsev

We report the synthesis, electronic properties, and electronic states of Zr6MTe2 (M = Cr, Mn, Fe, and Co), which is isostructural to a recently discovered superconductor family Sc6MTe2. Based on the electrical resistivity and heat capacity…

We report synthesis and properties of superconducting Bi$_2$PdPt, a new member of Bi-Pd based compounds known for their simultaneous existence of topological surfaces states and superconductivity. It crystallizes in a hexagonal structure…

Superconductivity · Physics 2022-08-17 A. Kataria , T. Agarwal , S. Sharma , D. Singh , S. Marik , R. P. Singh
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