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The standard model of classical Density Functional Theory for pair potentials consists of a hard-sphere functional plus a mean-field term accounting for long ranged attraction. However, most implementations using sophisticated Fundamental…

Computational Physics · Physics 2021-01-04 James F. Lutsko , Cédric Schoonen

A new ATSP2K module is presented for evaluating the electron density function of any multiconfiguration Hartree-Fock or configuration interaction wave function in the non relativistic or relativistic Breit-Pauli approximation. It is first…

Atomic Physics · Physics 2015-05-13 A. Borgoo , O. Scharf , G. Gaigalas , M. Godefroid

The structure of low-energy collective states in proton-deficient N=28 isotones is analyzed using structure models based on the relativistic energy density functional DD-PC1. The relativistic Hartree-Bogoliubov model for triaxial nuclei is…

Nuclear Theory · Physics 2012-09-28 Z. P. Li , J. M. Yao , D. Vretenar , T. Niksic , H. Chen , J. Meng

Correlated materials with open-shell d- and f-ions having degenerate band edge states show a rich variety of interesting properties ranging from metal-insulator transition to unconventional superconductivity. The textbook view for the…

Strongly Correlated Electrons · Physics 2020-07-15 Yubo Zhang , James Furnes , Ruiqi Zhang , Zhi Wang , Alex Zunger , Jianwei Sun

This study investigates the structural evolution of even-even tungsten isotopes ($^{154\text{--}264}$W) using covariant density functional theory (CDFT) with four relativistic functionals: DD-ME1, DD-ME2, DD-PC1, and DD-PCX. Key nuclear…

Nuclear Theory · Physics 2026-04-13 Usuf Rahaman

Accurately modeling photochemical reactions is difficult due to the presence of conical intersections and locally avoided crossings as well as the inherently multiconfigurational character of excited states. As such, one needs a multi-state…

Chemical Physics · Physics 2024-04-26 Matthew R. Hennefarth , Matthew R. Hermes , Donald G. Truhlar , Laura Gagliardi

The Relativistic Configuration-interaction Density functional (ReCD) theory that combines the advantages of large-scale configuration-interaction shell model and relativistic density functional theory is extended to study nuclear chiral…

Nuclear Theory · Physics 2023-10-30 Yakun Wang , Pengwei Zhao , Jie Meng

Non-covalent interactions are essential in the description of soft matter, including materials of technological importance and biological molecules. In density-functional theory, common approaches fail to describe dispersion forces, an…

Chemical Physics · Physics 2014-12-30 Gino A. DiLabio , Alberto Otero-de-la-Roza

A density functional theory is developed for fermions in one dimension, interacting via a delta-function. Such systems provide a natural testing ground for questions of principle, as the local density approximation should work well for…

Other Condensed Matter · Physics 2007-05-23 R. J. Magyar , K. Burke

Background: The study of additional terms in functionals is relevant to better describe nuclear structure phenomenology. Among these terms, the tensor one is known to impact nuclear structure properties, especially in neutron-rich nuclei.…

Nuclear Theory · Physics 2023-03-29 F. Mercier , J. -P. Ebran , E. Khan

The spectroscopic properties of the odd-odd isotopes $^{124-132}$Cs have been studied within the interacting boson-fermion-fermion model based on the Gogny-D1M energy density functional framework. Major ingredients to build the interacting…

Nuclear Theory · Physics 2020-01-15 K. Nomura , R. Rodríguez-Guzmán , L. M. Robledo

Nonadiabatic molecular dynamics is an effective method for modeling nonradiative decay in electronically excited molecules. Its accuracy depends strongly on the quality of the potential energy surfaces, and its affordability for long…

Chemical Physics · Physics 2024-10-11 Matthew R. Hennefarth , Donald G. Truhlar , Laura Gagliardi

Approximate exchange-correlation functionals built by modeling in a non-linear way the adiabatic connection (AC) integrand of density functional theory have many attractive features, being virtually parameters-free and satisfying different…

Chemical Physics · Physics 2018-05-25 S. Vuckovic , P. Gori-Giorgi , F. Della Sala , E. Fabiano

A framework is proposed that allows to write down field theories with a new energy scale while explicitly preserving Lorentz invariance and without spoiling the features of standard quantum field theory which allow quick calculations of…

High Energy Physics - Theory · Physics 2008-11-26 Tomasz Konopka

We present a new quantum embedding theory called dynamical configuration interaction (DCI) that combines wave function and Green's function theories. DCI captures static correlation in a correlated subspace with configuration interaction…

Chemical Physics · Physics 2019-11-21 Marc Dvorak , Dorothea Golze , Patrick Rinke

We re-adapt a spectral renormalization method, introduced in nonlinear optics, to solve the Kohn-Sham (KS) equations of density functional theory (DFT), with a focus on functionals based on the strictly-correlated electrons (SCE) regime,…

Strongly Correlated Electrons · Physics 2020-04-23 Juri Grossi , Ziad H. Musslimani , Michael Seidl , Paola Gori-Giorgi

Even when starting with a very poor initial guess, the iterative configuration interaction (iCI) approach can converge from above to full CI very quickly by constructing and diagonalizing a small Hamiltonian matrix at each…

Chemical Physics · Physics 2020-01-07 Ning Zhang , Wenjian Liu , Mark R. Hoffmann

We present a novel nuclear energy density functional method to calculate spectroscopic properties of atomic nuclei. Intrinsic nuclear quadrupole deformations and rotational frequencies are considered simultaneously as the degrees of freedom…

Nuclear Theory · Physics 2016-02-10 J. Luis Egido , Marta Borrajo , Tomás R. Rodríguez

Motivated by the recent observation of coherent elastic neutrino-nucleus scattering (CE$\nu $NS) at the COHERENT experiment, our goal is to explore its potential in probing important nuclear structure parameters. We show that the recent…

High Energy Physics - Phenomenology · Physics 2019-12-09 D. K. Papoulias , T. S. Kosmas , R. Sahu , V. K. B. Kota , M. Hota

We present the concept, derivation, and implementation of dynamical configuration interaction, a quantum embedding theory that combines Green's function methodology with the many-body wave function. In a strongly-correlated active space, we…

Chemical Physics · Physics 2019-04-03 Marc Dvorak , Patrick Rinke